PALIOGEN RED K 3580 General Properties - BASF USA

1 PALIOGEN RED K 3580 General PropertiesChemical StructurePerylene RedColour Index Part 149 Colour Index Part II71137 CAS Number4948-15-6 Physical FormPowderColour ShadeRedPreparationsLuprofil Red 35-8005 C 4 Palamid Red 35-8005 Rakusol Red 35-8005 Rakusol Red 35-8007(Other) preparations can be made on special Properties Grade in PVC 1/3 in PVC 1/3 Ratio in PVC 1/3 Hue Grade in PVC 1/9 in PVC 1/9 Ratio in PVC 1/9 Hue Grade in PE-LD 1/3 in PE-LD 1/3 Ratio PE-LD 1/3 Hue Grade in PE-LD 1/9 in PE-LD 1/9 Ratio in PE-LD 1/9 Ease of Dispersion<10 Physical Bulk Index of pH7 Conductivity20 S/cmSpecific Surface76m /gFastness propertiesHeat stability300 CLight fastness8 Weather fastnessMigration fastness4-5 All data is subject to the producer's disclaimerLUCOLOR - basf Colourants for Plastics ( ) - Printed: 8/24/99 Page.

2 1 PALIOGEN RED K 3580 Infl. on warping of PE-HDDistinct Fastness to chemicals:HCl conc.>6 MonthsHCl 10%>6 MonthsH2SO4 10%>6 MonthsHNO3 10%>6 MonthsNaOH conc.>6 MonthsNa2CO3 sat.>6 MonthsCriteria for the fastness to chemicals was a possible colour change of the coloured plastic material during the storage in the test for applicationsPVC-pSuitablePVC-uSuitablePU RS uitableLD-PESuitableHD-PESuitablePPSuita blePSSuitableSBSuitableSANS uitableABS/ASAUCCPMMAS uitablePCUCCPAUCCPETPUCCCA/CABS uitableUPSuitableUCC: Under certain conditionsRecommendations for food : Under certain conditionsAll data is subject to the producer's disclaimerLUCOLOR - basf Colourants for Plastics ( ) - Printed: 8/24/99 Page: 2 LUCOLOR Product Specification - PALIOGEN RED K 3580 Properties Pigment type.

3 Perylene red Colour Index:Pigment Red 149 Application:Colourant for plastics Physical form:Powder Storage:practically unlimited shelf life Food packaging:approved according to "Empfehlung IX des BgVV". SPECIFICATION Colour tolerances:dH* ; dC* ; dL* ; dE* <= ; da* ; db* Strength equivalence:100 5 % Test method: basf test method Please note:The above data will be warranted by us. These data, however, as well as the Properties of any product samples do not imply any legally binding assurance of certain Properties or of suitability for a specific purpose so that any liability for damages cannot be derived - PALIOGEN RED K 3580 All data is subject to the producer's disclaimerLUCOLOR - basf Colourants for Plastics ( ) - Printed: 8/24/99 Weather fastnessPALIOGEN RED K 3580 hoursSteps grey scale 1:501 Test medium.

4 PE-HD (Lupolen 6031M) According to DIN 53387, 54001 0123450500100020003000 All data is subject to the producer's disclaimerLUCOLOR - basf Colourants for Plastics ( ) - Printed: 8/24/99 Particle Size DistributionPALIOGEN RED K 3580 Oversize %Diameter Note: The program stores curve points (see table). The diagram shows approximations. Susp. Fluid: H2O Disp. Agent: Tetronic Mixer Time: 60 s Median Size: u data is subject to the producer's disclaimerLUCOLOR - basf Colourants for Plastics ( ) - Printed: 8/24/99 Reflection CurvePALIOGEN RED K 3580 %Wavelength nmNote: The program stores curve points (see table).

5 The diagram shows :101:100 Test medium: PVC-p 400450500550600650700020406080100 All data is subject to the producer's disclaimerLUCOLOR - basf Colourants for Plastics ( ) - Printed: 8/24/99 Heat StabilityPALIOGEN RED K 3580dE* Temperature CNote: The program stores curve points (see table). The diagram shows :501:10 Test medium: PE-HD (Lupolen 6031M) According to DIN 53772 200220240260280300320012345 All data is subject to the producer's disclaimerLUCOLOR - basf Colourants for Plastics ( ) - Printed: 8/24/99 Light fastnessPALIOGEN RED K 3580 Steps blue wool scale Test medium: PE-HD (Lupolen 6031M) According to DIN 53387, 54004 1:501 Safety DatasheetBASFBASFBASFBASFName of productPALIOGEN Red K No.

6 / Name71 137 / Pigment Red 149, Perylene RedCAS No. / EINECS / 225-590-9 Name of productPALIOGEN Red K 3911 No. / Name71 155 / Pigment Red 178, Perylene RedCAS No. / EINECS / 221-264-5 Name of productPALIOGEN Red K No. / Name71 130 / Pigment Red 179, Perylene RedCAS No. / EINECS / 226-866-1 Name of productPALIOGEN Red Violet K No. / Name71 129 / Pigment Violet 29, Perylene RedCAS No. / EINECS / 201-344-6 Chemical natureThe listed PALIOGEN types, also known as perylene pigments , are derivatives of perylenetetracarboxylic anhydride. Originally used as vat dyes, it is only since 1950 that they have found application as pigments for colouring plastics and high-grade industrial pigments do not exhibit acute oral toxicity in animal trials, nor do they irritate the skin and mucous membranes.

7 A 28-day (subacute) feeding trial carried out with a perylene pigment did not show any adverse toxicological of their poor solubility in water, perylene pigments are nontoxic to aquatic organisms and are not an environmental hazard. An 8-week bioaccumulation study with a perylene pigment on fish showed that the pigment does not accumulate in the above listed products are not dangerous substances in the sense of the German Ordinance on Dangerous Substances or of corresponding EU regulations. Classification as dangerous goodsThe products are not classified as hazardous under transport metal contentPALIOGEN pigments do not contain any lead, cadmium, chromium(VI) and mercury compounds in their formulations.

8 The sum of the total contents of these elements, according to tests on standard samples, is less than 100 mg/kg. It is thus below the limit in the EU packaging directives and the American CONEG < 20 mg/kgChromium< 50 mg/kgArsenic< 20 mg/kgSelenium< 20 mg/kgLead< 20 mg/kgMercury< 20 mg/kgCadmium< 30 mg/kgZinc< 20 mg/kgPrim. aromatic amines< 100 mg/kgThe metal levels quoted are based on the detection limit of the analytical determination method used (X-ray fluorescence spectroscopy). The actual levels may lie well below these contentPALIOGEN pigments do not contain organically combined legislationAccording to tests on standard samples (Type 8081) the listed PALIOGEN pigments conform to the demands on purity in the following food legislation (see also "Heavy metal content"):Europe:Resolution AP (89)Germany:BgVV Empfehlung IX.

9 , 190. Mitteilung vom :Brochure No. 1227. Red K 4180 and Redviolet K 5011 arenot listed in the French Positive :Decreto Ministeriale dated :Resoluci n del de la Subsecretar a de Pigment Red 179 ist listed in the FDA-Positive List ( , ). The other PALIOGEN pigments are in approval. Current use only on evidence of "non migration".ToysAccording to tests on standard samples (Type 8082), the listed PALIOGEN pigments conform to the demands on purity in the European standard on toys, EN 71, Part statusThe components of the products are listed in the chemical inventories of the following countries: EU (EINECS), USA (TSCA), Canada (DSL), Japan (MITI), Australia (AICS), Korea (ECL), Philippines (PICCS, Final Version 1995), and Switzerland (BAGT No.)

10 612200, Class free).Other legislation on chemicalsThe products do not fall under the provisions of the agreement on chemical weapons and do not contain any substances that are mentioned in the German Ordinance on the Prohibition of Certain Chemicals (ChemVerbotsV). They are produced without using substances that destroy ozone (Montreal Agreement - Ozone Depleting Substances).TA LuftPara - Total dust (Germany)MAK valueThe General threshold value for dust, 6 mg/m , must be observed. (Proposal of the MAK commission for the alveolar passing dust fraction, mg/m , is not yet valid) (Germany)Water hazard classWGK 1 (slightly water hazardous according to German legislation - KBwS - group classification organic colours) Further information can be found in our Material Safety Data Sheets and Technical Information Bulletins.