1 PENAPATCH STRUCTURAL hb80 20 KGChemwatch Independent Material Safety Data SheetIssue Date: 5-Jun-2012 CHEMWATCH 32-16379317 SPVersion 2012/2 Page 1 of 7 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEPENAPATCH STRUCTURAL hb80 20 KGPRODUCT USEHigh strength cementitious mortar used for STRUCTURAL : ITLS- TWA Australia Pty LtdAddress:250 Princes HighwayDandenongVIC, 3175 AustraliaTelephone: +61 3 9791 8211 Emergency Tel:+61 3 9791 8211 Fax: +61 3 9791 8644 Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG CodesRisk PhrasesR37/38 Irritating to respiratory system and Risk of serious damage to Harmful: danger of serious damage to health by prolongedexposure through CodesSafety PhrasesS22 Do not breathe Avoid contact with Avoid contact with Wear suitable protective Wear suitable Wear eye/face Use only in well ventilated Keep container in a well ventilated To clean the floor and all objects contaminated by thismaterial, use waterand Keep away from food, drink and animal feeding In case of contact with eyes, rinse with plenty of water and contact Doctor orPoisons Information If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre.
2 (showthis container or label). STRUCTURAL hb80 20 KGChemwatch Independent Material Safety Data SheetIssue Date: 5-Jun-2012 CHEMWATCH 32-16379317 SPVersion 2012/2 Page 2 of 7 Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAMECAS RN%portland cement65997-15-130-60silica crystalline - quartz14808-60-730-60 NOTE: Manufacturer has supplied full ingredientinformation to allow CHEMWATCH 4 - FIRST AID MEASURESSWALLOWED - If swallowed do NOT induce If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent Observe the patient Never give liquid to a person showing signs of being sleepy or with reduced awareness; becoming If this product comes in contact with the eyes:- Immediately hold eyelids apart and flush the eye continuously with running Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 Transport to hospital or doctor without If skin contact occurs:- Immediately remove all contaminated clothing, including Flush skin and hair with running water (and soap if available).
3 - Seek medical attention in event of - If fumes or combustion products are inhaled remove from contaminated Lay patient down. Keep warm and Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if TO PHYSICIAN Treat 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA - There is no restriction on the type of extinguisher which may be Use extinguishing media suitable for surrounding FIGHTING - Alert Fire Brigade and tell them location and nature of Wear breathing apparatus plus protective gloves in the event of a Prevent, by any means available, spillage from entering drains or water Use fire fighting procedures suitable for surrounding HAZARD - Non Not considered a significant fire risk, however containers may burn, silicon dioxide (SiO2).
4 May emit poisonous emit corrosive INCOMPATIBILITY None STRUCTURAL hb80 20 KGChemwatch Independent Material Safety Data SheetIssue Date: 5-Jun-2012 CHEMWATCH 32-16379317 SPVersion 2012/2 Page 3 of 7 Section 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS - Remove all ignition Clean up all spills Avoid contact with skin and Control personal contact with the substance, by using protective SPILLS Moderate CAUTION: Advise personnel in Alert Emergency Services and tell them location and natureof Control personal contact by wearing protective Prevent, by any means available, spillage from entering drains or water Protective Equipment advice is contained in Section 8 of the 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING - Avoid all personal contact, including Wear protective clothing when risk of exposure Use in a well-ventilated Prevent concentration in hollows and CONTAINER - Polyethylene or polypropylene Check all containers are clearly labelled and free from INCOMPATIBILITY - Avoid strong acids, acid chlorides, acid anhydrides and REQUIREMENTS - Store in original Keep containers securely Store in a cool.
5 Dry area protected from environmental Store away from incompatible materials and foodstuff 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSS ourceMaterialTWA mg/m Notes_____Australia Exposure Standardsportland cement (Portland cement10(see Chapter 14)(a))Australia Exposure Standardssilica crystalline - (see Chapter 14)(Silica - Crystalline Quartz)MATERIAL DATAPORTLAND CEMENT:SILICA CRYSTALLINE - QUARTZ: The concentration of dust, for application of respirable dust limits, is to be determined from the fraction that penetratesa separator whose size collection efficiency is described by a cumulative log-normal function with a median aerodynamic diameterof m (+-) m and with a geometric standard deviation of m (+-) m, less than 5 STRUCTURAL hb80 20KG:Not availablePORTLAND CEMENT: for calcium silicate:containing no asbestos and <1% crystalline silicaES TWA: 10 mg/m3 inspirable dustTLV TWA.
6 10 mg/m3 total dust (synthetic nonfibrous) A4 Although in vitro studies indicate that calcium silicate ismore toxic than substances described as "nuisance dusts" isthought that adverse health effects which might occur following exposure to 10-20 mg/m3 are likely to be minimal. The TLV-TWA STRUCTURAL hb80 20 KGChemwatch Independent Material Safety Data SheetIssue Date: 5-Jun-2012 CHEMWATCH 32-16379317 SPVersion 2012/2 Page 4 of 7 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION thought to be protective against the physical risk of eye andupper respiratory tract irritation in workers and to preventinterference with vision and deposition of particulate in the eyes, ears, nose and calcium oxide:The TLV-TWA is thought to be protective against undue irritation and is analogous to that recommended for sodium.
7 This substance has been classified by the ACGIH as A4 NOT classifiable as causing Cancer in cement is considered to be a nuisance dust that doesnot cause fibrosis and has little potential to induce adverseeffects on the CRYSTALLINE - QUARTZ: Because the margin of safety of the quartz TLV is not known with certainty and given the associated link between silicosisand lung cancer it is recommended that quartz concentrations be maintained as far below the TLV as prudent practices : For inhalation exposure ONLY:This substance has been classified by the ACGIH as A2 Suspected Human PROTECTIONRESPIRATOR Type AX-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)EYE - Safety glasses with side Chemical Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants.
8 A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areviewof lens absorption and adsorption for the class of chemicalsin use and an account of injury experience. Medical and first-aidpersonnel should be trained in their removal and suitable equipment should be readily available. In the event of chemicalexposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at thefirstsigns of eye redness or irritation - lens should be removed ina clean environment only after workers have washed handsthoroughly. [CDC NIOSH Current Intelligence Bulletin 59],[AS/NZS 1336 or national equivalent].HANDS/FEET NOTE:- The material may produce skin sensitisation in predisposed individuals.
9 Care must be taken, when removing gloves and otherprotective equipment, to avoid all possible skin Contaminated leather items, such as shoes, belts and watch-bands should be removed and and durability of glove type is dependent on usage. Important factors in the selection of gloves include:- frequency and duration of contact,- chemical resistance of glove material,- glove thickness and- indicates that the following polymers are suitable as glove materials for protection against undissolved,dry solids,where abrasive particles are not polychloroprene- nitrile rubber- butyl rubber- - Barrier Skin cleansing CONTROLS Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protectingworkers and will typically be independent of worker interactions toprovide this high level of basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the and/or isolation of emission source which keeps aselected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEFine grey powder.
10 Partly mixes with STRUCTURAL hb80 20 KGChemwatch Independent Material Safety Data SheetIssue Date: 5-Jun-2012 CHEMWATCH 32-16379317 SPVersion 2012/2 Page 5 of 7 Section 9 - PHYSICAL AND CHEMICAL PROPERTIESPHYSICAL PROPERTIESS tateDivided SolidMolecular WeightNot ApplicableMelting Range ( C)Not AvailableViscosityNot ApplicableBoiling Range ( C)Not ApplicableSolubility in water (g/L)Partly MiscibleFlash Point ( C)Not ApplicablepH (1% solution)Not AvailableDecomposition Temp ( C)Not AvailablepH (as supplied)Not ApplicableAutoignition Temp ( C)Not AvailableVapour Pressure (kPa)NegligibleUpper Explosive Limit (%)Not ApplicableSpecific Gravity (water=1) Explosive Limit (%)Not ApplicableRelative Vapour DensityNot Available(air=1)Volatile Component (%vol)