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Regulatory up date on biocides - aptintas.pt

Regulatory up date on biocides Gilles PRADIER. New Products Leader APT Seminar April 4th 2014. Ashland Specialty Ingredients Overview Introduction about Ashland biocides Technical support Re-Classification of Formaldehyde Impact on Ashland's FH-donors classification? New labeling contrains (CLP regulation). Ashland's solutions to avoid EU H208. Conclusion, 2. Ashland Specialty Ingredients 1. Introduction Ashland's biocides 3. Ashland Specialty Ingredients History of Ashland's biocides Nuodex/Tenneco/. Creanova/Degussa 2002: Acquired Degussa's biocides 2006: Added businesses business of Milker & Gr ning, Progiven, 2011. ISP. acquisition 2004: Acquired Biochema 2007: Acquired Schwaben Bode Chemie 4. Ashland Specialty Ingredients biocides manufacturing facilities Leaside, Canada Memmingen, Germany Chatham, USA Horhausen, Germany 5.

17 Ashland Specialty Ingredients ¤ O-FORMAL EDDM or EG-formal (Bodoxin) Fast releasing FA-Donor / release factor 49% Free FH content > 0,1% for most of EDDM

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Transcription of Regulatory up date on biocides - aptintas.pt

1 Regulatory up date on biocides Gilles PRADIER. New Products Leader APT Seminar April 4th 2014. Ashland Specialty Ingredients Overview Introduction about Ashland biocides Technical support Re-Classification of Formaldehyde Impact on Ashland's FH-donors classification? New labeling contrains (CLP regulation). Ashland's solutions to avoid EU H208. Conclusion, 2. Ashland Specialty Ingredients 1. Introduction Ashland's biocides 3. Ashland Specialty Ingredients History of Ashland's biocides Nuodex/Tenneco/. Creanova/Degussa 2002: Acquired Degussa's biocides 2006: Added businesses business of Milker & Gr ning, Progiven, 2011. ISP. acquisition 2004: Acquired Biochema 2007: Acquired Schwaben Bode Chemie 4. Ashland Specialty Ingredients biocides manufacturing facilities Leaside, Canada Memmingen, Germany Chatham, USA Horhausen, Germany 5.

2 Ashland Specialty Ingredients Ashland s brands WET-STATE PROTECTION DRY FILM PROTECTION. Nuosept Fungitrol . Bodoxin, Bacillat, Ebotec Cinon, Fongal Nuosept : IN-CAN biocides Fungitrol : DRY-FILM biocides ensure wet-state preservation ensure film protection against of water-based products fungi & algae defacements 6. Ashland Specialty Ingredients Active substances supported by Ashland in Europe CAS N Product Rapporteur Dossier submitted by /. Active substances Types(PT) Member companies State EG-Form (EU) 3586--55--8 2, 6, 11, Poland ASI in task force (Ethylendioxy) dimethanol 12*, 13 * ASI. HHT (EU/US) 4719-04-4 6, Poland ASI in task force (Hexahydrotriazin) 11*,12*, *ASI. 13. TMAD (EU) 5395-50-6 2, 6, 11, Spain ASI in task force (Tetra Methylol Acetylene Diurea) 12, 13. Na-N(hydroxymethylglycinate) 70161-44-3 6 Austria ASI.

3 (EU/US/CDN). BIT (EU/US/CDN) 2634-33-5 6, 12, 13 Spain Data access IPBC (EU/US/CDN) 55406-53-6 6, 7, 8, 9, Denmark ASI in task force (Iodo propynyl butyl carbamate) 10, 13. Folpet) EU/US/CDN) 133-07-3 7, 9 Italy Data access (N-(trichloromethylthio)phthalimide). 7. Ashland Specialty Ingredients 2. Technical support 8. Ashland Specialty Ingredients Technical support Biocide selection Optimal preservation Challenge tests Plant Hygiene HPLC analysis Bio-audit9. Ashland Specialty Ingredients Technical support/In-Can challenge tests 10. Ashland Specialty Ingredients Technical support/ Dry film biocides Bio-resistance tests : Fungus resistance EN 15457. Algae resistance EN 15458. Yellowing (L*a*b ; Yi measurement). On site expertise/strain identification Fence test exposure (Memmingen). 11. Ashland Specialty Ingredients Fungus resistance test/ Fa ade paints Unprotected paint Protected protected 12.

4 Ashland Specialty Ingredients Algae resistance test of fa ade paints Unprotected render Protected render 13. Ashland Specialty Ingredients Technical support/Dry film challenge tests 14. Ashland Specialty Ingredients 3. Re-classification of Formaldehyde & FH-donors 15. Ashland Specialty Ingredients Reclassification of Formaldehyde and related effects on FH Donors mixtures Formaldehyde will be reclassified from 1st April 2015 : carcinogen category 2 H351 to a carcinogen category 1B H350. Formaldehyde Donors and Formaldehyde donors containing mixtures will be reclassified as carcinogen category 1B H350 if containing > Free Formaldehyde (NMR analysis). No labeling impact to paints when FH-donors are used at recommended levels Handling restrictions for CAR Cat 1B mixtures (limited storage for plants below Seveso classification). 16.

5 Ashland Specialty Ingredients Impact on Ashland's FH Donors O-FORMAL. eddm or EG-formal (Bodoxin). Fast releasing FA-Donor / release factor 49%. Free FH content > 0,1% for most of eddm - biocides Most of eddm - biocides will be classified as CAR Cat 1B. Might limit storage in plant sites not classified SEVESO . N-FORMAL. TMAD (Bacillat ). Slow releasing FA-Donor / release factor 26%. Premium quality TMAD available with less than 0,1% Free FH. Most of Bacillat will not get re-classified Car Cat 1B. No handling & storage restriction 17. Ashland Specialty Ingredients 5. Impact of the new labeling regulation (CLP). 18. Ashland Specialty Ingredients CLP Regulation/ New EU H208 Info statement Labeling rules will change for mixtures containing skin sensitizing substances from 1st June 2015. New Information statement EU H208 . will prevent end-users about the presence of skin sensitizing substances if their concentrations exceed 1/10 of current labelling limits Contains (name of sensitizing substance).

6 May produce an allergic reaction . This information statement might be a problem for DIY. market and more particularly for premium quality paints 19. Ashland Specialty Ingredients New labeling limits EU H208. Substances EU H208 triggers EU Ecolabel CMIT/MIT ppm 15 ppm/ Iso total<500ppm IN-CAN TOTAL <600ppm OIT 50 ppm <500ppm IN-CAN TOTAL <600ppm BIT 50 ppm <500ppm IN-CAN TOTAL <600ppm MIT 100 ppm 200 ppm: Iso total<500ppm IN-CAN TOTAL <600ppm DCOIT 100 ppm Dry film total < 0,1% Indoor Dry film tottal < 0,3% outdoor eddm 410 ppm* <10ppm free FH VdL 03. TMAD 760 ppm* <10 ppm free FH VdL 03. DBDCB 1000 ppm IN-Can tital < 600ppm IPBC 1000 ppm 1000p pm indoor 6500 ppm outdoor BRONOPOL Non skin sensitizing <10 ppm Free FH VdL 03. IN-CAN TOTAL <600ppm Zinc Pyrithione Non skin sensitizing 500ppm IN-CAN TOTAL <600ppm Phenoxy Ethanol Non skin sensitizing IN-CAN TOTAL <600ppm *Max.

7 Values recommended by ASI to avoid exceeding 200ppm free Formaldehyde in end products 20. Ashland Specialty Ingredients Ashland's solutions to avoid EU H208. a. Formaldehyde-donors biocides b. Bronopol- biocides c. Formaldehyde-free biocides 21. Ashland Specialty Ingredients free solutions/ FH-Donors N-Formal Actives EUH208. statement . trigger Nuosept TBM 40 (NEW) TMAD + BIT+ MIT 0,20%. Bacillat TK TMAD + MIT 0,28%. Bacillat TOK TMAD + MIT + OIT 0,33%. Bacillat TMAD 0,13%. 0,1-0,2% Nuosept TBM 40 max. (760ppmTMAD +50ppm BIT+ 50ppm MIT). Ideal for replacing CMIT/MIT + FH-Donors and/or BIT+ FH-Donors Bacillat TK : Max. (760ppm TMAD+ 50ppm MIT). Booster recommended in combination with 0,1% Nuosept BM22) (5%BIT+ 5%MIT). Flex solution 50ppm BIT+ 100ppm MIT+ 760 ppm TMAD. Bacillat TOK: Max. ( 250 ppm TMAD+ 100ppm MIT+ 50ppmOIT). Low emission FH <100ppm/, Enhanced fungicidal resistance Bacillat + Nuosept BM22 : max.

8 (760ppmTMAD +50ppmBIT+ 50ppmMIT). Flex. Solution/Possible adjustment of active contents 22. Ashland Specialty Ingredients free solutions/ FH-Donors Nuosept TBM40. Solution of BIT/MIT/TMAD in a non VOC carrier No CAR Cat 1B classification No EUH208 to customer end-products Liquid solution/easy to pour & handle Low odor Highly concentrated/High performances Broad spectrum of efficacy vs bacteria/yeasts/molds Head space protection Typical use : 0,1-0,2%. 23. Ashland Specialty Ingredients b. Labeling free solutions/Bronopol PRODUCT name Actives NEW. EU H308. triggers Nuosept KMB (NEW) BIT/MIT/BNPD Ebotec KB MIT/BNPD Nuosept KMB : Broad spectrum of activity Fast speed of kill Eu Ecolabel compliance Cost effective Ebotec KB : Booster recommended at the early stage of the production in combination with BIT/MIT. 0,1-0,2% Ebotec KB + 0,1% Nuosept BM22.

9 Max. 50ppm BIT+ 100ppm MIT+ 200 ppm BNPD. 24. Ashland Specialty Ingredients c. Labeling free solutions/FH-Free biocides FA-free products Actives EU H208. statement . trigger in %. Nuosept BM22 BIT/MIT 0,10%. Nuosept BMZ (NEW) BIT/MIT/ZnPt 0,2%. Nuosept BMZ: BIT + MIT + ZnPt Broad spectrum of efficacy Enhanced fungicidal properties protection of the interface liquid/head space Cost effective preservation Ideal substitution of preservation based on BIT+ MIT + CMIT/MIT. 25. Ashland Specialty Ingredients Conclusion Ashland offers FH-donors biocides which will not get reclassified as CAR Cat 1B. Ashland offers various biocide solutions in line with Eu- Ecolabel & without EU H208 Infop statement to your paints For more information and discuss the most adequate solutions to your needs, please contact : BRENTAG Portugal or directly 26.

10 Ashland Specialty Ingredients Thanks for your attention Any question? 27. Ashland Specialty Ingredients


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