Page 1 Safety Data Sheet - Touch 'n Seal

1 Page 1 Safety data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date Revision: SECTION 1: Identification of the substance/mixture and of the company/ undertaking Product identifier Trade name: Touch 'n Seal Quick Cure High Yield Straw Foam Article number: EHS 9464 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Sealant Details of the supplier of the Safety data Sheet Manufacturer/Supplier: Convenience Products, division of Clayton Corp. 866 Horan Drive Fenton, MO 63026-2416 Phone: 636-349-5855 Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Classifications listed also are applicable to the OSHA GHS Hazard Com m unication Standard ( ).

2 The following Hazard Statements are applicable only to the EU regulations and not the US GHS regulation: H412. flame Flam. Aerosol 2 H223-H229 Flammable aerosol. Pressurised container: May burst if heated. health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 STOT RE 2 H351 H373 Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. (Contd. on page 2) Page 2 Safety data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date Revision: Trade name: Touch 'n Seal Quick Cure High Yield Straw Foam Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.

3 Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R40-20: Limited evidence of a carcinogenic effect. Harmful by inhalation. Xn; Sensitising R42/43: May cause sensitisation by inhalation and skin contact. Xi; Irritant R36/37/38: Irritating to eyes, respiratory system and skin. F+; Extremely flammable R12: Extremely flammable. (Contd. of page 1) R52/53: Harm ful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Warning! Pressurised container. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data .

4 The classification is in accordance with the latest editions of international substances lists, and is supplemented by information from technical literature and by information provided by the company. Label elements Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the Globally Harmonized System within the United States (GHS). The product is classified and labelled according to the CLP regulation. Hazard pictograms GHS02 GHS07 GHS08 Signal word Danger Hazard-determining components of labelling: diphenylmethanediisocyanate,isomeres and homologues tris[2-chloro-1-(chloromethyl)ethyl] phosphate 4,4'-methylenediphenyl diisocyanate Hazard statements The following Hazard Statements are applicable only to the EU regulations and not the US GHS regulation: H412.

5 H223-H229 Flammable aerosol. Pressurised container: May burst if heated. H315 Causes skin irritation. (Contd. on page 3) Page 3 Safety data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date Revision: Trade name: Touch 'n Seal Quick Cure High Yield Straw Foam H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use. P260 Do not breathe mist/vapours/spray.

6 P211 Do not spray on an open flame or other ignition source. P281 Use personal protective equipment as required. P314 Get medical advice/attention if you feel unwell. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F. (Contd. of page 2) P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Additional information: Contains isocyanates. May produce an allergic reaction. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Hazard description: WHMIS-symbols: A - Compressed gas B5 - Flammable aerosol D2A - Very toxic material causing other toxic effects NFPA ratings (scale 0 - 4) Health = 2 4 Fire = 4 2 0 Reactivity = 0 HMIS-ratings (scale 0 - 4) HEALTH FIRE *2 Health = *2 4 Fire = 4 REACTIVITY 0 Reactivity = 0 * - Indicates a long term health hazard from repeated or prolonged exposures.

7 HMIS Long Term Health Hazard Substances 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 101-68-8 4,4'-methylenediphenyl diisocyanate Other hazards Results of PBT and vPvB assessment PBT: Not applicable. (Contd. on page 4) Page 4 Safety data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date Revision: Trade name: Touch 'n Seal Quick Cure High Yield Straw Foam vPvB: Not applicable. (Contd. of page 3) SECTION 3: Composition/information on ingredients Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues Xn R20; Xn R42/43; Xi R36/37/38 Carc. Cat. 3 20-40% Resp. Sens. 1, H334; STOT RE 2, H373 Acute Tox. 4, H332; Skin Irrit.

8 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 CAS: 101-68-8 EINECS: 202-966-0 Index number: 615-005-00-9 4,4'-methylenediphenyl diisocyanate Xn R20; Xn R42/43; Xi R36/37/38 Carc. Cat. 3 10-20% Resp. Sens. 1, H334; STOT RE 2, H373 Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 CAS: 13674-84-5 tris(2-chlorisopropyl)-phosphate R52/53 5-10% Aquatic Chronic 3, H412 CAS: 74-98-6 EINECS: 200-827-9 Index number: 601-003-00-5 propane F+ R12 5-10% Flam. Gas 1, H220 Press. Gas C, H280 CAS: 72-28-5 Isobutane F+ R12 5-10% Flam. Gas 1, H220 CAS: 13674-87-8 EINECS: 237-159-2 Index number: 015-199-00-X tris[2-chloro-1-(chloromethyl)ethyl] phosphate Xn R40; N R51/53 5-10% Carc. 2, H351 Aquatic Chronic 2, H411 CAS: 156-60-5 EINECS: 205-860-2 Index number: 602-026-00-3 trans-dichloroethylene Xn R20; F R11 R52/53 1-5% Flam.

9 Liq. 2, H225 Acute Tox. 4, H332 Aquatic Chronic 3, H412 Additional information: For the wording of the listed risk phrases refer to section 16. (Contd. on page 5) Page 5 Safety data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date Revision: Trade name: Touch 'n Seal Quick Cure High Yield Straw Foam (Contd. of page 4) SECTION 4: First aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Take affected persons out into the fresh air. After inhalation: Supply fresh air; consult doctor in case of complaints. Provide oxygen treatment if affected person has difficulty breathing.

10 In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. Do not pull solidified product off the skin. If skin irritation continues, consult a doctor. After eye contact: Remove contact lenses if worn, if possible. Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. Most important symptoms and effects, both acute and delayed Asthma attacks Headache Breathing difficulty Allergic reactions Coughing Nausea Gastric or intestinal disorders when ingested. Irritant to skin and mucous membranes. Irritant to eyes. Dizziness Disorientation Hazards Danger of impaired breathing.