RUBIA TIR 7400 15W40 - Total

1 Quick-FDS [16613-38600-16921-015342] - 2013-06-25 - 10:43:20 MATERIAL SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006_____Page 1 / 12 SDS # : 30579 RUBIA TIR 7400 15W40 +33 1 49 00 00 49 (24h/24, 7d/7)France - ORFILA (INRS) T l : +33 (0)1 45 42 59 59In France : - PARIS : H pital Fernand Widal 200, rue du Faubourg Saint-Denis 75475 Paris C dex 10 , Tel : -MARSEILLE : Hopital Salvator, 249 bd Ste Marguerite 13274 Marseille cedex 5, Tel : - LYON : Hopital EdouardHerriot, 5 place d'Arsonvol, 69437 Lyon cedex 3, Tel : - NANCY : Hopital central, 29 Av du Mal De Lattre deTassigny, 54000 Nancy, Tel : ou le SAMU : Tel ( 15 )SupplierTOTAL LUBRIFIANTS562 Avenue du Parc de L'ile92029 Nanterre CedexT l: +33 (0)1 41 35 40 00 Fax: +33 (0)1 41 35 84 71 Product nameRUBIA TIR 7400 15W402. HAZARDS Relevant identified uses of the substance or mixture and uses advised Product identifierFor further information, please Classification of the substance or mixtureNumberREGULATION (EC) No 1272/200813 TContact PointFor the full text of the H-Statements mentioned in this Section, see Section usesMotor 67/548/EEC or 1999/45/ECFor the full text of the R-phrases mentioned in this Section, see Section Emergency telephone numberPure Details of the supplier of the safety data sheet1.

2 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGV ersion EUVersion 3 Revision Date: 2012-06-01 Date of the previous version: 2008-11-20 Quick-FDS [16613-38600-16921-015342] - 2013-06-25 - 10:43:20 _____Revision Date: 2012-06-01 RUBIA TIR 7400 15W40 Version 3 Page 2 / 12 SDS # : 30579 Directive 1999/45/ECEnvironmental propertiesShould not be released into the substance/mixture is non-dangerous in accordance with Directive(s) 67/548/EEC with amendments and/or 1999/45/EC withamendments3. COMPOSITION/INFORMATION ON INGREDIENTSR-phrase(s) Label elementsS-phrase(s) noneChemical NameEC-NoREACH registrationNoCAS-NoWeight %Classification ( )Classification ( )Polyolefin polyaminesuccinimide, polyol-no data available^<5R53 Contains Calcium long chain alkarylsulphonate . May produce an allergic alkyldithiophosphate272-028-3no data available68649-42-3< ;R41N;R51-53 Symbol(s) Not ClassifiedCalcium long chainalkarylsulphonate-no data available^< data sheet available on informationProduct containing mineral oil with less than 3% DMSO extract as measured by IP Other hazardsLabelled according toPhysical-Chemical PropertiesContaminated surfaces will be extremely EUQuick-FDS [16613-38600-16921-015342] - 2013-06-25 - 10:43:20 _____Page 3 / 12 SDS # : 30579 Revision Date: 2012-06-01 RUBIA TIR 7400 15W40 Version Description of first-aid measuresIngestionDo NOT induce vomiting.

3 Never give anything by mouth to an unconscious person. Call aphysician or Poison Control Center Indication of immediate medical attention and special treatment needed, if necessaryRinse thoroughly with plenty of water, also under the FIRST AID MEASURESFor the full text of the R-phrases mentioned in this Section, see Section 16 Notes to physicianTreat Most important symptoms and effects, both acute and delayed5. FIRE-FIGHTING MEASURESSkin contactEye contactNot Extinguishing mediaRemove contaminated clothing and shoes. Wash off with soap and water. Washcontaminated clothing before adviceSuitable Extinguishing MediaCarbon dioxide (CO2). ABC powder. Foam. Water spray or contactNot classified. May produce an allergic CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OREMERGENCY MEDICAL Extinguishing MediaDo not use a solid water stream as it may scatter and spread fireInhalationMove to fresh Special hazards arising from the substance or mixtureInhalationNot classified.

4 Inhalation of vapors in high concentration may cause irritation of the full text of the H-Statements mentioned in this Section, see Section EUIngestionNot classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting [16613-38600-16921-015342] - 2013-06-25 - 10:43:20 _____Page 4 / 12 SDS # : 30579 Revision Date: 2012-06-01 RUBIA TIR 7400 15W40 Version 3Do not touch or walk through spilled material. Contaminated surfaces will be extremelyslippery. Use personal protective equipment. Ensure adequate ventilation. Remove allsources of Reference to other sectionsSpecial protective equipment forfire-fightersWear self-contained breathing apparatus and protective suitPersonal Protective EquipmentSee Section 8 for more Environmental precautions6. ACCIDENTAL RELEASE Advice for fire-fightersWaste treatmentSee section 13 Special HazardGeneral InformationDo not allow material to contaminate ground water system.

5 Try to prevent the material fromentering drains or water courses. Local authorities should be advised if significant spillagescannot be HANDLING AND Precautions for safe Personal precautions, protective equipment and emergency Methods and materials for containment and cleaning upOther informationCool containers / tanks with water spray. Fire residues and contaminated fire extinguishingwater must be disposed of in accordance with local EUMethods for cleaning upDam up. Contain spillage, and then collect with non-combustible absorbent material, ( , earth, diatomaceous earth, vermiculite) and place in container for disposal accordingto local / national regulations (see section 13). Keep in suitable, closed containers combustion and thermolysis may produce gases of varying toxicity such ascarbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These maybe highly dangerous if inhaled in confined spaces or at high InformationQuick-FDS [16613-38600-16921-015342] - 2013-06-25 - 10:43:20 _____Page 5 / 12 SDS # : 30579 Revision Date: 2012-06-01 RUBIA TIR 7400 15W40 Version 3 When using, do not eat, drink or smoke.

6 For personal protection see section 8. Use only inwell-ventilated areas. Do not breathe vapors or spray mist. Avoid contact with skin, eyesand of fire and explosionLegendSee section Conditions for safe storage, including any Specific end usesHygiene measuresEnsure the application of strict rules of hygiene by the personnel exposed to the risk ofcontact with the product. Regular cleaning of equipment, work area and clothing isrecommended. Wash hands before breaks and immediately after handling the product. Donot use abrasives, solvents or fuels. Do not dry hands with rags that have beencontaminated with product. Do not put product contaminated rags into workwear precautionary measures against static discharges. Ground/bond containers, tanksand transfer/receiving EXPOSURE CONTROLS/PERSONAL PROTECTIONT echnical measures/StorageconditionsKeep away from food, drink and animal feedingstuffs.

7 Keep in a bunded area. Keepcontainer tightly closed. Keep preferably in the original container. Otherwise reproduce allindication of the regulation label on the new container. Do not remove the hazard labels ofthe containers (even if they are empty). Design the installations in order to avoid accidentalemissions of product (due to seal breakage, for example) onto hot casings or electricalcontacts. Protect from frost, heat and sunlight. Protect from Exposure Control parametersAdvice on safe handlingOccupational Exposure ControlsExposure limitsoil mist : 10mg/m3, for 15 minutesoil mist : 5mg/m3, for 8 hoursMaterials to AvoidVersion EUStrong oxidizing [16613-38600-16921-015342] - 2013-06-25 - 10:43:20 _____Page 6 / 12 SDS # : 30579 Revision Date: 2012-06-01 RUBIA TIR 7400 15W40 Version 3 When workers are facing concentrations above the exposure limit they must useappropriate certified respirators.

8 Respirator with combination filter for vapour/particulate(EN 141). The use of breathing apparatus must comply strictly with the manufacturer'sinstructions and the regulations governing their choices and ProtectionColorbrownHydrocarbon-proof gloves, Nitrile rubber, Fluorinated rubber. Please observe theinstructions regarding permeability and breakthrough time which are provided by thesupplier of the gloves. Also take into consideration the specific local conditions under whichthe product is used, such as the danger of cuts, abrasion. If used in solution, or mixed withother substances, and under conditions which differ from EN 374, contact the supplier ofthe EC approved InformationPhysical State @20 CliquidOdorNo information availableIf the product is used in mixtures, it is recommended that you contact the appropriateprotective equipment suppliers. These recommendations apply to the product as technical measures to comply with the occupational exposure limits.

9 When workingin confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable forbreathing and wear the recommended ProtectionEnvironmental exposure controlsIf splashes are likely to occur, wear:. Safety glasses with Protective EquipmentGeneral InformationThe product should not be allowed to enter drains, water courses or the soilEngineering Measures9. PHYSICAL AND CHEMICAL PROPERTIESSkin and body protectionWear suitable protective clothing. Protective shoes or boots. Long sleeved Information on basic physical and chemical propertiesRespiratory protectionEvaporation rateMethodCleveland Open Cup (COC)No information availablepHFlash pointValues450 FPropertyNot applicable232 CVersion EUNot applicableBoiling point/boiling rangeCleveland Open Cup (COC).RemarksQuick-FDS [16613-38600-16921-015342] - 2013-06-25 - 10:43:20 _____SDS # : 30579 Revision Date: 2012-06-01 RUBIA TIR 7400 15W40 Version 3 Page 7 / Chemical stabilityStabilityStable under recommended storage Possibility of hazardous reactionsHazardous ReactionsNone under normal Conditions to AvoidConditions to AvoidHeat (temperatures above flash point), sparks, ignition points, flames, static Incompatible MaterialsMaterials to AvoidStrong oxidizing Hazardous Decomposition Other informationHazardous Decomposition ProductsNone under normal use10.

10 STABILITY AND REACTIVITYNot applicableNo information availableAutoignition temperatureWater solubility14 mm2/sDensitySoluble in many commonorganic solvents@ 100 CISO 3104No information available889 kg/m3 InsolublelogPowNo information availableViscosity, kinematic@ 15 C101 mm2/sFlammability Limits in AirExplosive propertiesNot explosive@ 40 CNo information availableSolubility in other solventsOxidizing PropertiesNot applicableISO 3104 Vapor densityVersion EUVapor PressureNo information availablePossibility of hazardous reactionsQuick-FDS [16613-38600-16921-015342] - 2013-06-25 - 10:43:20 _____Page 8 / 12 SDS # : 30579 Revision Date: 2012-06-01 RUBIA TIR 7400 15W40 Version 3 Acute toxicity Component InformationMutagenicityThis product is not classified as contactNot toxicityThis product does not contain any known or suspected reproductive Dose ToxicitySensitizationSubchronic toxicityNo information classified.