Roebic Foaming Root Killer GHS SDS 11 7 2016

1 SAFETY DATA SHEET. Roebic Foaming root Killer Prepared to OSHA, CMA, ANSI, Canadian WHMIS Standards, Australian WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and European Directives 1. PRODUCT IDENTIFICATION. TRADE NAME (AS LABELED): Roebic Foaming root Killer PRODUCT NUMBERS: Various EPA REGISTRATION NUMBER: 7792-7. SYNONYMS: None known CAS#: Mixture PRODUCT USE: A Foaming herbicide for control of roots in pipelines. MANUFACTURER'S NAME: Roebic Laboratories, Inc. ADDRESS: 927, 25 Connair Road, Orange, CT 06477 USA. BUSINESS PHONE: 1-203-795-1283 (Product Information).

2 FAX NUMBER: 1-203-795-5227. EMERGENCY PHONE NUMBER: EMERGENCY PHONE #: 1-800-424-9300 Chemtrec (TOLL-FREE in USA/Canada). EMAIL: PREPARATION INFORMATION: DATE OF CURRENT REVISION: November 7, 2016. DATE OF LAST REVISION: October 25, 2016. 2. HAZARD IDENTIFICATION. EMERGENCY OVERVIEW: Product Description: This product is a white to brown powder with a slight aromatic odor. Health Hazards: May cause skin or eye irritation. Flammability Hazards: This product is a non-flammable liquid. Reactivity Hazards: None known Environmental Hazards: The Environmental effects of this product have not been investigated.

3 Release of this product may have adverse effects in the aquatic environment. GHS LABELING AND CLASSIFICATION: This product does meet the definition of a hazardous substance or preparation as defined by 29 CFR 1910. 1200 and regulation (EU) No. 2015/830 and regulation (EC) No. 1272/2008. Index Number: EC# 226-218-8 This substance is classified in the Annex V Index #016-026-00-0. EC# 207-838-8 This substance is classified in the Annex V Index #011-005-00-2. EC# 214-787-5 This substance is classified in the Annex V Index #608-015-00-X. EC# 310-194-1 This substance is not classified in the Annex V.

4 EC# 500-315-8 This substance is not classified in the Annex V. EC# 271-657-0 This substance is not classified in the Annex V. Substances not listed either individually or in group entries must be self classified. Component(s) Contributing to Classification(s). All Components LABEL ELEMENTS: GHS Hazard Symbol(s). Signal Word: Warning! GHS Hazard Classification(s): Skin Irritation Category 2. Eye Irritation Category 2. Aquatic Chronic Category 3. Aquatic Acute Category 3. Roebic Laboratories, Inc. Page 1 of 8. SAFETY DATA SHEET. Roebic Foaming root Killer Hazard Statement(s): Prevention Statement(s): H315: Causes skin irritation P264: Wash skin after handling H319: Causes serious eye irritation P280: Wear eye protection / face protection H402: Harmful to aquatic life P273: Avoid release to the environment H412: Harmful to aquatic life with long lasting effects Response Statement(s): Storage Statement(s): P302+P352: IF ON SKIN: Wash with plenty of water.

5 None applicable Manufacturer / Supplier or the competent authority may specific a cleansing agent if appropriate, or may recommend an alternative Disposal Statement(s): agent in exceptional cases if water is clearly inappropriate. P501: Dispose of contents/container in accordance P332+P313: If skin irritation occurs: Get medical advice / attention. with local/regional/national/international regulations P362+P364: Take off contaminated clothing and wash it before reuse. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

6 Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. OTHER HAZARDS: None Applicable 3. COMPOSITION AND INFORMATION ON INGREDIENTS. Hazardous Ingredients: WT% CAS# EINECS # Hazard Classification Sulphamic Acid Skin Irritant Cat 2, Eye Irritant Cat 2, 30-50% 5329-14-6 226-218-8. Aquatic Acute Cat 3, Aquatic Chronic Cat 3. Sodium Carbonate 20-40% 497-19-8 207-838-8 Eye Irritant Cat 2. Kaolin 11-12% 1332-58-7 310-194-1 Not Classified 4-Nonylphenol, branched, Acute Toxicity Category 4 (Oral), Eye Damage Cat 1, Aquatic <3% 127087-87-0 500-315-8.

7 Ethoxylated Acute Cat 2, Aquatic Chronic Cat 2. Cocoamide DEA <1% 68603-42-9 271-657-0 Skin Irritant Cat 2, Eye Irritant Cat 2. Dichlobenil <1% 1194-65-6 214-787-5 Acute Toxicity Category 4 (Oral), Aquatic Chronic Cat 2. Balance of other ingredients is less than 1% in concentration (or for carcinogens, reproductive toxins, or respiratory sensitizers). NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI format. This product has been classified in accordance with the hazard criteria of the CPR and the SDS contains all the information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250: 2000.

8 4. FIRST-AID MEASURES. DESCRIPTION OF FIRST AID MEASURES: EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for at least 15 minutes. Seek medical attention if irritation persists. SKIN CONTACT: If product contacts skin, wash skin thoroughly with soap and water after handling. Seek medical attention if irritation develops and persists. INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Seek medical attention. INGESTION: If product is swallowed, call physician or poison control center for most current information.

9 If professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the label and/or SDS with the victim to the health professional. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: Exposure to this product may cause irritation to skin and eyes. RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. Roebic Laboratories, Inc.

10 Page 2 of 8. SAFETY DATA SHEET. Roebic Foaming root Killer 5. FIRE-FIGHTING MEASURES. FIRE EXTINGUISHING MATERIALS: Use fire extinguishing methods below: Water Spray: Yes Carbon Dioxide: Yes Foam: Yes Dry Chemical: Yes Halon: Yes Other: Any C Class UNUSUAL FIRE AND EXPLOSION HAZARDS: None known Explosion Sensitivity to Mechanical Impact: No Explosion Sensitivity to Static Discharge: No SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment.