Safety Data Sheet - DP SURVEY GROUP

1 Please do not use this e-mail adress to ask for the latest Safety data Sheet . For this purpose contactItochu Deutschland GmbH. As above or next toxicological information 1: Identification of the substance/mixture and of the identifierTrade nameDuranate TKA-100 Registration number (REACH)01-2119485796-17-XXXXEC number500-060-2931-274-8 CAS identified uses of the substance or mixture and uses advised againstRelevant identified usesHardening agent / Curing agentPreparation of coatingsPreparation of adhesivesE-mail address of competent personresponsible for the of the supplier of the Safety data sheetItochu Deutschland GmbHAm Seestern 18D-40547 D sseldorfGermanyTelephone: ++49 (0) 211 - 5290-0 Telefax.

2 ++49 (0) 211 - 59 64 telephone numberSECTION 2: Hazards of the substance or mixtureClassification according to Regulation (EC) No 1272/2008 (CLP)Classification acc. to GHSS ectionHazard classCategoryHazard class andcategoryHazard toxicity (inhal.)4 Acute Tox. sensitisation1 Skin Sens. 1H317 Safety data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH)bbbDuranate TKA-100 Version number: version of: 2014-08-17 (2)Revision: 2016-05-31 First version: Kingdom: enPage: 1 / 17for full text of abbreviations: see SECTION 16 There is no additional information.

3 According to the results of its assessment, this substance is not a PBT or a vPvB. Classification acc. to GHSS ectionHazard classCategoryHazard class andcategoryHazard target organ toxicity - single expos-ure (respiratory tract irritation)3 STOT SE elementsLabelling according to Regulation (EC) No 1272/2008 (CLP)Signal wordwarningPictogramsGHS07 Hazard statementsH317 May cause an allergic skin if cause respiratory statementsP333+P313If skin irritation or rash occurs: Get medical not breathe mist/ +P340IF INHALED: Remove person to fresh air and keep comfortable for [In case of inadequate ventilation] wear respiratory +P352IF ON SKIN.

4 Wash with plenty of soap and protective gloves/protective clothing/eye protection/face +P233 Store in a well-ventilated place. Keep container tightly hazard informationSupplemental hazard informationEUH204 Contains isocyanates. May produce an allergic hazardsResults of PBT and vPvB assessmentDuranate TKA-100 United Kingdom: enPage: 2 / 17for full text of H-phrases: see SECTION 16 Take off immediately all contaminated all cases of doubt, or when symptoms persist, seek medical advice. Provide fresh to mouth resuscitation should be avoided. Use alternative methods, preferably with oxygen orcompressed air driven breathing is irregular or stopped, immediately seek medical assistance and start first aid case of respiratory tract irritation, consult a physician.

5 After contact with skin, take off immediately all contaminated clothing, and wash immediately withplenty of water and skin irritation or rash occurs: Get medical contaminated clothing before reuse. SECTION 3: Composition/information on of substanceHDI oligomers, isocyanurateIdentifiersCAS No28182-81-2EC No500-060-2, 931-274-8 Purity100 %Impurities and additives, classification acc. to GHSName of substanceIdentifierWt%Classification acc. toGHSP ictogramsHexamethylene-di-isocyanateCAS No822-06-0EC No212-485-8< Tox. 4 / H302 Acute Tox. 1 / H330 Skin Irrit.

6 2 / H315 Eye Irrit. 2 / H319 Resp. Sens. 1 / H334 Skin Sens. 1 / H317 STOT SE 3 / H335 SECTION 4: First aid of first aid measuresGeneral notesFollowing inhalationFollowing skin contactDuranate TKA-100 United Kingdom: enPage: 3 / 17In case of contact with eyes, rinse immediately with plenty of water and seek medical contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do not induce swallowed, seek medical advice immediately and show this container or label. noneCough, pain, choking, and breathing difficulties. nonewater spray, alcohol resistant foam, fire extinguishing powder, carbon dioxide (CO2)water jetHazardous decomposition products: Section 10.

7 Nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2), hydrogen cyanide (HCN, prussicacid), isocyanate, pyrolysis products, toxicKeep containers cool with water case of fire and/or explosion do not breathe firefighting measures to the fire not allow firefighting water to enter drains or water contaminated firefighting water fire with normal precautions from a reasonable distance. wear self-contained breathing apparatusFollowing eye contactFollowing ingestionNotes for the important symptoms and effects, both acute and of any immediate medical attention and special treatment neededSECTION 5: Firefighting mediaSuitable extinguishing mediaUnsuitable extinguishing hazards arising from the substance or mixtureHazardous combustion for firefightersSpecial protective equipment for firefightersDuranate TKA-100 United Kingdom: enPage.

8 4 / 17 Remove persons to affected of ignition not breathe mist/ not get in eyes, on skin, or on of suitable protective equipment (including personal protective equipment referred to underSection 8 of the Safety data Sheet ) to prevent any contamination of skin, eyes and personal danger of slipping by leaking/spilling product. Wear breathing apparatus if exposed to vapours/dust/spray/gases. Keep away from drains, surface and ground contaminated washing water and dispose it. Collect material ( sand, diatomaceous earth, acid binder, universal binder, sawdust, etc.)

9 Clean with detergents. Use of adsorbent materials. Place in appropriate containers for affected area. Hazardous combustion products: see section protective equipment: see section materials: see section considerations: see section 13. SECTION 6: Accidental release precautions, protective equipment and emergency proceduresFor non-emergency personnelFor emergency and material for containment and cleaning upAdvices on how to clean up a spillAppropriate containment techniquesOther information relating to spills and to other sectionsDuranate TKA-100 United Kingdom: enPage: 5 / 17 Use local and general away from sources of ignition - No smoking.

10 None. Avoid release to the environment. Do not to eat, drink and smoke in work contaminated clothing and protective equipment before entering eating not breathe mist/ not get in eyes, on skin, or on hands after skin protection (barrier creams/ointments) is recommended. Incompatible materials: see section not allow contact with water. heat, humidityKeep away from food, drink and animal in a dry place. Store in a closed in a cool, well-ventilated place. Keep any substance that emits harmful vapours or gases in a place that allows these to be perman-ently of sufficient ventilation.