SAFETY DATA SHEET BARTOLINE - Methylated Spirits

1 Revision date: 11/05/2018 Revision: 3 Supersedes date: 06/06/2017 SAFETY data SHEETBARTOLINE - Methylated SpiritsAccording to Regulation (EC) No 1907/2006 Annex II as amended by Regulation (EU) 2015 1: Identification of the substance/mixture and of the Product identifierProduct nameBARTOLINE - Methylated SpiritsREACH registration notesNo REACH registration number required as this product is a Relevant identified uses of the substance or mixture and uses advised againstIdentified usesFuel for camping stoves and fondues. Glass advised againstNot to be used for cleaning skin as this may lead to skin Details of the supplier of the SAFETY data sheetSupplierBartoline LimitedBarmston CloseBeverleyEast YorkshireHU17 0LW01482 personProduct Compliance Emergency telephone numberEmergency telephone01482 678710 ( - Monday to Friday) or NHS 111 (General Public) (24 Hourservice)National emergency telephonenumberNational Poisons Information Service (24hours) 0844 892 0111 SECTION 2: Hazards Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazardsFlam.

2 Liq. 2 - H225 Health hazardsNot ClassifiedEnvironmental hazardsNot ClassifiedPhysicochemicalHighly Label elementsPictogramSignal wordDanger1/19 Revision date: 11/05/2018 Revision: 3 Supersedes date: 06/06/2017 BARTOLINE - Methylated SpiritsHazard statementsH225 Highly flammable liquid and statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Keep container tightly Take action to prevent static Wear protective gloves/ protective clothing/ eye protection/ face +P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated skin with water or +P235 Store in a well-ventilated place. Keep Keep out of reach of If medical advice is needed, have product container or label at Dispose of contents/container to hazardous waste collection labelinformationTO AVOID THE RISK OF SPILLAGE ALWAYS ENSURE THE LID IS SECURE AND THECONTAINER IS SECURED UPRIGHT DURING TRANSPORTATION AND Other hazardsSECTION 3: Composition/information on Mixturesethanol>=90%CAS number: 64-17-5EC number: 200-578-6 REACH registration number: 01-2119457610-43-XXXXC lassificationFlam.

3 Liq. 2 - H225propan-2-ol 1<5%CAS number: 67-63-0EC number: 200-661-7 ClassificationFlam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336butanone 1<5%CAS number: 78-93-3EC number: 201-159-0 REACH registration number: 01-2119457290-43-XXXXC lassificationFlam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section commentsThis product complies with the Denatured Alcohol Regulations date: 11/05/2018 Revision: 3 Supersedes date: 06/06/2017 BARTOLINE - Methylated SpiritsSECTION 4: First aid Description of first aid measuresGeneral informationIN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR THE NHS111 SERVICE. Move affected person to fresh air and keep warm and at rest in a positioncomfortable for breathing. Keep affected person away from heat, sparks and flames. Whenbreathing is difficult, properly trained personnel may assist affected person by administeringoxygen.

4 Never give anything by mouth to an unconscious person. Treat affected person to fresh air and keep warm and at rest in a position comfortable forbreathing. Place unconscious person on their side in the recovery position and ensurebreathing can take place. It may be dangerous for first aid personnel to carry out mouth-to-mouth resuscitation. When breathing is difficult, properly trained personnel may assistaffected person by administering oxygen. Get medical attention if any discomfort mouth thoroughly with water. Promptly get affected person to drink large volumes ofwater to dilute the swallowed chemical. Get medical contactRemove contamination with soap and water or recognised skin cleansing agent. Do not useorganic solvents. Remove contaminated clothing immediately and wash skin with soap andwater. Get medical attention if symptoms are severe or persist after contactRinse immediately with plenty of water.

5 Remove contact lenses, if present and easy to rinsing. Continue to rinse for at least 15 minutes and get medical of first aidersFirst aid personnel should wear appropriate protective equipment during any rescue. It maybe dangerous for first aid personnel to carry out mouth-to-mouth resuscitation. Washcontaminated clothing thoroughly with water before removing it from the affected person, orwear Most important symptoms and effects, both acute and delayedGeneral informationThe severity of the symptoms described will vary dependent on the concentration and thelength of exposure. Treat cause respiratory irritation. Vapours inhaled in strong concentration have a narcotic effecton the central nervous system. Irritation of the respiratory tract due to excessive fume, causesheadache, drowsiness or other effects to the central nervous system, loss of cause nausea, headache, dizziness and intoxication. Ingestion of large amounts maycause contactProlonged or repeated contact may cause irritation and dry contactThis product is moderately irritating.

6 Irritation and redness, followed by blurred Indication of any immediate medical attention and special treatment neededNotes for the doctorTreat treatmentsNo specific chemical antidote is known to be required after exposure to this 5: Firefighting Extinguishing mediaSuitable extinguishing mediaExtinguish with alcohol-resistant foam, carbon dioxide, dry powder or water extinguishingmediaDo not use water jet as an extinguisher, as this will spread the date: 11/05/2018 Revision: 3 Supersedes date: 06/06/2017 BARTOLINE - Methylated Special hazards arising from the substance or mixtureSpecific hazardsThe product is highly flammable. Severe explosion hazard when vapours are exposed toflames. Vapours may be ignited by a spark, a hot surface or an ember. May form explosivemixture with air at very high concentration. Vapours are heavier than air and may spread nearground and travel a considerable distance to a source of ignition and flash back.

7 Vapours areheavier than air and may travel along the floor and accumulate in the bottom of of re-ignition after fire has been extinguished. Containers can burst violently or explodewhen heated, due to excessive pressure build-up. Fire-water run-off in sewers may create fireor explosion combustionproductsIncomplete combustion and thermolysis may produce gases of varying toxicity such as carbonmonoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may be highlydangerous if inhaled in confined spaces or at high Advice for firefightersProtective actions duringfirefightingAvoid breathing fire vapours. Cool containers exposed to flames with water until well after thefire is out. Keep run-off water out of sewers and water sources. Dike for water close to fire should be removed or cooled with protective equipmentfor firefightersIn case of a large fire or in confined or poorly ventilated spaces, wear full fire resistantprotective clothing and self-contained breathing apparatus (SCBA) with a full face-pieceoperated in positive pressure 6: Accidental release Personal precautions, protective equipment and emergency proceduresPersonal precautionsKeep unnecessary and unprotected personnel away from the spillage.

8 No smoking, sparks,flames or other sources of ignition near spillage. Do not touch or walk into spilled material. Donot enter storage areas or confined spaces unless adequately ventilated. Wear protectiveclothing as described in Section 8 of this SAFETY data SHEET . Treat the spilled materialaccording to the instructions in the clean-up emergency respondersWear protective clothing as described in Section 8 of this SAFETY data SHEET . See section 11 foradditional information on health waste disposal, see section Environmental precautionsEnvironmental precautionsThe product contains a substance which may cause long-term adverse effects in the aquaticenvironment. The product contains substances which are water-soluble and may spread inwater systems. The product is biodegradable but it must not be discharged into drains withoutpermission from the authorities. Volatile substances are degraded in the atmosphere within afew days.

9 Avoid the spillage or runoff entering drains, sewers or watercourses. To preventrelease, place container with damaged side up. Spillages or uncontrolled discharges intowatercourses must be reported immediately to the Environmental Agency or other appropriateregulatory Methods and material for containment and cleaning up4/19 Revision date: 11/05/2018 Revision: 3 Supersedes date: 06/06/2017 BARTOLINE - Methylated SpiritsMethods for cleaning upStop leak if safe to do so. Eliminate all ignition sources if safe to do so. No smoking, sparks,flames or other sources of ignition near spillage. To prevent release, place container withdamaged side up. Do not touch or walk into spilled material. Cover large spillages withalcohol-resistant foam. Allow small quantities to evaporate to the atmosphere in a safe, openplace. Large Spillages: Contain spillage with sand, earth or other suitable non-combustiblematerial. Absorb in vermiculite, dry sand or earth and place into containers.

10 Containers withcollected spillage must be properly labelled with correct contents and hazard symbol. Waste,residues, empty containers, discarded work clothes and contaminated cleaning materialsshould be collected in designated containers, labelled with their contents. Dispose of waste tolicensed waste disposal site in accordance with the requirements of the local Waste DisposalAuthority. For waste disposal, see Section 13. Wash thoroughly after dealing with a Reference to other sectionsReference to other sectionsFor personal protection, see Section 8. For waste disposal, see Section 13. See Section 11for additional information on health hazards. See Section 12 for additional information onecological 7: Handling and Precautions for safe handlingUsage precautionsAvoid contact with skin and eyes. Keep away from heat, sparks and open flame. Eliminate allsources of ignition. Use explosion proof electric equipment.