Safety Data Sheet - ADACOLOR

1 International Paint Ltd. Safety data Sheet PHA046 INTERTHANE 990 PART BVersion No. 3 Date Last Revised 04/12/11 Conforms to the requirements of Regulation (EC) (REACH), Annex II and Regulation (EC) 1: Identification of the substance/mixture and of the company/undertaking Product identifier INTERTHANE 990 PART B Product CodePHA046 Registration Number Relevant identified uses of the substance or mixture and uses advised against Intended useSee Technical data Sheet . Application MethodSee Technical data Sheet . Details of the supplier of the Safety data sheetManufacturerInternational Paint Ltd. Stoneygate Lane Felling Gateshead Tyne and Wear NE10 0JY UK Telephone No.+44 (0)191 469 6111 Fax No.+44 (0)191 438 3711 Emergency telephone numberManufacturer+44 (0)191 469 6111 24hr Official Advisory Body Telephone No.: Advice for Doctors and Hospitals +44 (0)844 892 0111 SECTION 2: Hazards identification Classification of the substance or mixtureMixture NOT yet classified according to Regulation (EC) No.

2 1272/2008 Classification according to 67/548/EEC or 1999/45 for the cause sensitization by inhalation and skin to aquatic organisms, may cause long-term adverse effects in the aquatic Label elementsPage 1 of 10 According to 1999/45/EC Harmful Dangerous for the environment Contains:Hdi homopolymer, R10 May cause sensitization by inhalation and skin Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic Do not breathe Avoid contact with Wear suitable gloves and eye/face During spraying wear suitable respiratory In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).S51 Use only in well-ventilated Phrases;Contains isocyanates. See information supplied by the manufacturer. Other hazardsThis product contains no PBT/vPvB 3: Composition/information on ingredients If the product contains substances that present a health hazard within the meaning of the Dangerous Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances are listed DesignationsWeight %67/548/EEC ClassificationEC No.

3 1272/2008 ClassificationNotesHdi homopolymer CAS Number: 0028182-81-2 EC No. 500-060-2 Index No.: REACH Reg. No.: 01-2119485796-17-xxxx 50 - 100Xn; R42/43 Skin Sens. 1;H317 Resp. Sens. 1;H334 [1]Solvent naphtha (petroleum), light aromatic CAS Number: 0064742-95-6 EC No. 265-199-0 Index No.: 649-356-00-4 REACH Reg. No.: 10 - < 25Xn;R65 Asp. Tox. 1;H304H; P [1]1,2,4-trimethylbenzene CAS Number: 0000095-63-6 EC No. 202-436-9 Index No.: 601-043-00-3 REACH Reg. No.: - < 10R10 Xn;R20 Xi;R36/37/38 N;R51-53 Flam. Liq. 3;H226 Acute Tox. 4;H332 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Aquatic Chronic 2;H411 [1][2]1,3,5-trimethylbenzene CAS Number: 0000108-67-8 EC No. 203-604-4 Index No.: 601-025-00-5 REACH Reg. No.: 1 - < Xi;R37 N;R51-53 Flam. Liq. 3;H226 STOT SE 3;H335 Aquatic Chronic 2;H411 [1]Page 2 of 10 Hexamethylene-1,6-diisocyanate CAS Number: 0000822-06-0 EC No.

4 212-485-8 Index No.: 615-011-00-1 REACH Reg. No.: 0 - < 1T;R23 R42/43 Xi;R36/37/38 Acute Tox. 3;H331 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Resp. Sens. 1;H334 Skin Sens. 1;H3172 [1][2][1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vPvB-substance. *The full texts of the phrases are shown in Section 4: First aid measures Description of first aid measuresGeneralIn all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin cleanser. Do NOT use solvents or copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical accidentally swallowed obtain immediate medical attention.

5 Keep at rest. Do NOT induce Most important symptoms and effects, both acute and delayedNo data Indication of any immediate medical attention and special treatment neededNo data availableSECTION 5: Fire-fighting measures Extinguishing mediaRecommended extinguishing media; alcohol resistant foam, CO2. powder, water spray. Do not use; water Special hazards arising from the substance or mixtureFire will produce dense black smoke. Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen. Avoid exposure and use breathing apparatus as Advice for fire-fightersCool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter drains or water 6: Accidental release measures Page 3 of 10 Personal precautions, protective equipment and emergency proceduresRemove sources of ignition, do not turn lights or unprotected electrical equipment on or off.

6 In case of a major spill or spillage in a confined space evacuate the area and check that solvent vapour levels are below the Lower Explosive Limit before Environmental precautionsDo not allow spills to enter drains or Methods and material for containment and cleaning upVentilate the area and avoid breathing vapours. Take the personal protective measures listed in section 8. Contain and absorb spillage with non-combustible materials sand, earth, vermiculite. Place in a suitable container. The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises (by volume): water (45 parts), ethanol or isopropyl alcohol (50 parts), concentrated (d:0,880) ammonia solution (5 parts). A non-flammable alternative is sodium carbonate (5 parts), water (95 parts). Add the same decontaminant to any residues and allow to stand for several days in a non-sealed container until no further reaction occurs. Once this stage is reached, close container and dispose of in accordance with the waste regulations (see section 13).

7 Do not allow spills to enter drains or drains or sewers are contaminated, inform the local water company immediately. In the case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be 7: Handling and storage Precautions for safe handlingHandlingPersons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this preparation is used. Examination of lung function should be carried out on a regular basis on persons spraying this preparation. In StorageHandle containers carefully to prevent damage and flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks and electrical equipment are protected to the appropriate should be taken to minimise exposure to atmospheric humidity or water as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used Conditions for safe storage, including any incompatibilitiesKeep away from the following materials: oxidising agents, strong alkalis, strong skin and eye contact.

8 Avoid inhalation of vapours and spray mists. Observe label precautions. Use personal protection as shown in section 8. Smoking, eating and drinking should be prohibited in all preparation and application areas. Never use pressure to empty a container; containers are not pressure in a well ventilated, dry place away from sources of heat and direct sunlight. Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack more than 3 pallets high. Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in the original container or one of the same material. Prevent unauthorised Specific end use(s)Page 4 of 10 There are no exposure scenarios, see details in section 8: Exposure controls/personal protection Control parametersThe following workplace exposure limits have been established by the Health and Safety Executive as published in term (15 min.)

9 Ave) Long term (8hr TWA)Comments ppmmg/m3ppmmg/m3 1,2,4-trimethylbenzene 25 125 1,3,5-trimethylbenzene 25 125 Hexamethylene-1,6-diisocyanate- - (as-NCO) S For Key to entries in 'Comments' column see Section 16 DNEL/PNEC valuesNo data Exposure controlsProvide adequate ventilation. This should be achieved by the use of local exhaust ventilation and good general extraction. Air-fed protective respiratory equipment must be worn by spray operators even when good ventilation is provided . In other operations, if local exhaust ventilation and good general extraction are not sufficient to maintain concentrations of particulates and solvent vapour below the WEL, suitable respiratory protection must be worn.

10 (See Personal Protection) Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this preparation is used. Examination of lung function should be carried out on a regular basis on persons spraying this protectionWear Safety eyewear, Safety spectacles, goggles or visors to protect against the splash of liquids. Eyewear should meet the requirements of standard EN protectionFor prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed areas of skin, they should however not be applied once exposure has occurred. Skin should be washed after contact. Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and micro-organisms. Recommended gloves: Viton or Nitrile Breakthrough Time: 480 min When prolonged or frequently repeated contact may occur, a glove with a protection class of 6 (breakthrough time greater than 480 minutes according to EN 374) is recommended.