PRODUCT: TRIETHANOLAMINE 85% CODE: 931505 …

1 00001940 MATERIAL SAFETY DATA SHEETPage 1 CANADA COLORS & CHEMICALS LTD 152 KENNEDY ROAD SOUTHBRAMPTON, ONTARIOCANADA L6W 3G4(905) 459-1232; CODE: 931505 product : TRIETHANOLAMINE 85% section 01: chemical product AND COMPANY COLORS & CHEMICALS LTD. 152 KENNEDY ROAD SOUTH BRAMPTON, ONTARIO CANADA L6W 3G4 PREPARED AffairsPREPARATION 85% product chemical MATERIAL REFER TO TECHNICAL LITERATURE. EMERGENCY PHONE (416)-444-2112. section 02: COMPOSITION/INFORMATION ON INGREDIENTSH azardous Ingredients%Exposure #LD/50, Route,SpeciesLC/50 Route,SpeciesTRIETHANOLAMINE85-89 SEE section 11102-71-6 SEE section 11 SEE section 11N,N-DIETHANOLAMINE11-15 SEE section 11111-42-2 SEE section 11 SEE section 11 section 03: HAZARDS IDENTIFICATIONROUTE OF ENTRY:SKIN CONTACT MAY CAUSE SLIGHT IRRITATION WITH ITCHING AND LOCAL REDNESS.

2 PROLONGED CONTACT MAY CAUSE MORE SEVERE IRRITATION, WITH DISCOMFORT OR PAIN, LOCAL REDNESS AND SWELLING, AND POSSIBLE TISSUE DESTRUCTION. SKIN OR WIDESPREAD CONTACT MAY RESULT IN THE ABSORPTION OF POTENTIALLY HARMFUL AMOUNTS OF MATERIAL. EYE MODERATE TO SEVERE IRRITATION, EXPERIENCED AS DISCOMFORT OR PAIN, EXCESS BLINKING AND TEAR PRODUCTION, WITH MARKED EXCESS REDNESS AND SWELLING OF THE CONJUCTIVA. CAUSES CORNEAL DAMAGE. OR MIST FROM HEATED MATERIAL MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT, EXPERIENCED AS NASAL DISCOMFORT AND DISCHARGE, WITH CHEST PAIN AND COUGHING. TOXIC. MAY CAUSE BURNING OR PAINFUL SENSATIONS IN THE MOUTH, THROAT, CHEST, AND ABDOMEN, NAUSEA, VOMITING, AND DIARRHEA.

3 MAY CAUSE DIZZINESS, DROWSINESS, FAINTNESS, WEAKNESS, COLLAPSE, AND COMA. EFFECTS OF ACUTE TO ROUTE OF ENTRY. EFFECTS OF CHRONIC EXPOSURE MAY CAUSE DAMAGE TO KIDNEYS AND LIVER. SKIN CONTACT MAY CAUSE SENSITIZATION AND AN ALLERGIC SKIN REACTION IN A SMALL PROPORTION OF INDIVIDUALS. MEDICAL CONDITIONS AGGRAVATED BY SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS. INHALATION OF OVEREXPOSUREMATERIAL MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. section 04: FIRST AID MEASURESINSTRUCTIONS:..INHALATION: REMOVE TO FRESH AIR. EYE CONTACT: IMMEDIATELY FLUSH EYES WITH WATER AND CONTINUE WASHING FOR AT LEAST 15 MINUTES. DO NOT REMOVE CONTACT LENSES, IF WORN.

4 OBTAIN MEDICAL ATTENTION WITHOUT DELAY, PREFERABLY FROM AN OPHTHALMOLOGIST. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND WATER. OBTAIN MEDICAL ATTENTION IF CONTACT HAS BEEN WIDESPREAD AND PROLONGED, OR IF IRRITATION PERSISTS. WASH CLOTHING BEFORE REUSE. SWALLOWING: IF PATIENT IS FULLY CONSCIOUS, GIVE TWO GLASSES OF WATER. INDUCE VOMITING. THIS SHOULD BE DONE ONLY BY MEDICAL OR EXPERIENCED FIRST-AID PERSONNEL. OBTAIN MEDICAL ATTENTION. NOTES TO PHYSICIAN:..THERE IS NO SPECIFIC ANTIDOTE. TREATMENT SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS AND THE CLINICAL CONDITION OF THE PATIENT. THE HAZARDS OF THIS MATERIAL ARE DUE MAINLY TO ITS SEVERELY IRRITANT PROPERTIES ON THE SKIN AND MUCOSAL SURFACES.

5 00001940 MATERIAL SAFETY DATA SHEETPage 2 CODE: 931505 product : TRIETHANOLAMINE 85% section 05: FIRE FIGHTING FLASH POINT. IF YES, UNDER WHICH CONDITIONS?EXTINGUISHING FIRES WITH WATER SPRAY OR APPLY ALCOHOL-TYPE OR ALL-PURPOSE-TYPE FOAM BY MANUFACTURER'S RECOMMENDED TECHNIQUES FOR LARGE FIRES. USE CARBON DIOXIDE OR DRY chemical MEDIA FOR SMALL FIRES. SPECIAL NOT DIRECT A SOLID STREAM OF WATER OR FOAM INTO BURNING MOLTEN MATERIAL; THIS MAY CAUSE SPATTERING AND SPREAD THE FIRE. USE SELF-CONTAINED BREATHING APPARATUS, EYE PROTECTION, AND PROTECTIVE CLOTHING. FLASH POINT (C), C (382 F) PMCC ASTM D 93; 190. 5 C (375 F) COC ASTM D 92. AUTO IGNITION UPPER FLAMMABLE LIMIT (% BY VOL.)

6 NOT DETERMINED. LOWER FLAMMABLE LIMIT (% BY VOL.)..NOT DETERMINED. RATE OF SENSITIVITY TO STATIC SENSITIVITY TO UNUSUAL FIRE AND EXPLOSION ..DURING FIRE, OXIDES OF NITROGEN MAY BE EVOLVED. HAZARDSHAZARDOUS COMBUSTION CAN PRODUCE THE FOLLOWING PRODUCTS: OXIDES OF CARBON AND NITROGEN. CARBON MONOXIDE IS HIGHLY TOXIC IF INHALED; CARBON DIOXIDE IN SUFFICIENT CONCENTRATIONS CAN ACT AS AN ASPHYXIANT. ACUTE EXPOSURE TO THE PRODUCTS OF COMBUSTION MAY RESULT IN IRRITATION OF THE RESPIRATORY TRACT. section 06: ACCIDENTAL RELEASE FOR DISPOSAL. WEAR SUITABLE PROTECTION EQUIPMENT. AVOID CONTACT WITH EYES AND SKIN. section 07: HANDLING AND STORAGEHANDLING PROCEDURES AND.

7 AVOID BREATHING VAPOUR. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO EQUIPMENTNOT SWALLOW. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. DO NOT ADD NITRITES OR OTHER NITROSATING AGENTS. A NITROSAMINE, WHICH MAY CAUSE CANCER, MAY BE FORMED. (MECHANICAL) ROOM VENTILATION IS EXPECTED TO BE SATISFACTORY WHERE THIS product IS STORED AND HANDLED IN CLOSED EQUIPMENT. SPECIAL LOCAL VENTILATION IS NEEDED AT POINTS WHERE VAPOURS CAN BE EXPECTED TO ESCAPE TO THE WORKPLACE AIR. STORAGE SEGREGATE OR FREEZE BELOW 16 C (60 F). THAW AND MIX BEFORE SAMPLING OR USING. STORE AWAY FROM INCOMPATIBLE MATERIALS. section 08: EXPOSURE CONTROLS/PERSONAL PROTECTIONGLOVES/ , POLYVINYL CHLORIDE COATED.

8 SELF-CONTAINED BREATHING APPARATUS IN HIGH VAPOUR CONCENTRATIONS. FOOTWEAR. CLOTHING. chemical APRON. BATH AND SAFETY SHOWER. ENGINEERING (MECHANICAL) ROOM VENTILATION IS EXPECTED TO BE SATISFACTORY WHERE THIS product IS STORED AND HANDLED IN CLOSED EQUIPMENT. SPECIAL, LOCAL VENTILATION IS NEEDED AT POINTS WHERE VAPOURS CAN BE EXPECTED TO ESCAPE TO THE WORKPLACE AIR. ADDITIONAL HAZARD:.. WARNING: SUDDEN RELEASE OF HOT ORGANIC chemical VAPOURS OR MISTS FROM PROCESS EQUIPMENT OPERATING AT ELEVATED TEMPERATURE AND PRESSURE, OR SUDDEN INGRESS OF AIR INTO HOT EQUIPMENT UNDER A VACUUM, MAY RESULT IN IGNITIONS WITHOUT THE PRESENCE OF OBVIOUS IGNITION SOURCES.

9 PUBLISHED "AUTOIGNITION" OR "IGNITION" TEMPERATURE VALUES CANNOT BE TREATED AS SAFE OPERATING TEMPERATURES IN chemical PROCESSES WITHOUT ANALYSIS OR THE ACTUAL PROCESS CONDITIONS. ANY USE OF THIS product IN ELEVATED-TEMPERATURE PROCESSES SHOULD BE THOROUGHLY EVALUATED TO ESTABLISH AND MAINTAIN SAFE OPERATING CONDITIONS. FURTHER INFORMATION IS AVAILABLE IN A TECHNICAL BULLETIN ENTITLED "IGNITION HAZARDS OR ORGANIC chemical VAPOURS.". 00001940 MATERIAL SAFETY DATA SHEETPage 3 CODE: 931505 product : TRIETHANOLAMINE 85% section 09: PHYSICAL AND chemical PROPERTIESPHYSICAL TRANSPARENT COLOURLESS TO PALE AMBER. AMMONICAL. ODOUR VAPOUR PRESSURE (MMHG)..< (20 C).

10 VAPOUR DENSITY (AIR=1).. EVAPORATION < BOILING C ( F). EXTRAPOLATED WITH DECOMPOSITION. SPECIFIC GRAVITY (WATER=1).. (20 C/20 C). FREEZING C ( F). PERCENT VOLATILE (BY WEIGHT).. SOLUBILITY IN WATER (% W/W)..100 % (20 C). COEFFICIENT OF WATER/OIL section 10: STABILITY AND REACTIVITYCHEMICAL NO, WHICH CONDITIONS?..TEMPERATURES ABOVE 250 C. MAY UNDERGO SELF-SUSTAINING THERMAL DECOMPOSITION. COMPATABILITY WITH OTHER SUBSTANCES:YESNO, WHICH ONES?..STRONG OXIDIZING AGENTS, STRONG BASES, STRONG ACIDS, ALDEHYDES, KETONES, ACRYLATES, ORGANIC ANHYDRIDES, ORGANIC HALIDES. REACTIVITY CONDITIONS?..SEE ABOVE. HAZARDOUS PRODUCTS OF ..SEE HAZARDOUS COMBUSTION PRODUCTS.