Transcription of SAFETY DATA SHEET ETHANOL ABSOLUTE
1 Revision date: 06/12/2017 Revision: 4 Supersedes date: 04/08/2016 SAFETY data SHEETETHANOL ABSOLUTEA ccording to Regulation (EC) No 1907/2006, Annex IISECTION 1: Identification of the substance/mixture and of the Product identifierProduct nameETHANOL ABSOLUTEP roduct number2123 REACH registration number01-2119457610-43-0000 CAS number64-17-5EU index number603-002-00-5EC Relevant identified uses of the substance or mixture and uses advised againstIdentified usesLaboratory reagent. Cleaning agent. Antifreeze advised againstNo specific uses advised against are Details of the supplier of the SAFETY data sheetSupplierReagent Chemical Services18 Aston Fields RoadWhitehouse Industrial EstateRuncornCheshire WA7 3 DLT: 01928 716903 ( - )F: 01928 716425E: Emergency telephone numberEmergency telephoneOHES Environmental Ltd 24-7 Tel. 0333 333 9939 (24 hour)SECTION 2: Hazards Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazardsFlam.
2 Liq. 2 - H225 Health hazardsNot ClassifiedEnvironmental hazardsNot Label elementsEC number200-578-61/11 Revision date: 06/12/2017 Revision: 4 Supersedes date: 04/08/2016 ETHANOL ABSOLUTEP ictogramSignal wordDangerHazard statementsH225 Highly flammable liquid and statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Keep container tightly Wear protective gloves/ protective clothing/ eye protection/ face Dispose of contents / container to hazardous waste precautionarystatementsP240 Ground/ bond container and receiving Use explosion-proof electrical/ ventilating /lighting/../ Use only non-sparking Take precautionary measures against static +P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated skin with water/ +P378 In case of fire: Use .. for +P235 Store in a well-ventilated place. Keep Other hazardsThis substance is not classified as PBT or vPvB according to current EU 3: Composition/information on SubstancesProduct nameETHANOL ABSOLUTEREACH registration number01-2119457610-43-0000EU index number603-002-00-5 CAS number64-17-5EC number200-578-6 SECTION 4: First aid Description of first aid measuresGeneral informationKeep affected person away from heat, sparks and affected person from source of contamination.
3 Move affected person to fresh air andkeep warm and at rest in a position comfortable for breathing. When breathing is difficult,properly trained personnel may assist affected person by administering oxygen. Get medicalattention if any discomfort affected person from source of contamination. Never give anything by mouth to anunconscious person. Rinse mouth thoroughly with water. Do not induce vomiting. If vomitingoccurs, the head should be kept low so that vomit does not enter the lungs. Get medicalattention if symptoms are severe or contactRemove affected person from source of contamination. Remove contaminated clothingimmediately and wash skin with soap and water. Get medical attention if irritation persistsafter date: 06/12/2017 Revision: 4 Supersedes date: 04/08/2016 ETHANOL ABSOLUTEEye contactRemove affected person from source of contamination. Rinse immediately with plenty ofwater. Remove contact lenses, if present and easy to do.
4 Continue rinsing. Get medicalattention if irritation persists after of first aidersFirst aid personnel should wear appropriate protective equipment during any Most important symptoms and effects, both acute and delayedGeneral informationThe severity of the symptoms described will vary dependent on the concentration and thelength of cause respiratory irritation. Coughing, chest tightness, feeling of chest cause nausea, headache, dizziness and intoxication. Pneumonia may be the result ifvomited material containing solvents reaches the contactLiquid may irritate skin. Dry contactRepeated exposure may cause chronic eye Indication of any immediate medical attention and special treatment neededNotes for the doctorHave facilities in place to wash skin and eyes in case of treatmentsTreat 5: Firefighting Extinguishing mediaSuitable extinguishing mediaSmall fires: Extinguish with alcohol-resistant foam, carbon dioxide or dry powder.
5 Large fires:Dry powder, foam or water extinguishingmediaDo not use water jet as this can spread the fire. Do not use carbon dioxide in enclosed spaceswith insufficient Special hazards arising from the substance or mixtureSpecific hazardsVapours are heavier than air and may spread near ground and travel a considerable distanceto a source of ignition and flash back. Vapours may form explosive mixtures with can burst violently or explode when heated, due to excessive pressure combustionproductsCarbon monoxide (CO). Carbon dioxide (CO2). Advice for firefightersProtective actions duringfirefightingFight fire with normal precautions from a reasonable distance. Keep upwind to avoidinhalation of gases, vapours, fumes and smoke. Cool containers exposed to heat with waterspray and remove them from the fire area if it can be done without risk. Do not use water jetas an extinguisher, as this will spread the fire.
6 Control run-off water by containing and keepingit out of sewers and protective equipmentfor firefightersWear positive-pressure self-contained breathing apparatus (SCBA) and appropriate 6: Accidental release Personal precautions, protective equipment and emergency proceduresPersonal precautionsWear protective clothing as described in Section 8 of this SAFETY data SHEET . No smoking,sparks, flames or other sources of ignition near spillage. Take precautionary measuresagainst static discharges. Evacuate area. Do not touch or walk into spilled emergency respondersWear protective clothing as described in Section 8 of this SAFETY data date: 06/12/2017 Revision: 4 Supersedes date: 04/08/2016 ETHANOL Environmental precautionsEnvironmental precautionsDo not discharge into drains or watercourses or onto the ground. Avoid the spillage or runoffentering drains, sewers or watercourses. To prevent release, place container with damagedside Methods and material for containment and cleaning upMethods for cleaning upWear protective clothing as described in Section 8 of this SAFETY data SHEET .
7 Eliminate allsources of ignition. Small Spillages: Absorb small quantities with paper towels and evaporatein a safe place. Large Spillages: Stop leak if safe to do so. Collect and place in suitable wastedisposal containers and seal securely. Contain and absorb spillage with sand, earth or othernon-combustible material. Containers with collected spillage must be properly labelled withcorrect contents and hazard symbol. Collect and dispose of spillage as indicated in Section13. Wash thoroughly after dealing with a Reference to other sectionsReference to other sectionsRefer to sections 8 and 13 for additional 7: Handling and Precautions for safe handlingUsage precautionsWear protective clothing as described in Section 8 of this SAFETY data SHEET . Keep away fromheat, sparks and open flame. Static electricity and formation of sparks must be contact with skin, eyes and clothing. Avoid inhalation of vapours.
8 Eye wash facilitiesand emergency shower must be available when handling this on generaloccupational hygieneDo not eat, drink or smoke when using this product. Wash at the end of each work shift andbefore eating, smoking and using the toilet. Remove contaminated clothing and wash the skinthoroughly with soap and water after Conditions for safe storage, including any incompatibilitiesStorage precautionsStore in tightly-closed, original container in a dry, cool and well-ventilated place. Keep awayfrom heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Earthcontainer and transfer equipment to eliminate sparks from static electricity. Keep away fromfood, drink and animal feeding stuffs. Store away from incompatible materials (see Section10).Storage classFlammable liquid Specific end use(s)Specific end use(s)The identified uses for this product are detailed in Section 8: Exposure Controls/personal Control parametersOccupational exposure limitsLong-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m vapourWEL = Workplace Exposure LimitDNELW orkers - Inhalation; Long term systemic effects: 950 mg/m Workers - Dermal; Long term systemic effects: 343 mg/kg/dayGeneral population - Inhalation; Long term systemic effects: 114 mg/m General population - Dermal; Long term systemic effects: 206 mg/kg/dayGeneral population - Oral; Long term systemic effects: 87 mg/kg/day4/11 Revision date: 06/12/2017 Revision: 4 Supersedes date: 04/08/2016 ETHANOL ABSOLUTEPNEC- Fresh water; mg/l- Marine water; mg/l- STP; 580 mg/l- Fresh water, Sediment; mg/kg- Marine water, Sediment; mg/kg- Soil.
9 Exposure controlsProtective equipment Appropriate engineeringcontrolsAs this product contains ingredients with exposure limits, process enclosures, local exhaustventilation or other engineering controls should be used to keep worker exposure below anystatutory or recommended limits, if use generates dust, fumes, gas, vapour or mist. Useexplosion-proof general and local exhaust protectionWear tight-fitting, chemical splash goggles or face shield. Personal protective equipment foreye and face protection should comply with European Standard protectionWear protective gloves. To protect hands from chemicals, gloves should comply withEuropean Standard EN374. Considering the data specified by the glove manufacturer, checkduring use that the gloves are retaining their protective properties and change them as soonas any deterioration is detected. The breakthrough time for any glove material may bedifferent for different glove manufacturers.
10 For exposure up to 8 hours, wear gloves made ofthe following material: Butyl rubber. Thickness: ~ mm Viton rubber (fluoro rubber).Thickness: ~ mmOther skin and bodyprotectionWear anti-static protective clothing if there is a risk of ignition from static electricity. Wearappropriate clothing to prevent any possibility of liquid contact and repeated or prolongedvapour contact. Wear suitable protective clothing made of the following material: Butyl rubber (fluoro rubber).Hygiene measuresGood personal hygiene procedures should be implemented. Wash at the end of each workshift and before eating, smoking and using the toilet. Remove contaminated clothing andwash the skin thoroughly with soap and water after work. Contaminated clothing should beplaced in a closed container for disposal or protectionRespiratory protection must be used if the airborne contamination exceeds the recommendedoccupational exposure limit.