Safety Data Sheet CALCIUM CHLORIDE BRINE - IGas …

1 Safety Data SheetCALCIUM CHLORIDE BRINES afety data Sheet number MI10030 Version 7 Revision date 21/Apr/ 2014 Supercedes date 01/Feb/20111. Identification of the substance/preparation and of the Product identifier Product nameCALCIUM CHLORIDE BRINEP roduct codeMI10030 Norway Pr. no. 120037 Denmark Pr. no. Relevant identified uses of the substance or mixture and uses advised against Recommended useCompletion BRINE Drilling fluid additiveUses advised againstNone Details of the supplier of the Safety data Sheet Emergency Telephone Number Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600 NetherlandsNational Poisons Information Center (NL): +31 30 274 88 88 (NB: this service is onlyavailable to health professionals)NorwayPoison information centre: +47 22 59 13 002.

2 Hazards Classification of the substance or mixture Regulation (EC) No. 1272/2008 Health hazardsSerious eye damage/eye irritationCategory 2 Environmental hazardsNot classified_____Physical HazardsNot Label Elements Supplier identificationM-I Drilling Fluids UK LimitedC/O SchlumbergerEnterprise DriveWesthill Industrial EstateWesthill, AB32 6 TQScotland UK+47 51577424 Page 1 / CHLORIDE BRINES afety data Sheet number MI10030 Revision date 21/Apr/ 2014 Signal wordWARNINGH azard statementsH319 - Causes serious eye irritationPrecautionary Statements - EU ( 28, 1272/2008) P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/ protective clothing/ eye protection/ face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/ attention The substance/preparation is classified as dangerous in accordance with Directive(s) 67/548/EEC with amendments and/or1999/45/EC with amendmentsIndication of dangerXi - IrritantR-code(s)R36 ContainsCalcium chlorideFor the full text of the H-Statements mentioned in this Section, see Section Other data Not classified as PBT/vPvB by current EU criteria_____3.

3 Composition/information on Substances Mixtures Page 2 / 12_____CALCIUM CHLORIDE BRINES afety data Sheet number MI10030 Revision date 21/ % -rangeClassification(67/548)Classificati on ( )REACH registrationnumberCalcium chloride233-140-810043-52-430-60%Xi; R36 Eye Irrit. 2 (H319)01-2119494219-28-xxxxCommentThe product contains other ingredients which do not contribute to the overall First aid Description of first-aid measures InhalationIf inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation contactWash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention immediately if symptoms contactRemove contact lenses. Promptly wash eyes with lots of water while lifting eye to rinse for at least 15 minutes.

4 Get medical attention if any discomfort Most important symptoms and effects, both acute and delayed General adviceThe severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as symptomsInhalationPlease see Section 11. Toxicological Information for further see Section 11. Toxicological Information for further contactPlease see Section 11. Toxicological Information for further contactPlease see Section 11. Toxicological Information for further Indication of any immediate medical attention and special treatment needed Notes to physicianTreat Fire-fighting Extinguishing media Page 3 / 12 Suitable extinguishing mediaUse extinguishing media appropriate for surrounding CHLORIDE BRINES afety data Sheet number MI10030 Revision date 21/Apr/ 2014 Extinguishing media which shall not be used for Safety reasonsNone Special hazards arising from the substance or mixture Precautions against fire and explosionNone combustion productsFire or high temperatures create.

5 , Chlorine, chlorine oxides, hydrogen Advice for firefighters Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with Accidental release Personal precautions, protective equipment and emergency procedures Use personal protective equipment. See also section Environmental precautions The product should not be allowed to enter drains, water courses or the exposure controlsAvoid release to the Methods and materials for containment and cleaning up Methods for ContainmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later for cleaning upAbsorb with earth, sand or other non-combustable material and transfer to containers for later disposal. After cleaning, flush awaytraces with Reference to other sections See section 13 for more Handling and Precautions for safe handling Page 4 / 12 HandlingAvoid contact with skin and eyes.

6 Do not breathe vapors or spray mist. Avoid spills and splashing during CHLORIDE BRINES afety data Sheet number MI10030 Revision date 21/Apr/ 2014 Hygiene measuresHandle in accordance with good industrial hygiene and Safety practice. When using do not smoke, eat or drink. Wash hands andface before breaks and immediately after handling the Conditions for safe storage, including any incompatibilities Technical measures/precautionsEnsure adequate ventilation. Keep airborne concentrations below exposure containers tightly closed in a dry, cool and well-ventilated classChemical materialUse specially constructed containers onlyPackaging materials to be Specific end uses See also Section Exposure Controls/Personal Control parameters Exposure limitsComponentEU OEL - Third ListAustriaAustraliaDenmarkCalcium chlorideNot determinedNot determinedNot determinedNot determinedComponentFinlandFranceGermanyH ungaryCalcium chlorideNot determinedNot determinedNot determinedNot determinedComponentIrelandItalyNetherlan dsNorwayCalcium chlorideNot determinedNot determinedNot determinedNot determinedComponentPolandPortugalRomania RussiaCalcium chlorideNot determinedNot determinedNot determined2 mg/m MAC (aerosol)

7 ComponentSpainSwitzerlandTurkeyUKCalcium chlorideNot determinedNot determinedNot determinedNot determined_____ComponentACGIH TLVTWA / CCalcium chlorideNot DeterminedNot DeterminedDerived No Effect Level (DNEL)Page 5 / 12 Short term exposure local effects_____CALCIUM CHLORIDE BRINES afety data Sheet number MI10030 Revision date 21/Apr/ 2014 CALCIUM chlorideInhalation10 mg/m Long term exposure local effectsCalcium chlorideInhalation5 mg/m Exposure controls All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each measures toreduce exposureEnsure adequate protective equipmentEye protectionIt is good practice to wear goggles when handling any chemical.

8 Tightly fitting protectionUse protective gloves made of:, Neoprene, Nitrile, PVC disposable gloves, Be aware thatliquid may penetrate the gloves. Frequent change is protectionNo personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Chemical respirator with inorganic vapourcartridge (Grey B).Skin and body protectionWear suitable protective clothing, Provide eyewash measuresWash hands before eating, drinking or smoking, Remove and wash contaminated clothingbefore Physical and Chemical Information on basic physical and chemical properties AppearanceclearOdourOdourlessColourColou rlessOdor thresholdNot applicablePhysical stateLiquidProperty Values Remarks pH - @ dilutionMelting/freezing point-14 C / 7 FBoiling point/range> 100 C / >212 FFlash PointPage 6 / 12No information available_____CALCIUM CHLORIDE BRINES afety data Sheet number MI10030 Revision date 21/Apr/ 2014 Explosive propertiesNot ApplicableOxidizing propertiesNone Other information Pour pointNo information availableMolecular weightNo information availableVOC content(%)NoneDensity VALUENo information available10.

9 Stability and Reactivity No specific reactivity hazards associated with this Chemical stability Stable under normal temperature conditions and recommended Possibility of Hazardous Reactions Hazardous polymerizationHazardous polymerisation does not Conditions to avoid None Incompatible materials Hazardous decomposition products See also section ratenot applicableFlammability (solid, gas)Not ApplicableFlammability Limits in AirNot applicableUpper flammability LimitNot applicableLower flammability limitNot applicableVapor pressure9 mmHg@ 20 CVapor densityNo information availableSpecific - @ 20 CBulk densityNo information availableRelative densityNo information availableWater solubilitySoluble in waterSolubility in other solventsNo information availableAutoignition temperatureNo information available_____Decomposition temperatureNo information availableKinematic viscosityViscosity, dynamicNo information availableLog PowPage 7 / 12 Not determined_____CALCIUM CHLORIDE BRINES afety data Sheet number MI10030 Revision date 21/Apr/201411.

10 Toxicological Information on toxicological effects Acute toxicityInhalationInhalation of vapours in high concentration may cause irritation of respiratory contactCauses serious eye contactProlonged contact may cause redness and may cause stomach OralLD50 DermalLD50 InhalationCalcium CHLORIDE = 1000 mg/kg ( Rat )= 2630 mg/kg ( Rat )No data availableSensitisationThis product does not contain any components suspected to be effectsThis substance has no evidence of mutagenic substance has no evidence of carcinogenic toxicityNone of exposureEye of entryEye target organ toxicity (singleexposure)Not classifiedSpecific target organ toxicity(repeated exposure)Not hazardNo hazard from product as Ecological Toxicity Ecotoxicity effectsListed on PLONOR list of OSPAR. The product components are not classified as environmentally hazardous. However, this doesnot exclude the possibility that large or frequent spills can have a harmful or damaging effect on the 8 / 12 Toxicity to algaeNot determined.