Safety Data Sheet - Fisher Sci

1 Safety data Sheetaccording to 29 CFR1910/1200 and GHS Rev. 3 Effective date : 1 of 7 VinegarCreated by Global Safety Management, 1-813-435-5161 - 1 : Identification of the substance/mixture and of the supplierProduct name :VinegarManufacturer/Supplier Trade name:Manufacturer/Supplier Article number:S25623 Recommended uses of the product and restrictions on use:Manufacturer Details:AquaPhoenix Scientific, Inc9 Barnhart Drive, Hanover, PA 17331(717) 632-1291 Supplier Details: Fisher Science Education6771 Silver Crest Road, Nazareth, PA 18064(724)517-1954 Emergency telephone number: Fisher Science Education Emergency Telephone No.: 800-535-5053 SECTION 2 : Hazards identificationClassification of the substance or mixture:IrritantSkin irritation, category 2 Eye irritation, category 2 ASkin Irritation 2 Eye Irritation 2 Signal word :WarningHazard statements:Causes skin irritationCauses serious eye irritationPrecautionary statements:If medical advice is needed, have product container or label at handKeep out of reach of childrenRead label before useDo not eat, drink or smoke when using this productWear protective gloves/protective clothing/eye protection/face protectionWash skin thoroughly after handlingTake off contaminated clothing and wash before reuseIF ON SKIN: Wash with soap and waterIf skin irritation occurs: Get medical advice/attentionIF IN EYES: Rinse cautiously with water for several minutes.

2 Remove contact lenses if present and easy to do continue rinsingIf eye irritation persists get medical advice/attentionSpecific treatment (see supplemental first aid instructions on this label)Flammability:The mixture is being classified on the basis of the classification of the flammable ingredient at or equal to 50% Safety data Sheetaccording to 29 CFR1910/1200 and GHS Rev. 3 Effective date : 2 of 7 VinegarCreated by Global Safety Management, 1-813-435-5161 - (Source: CRC Handbook of Chemistry and Physics, 63rd Edition)Other Non-GHS Classification:WHMISB3 ENFPA/HMISNFPA SCALE (0-4)HMIS RATINGS (0-4)SECTION 3 : Composition/information on ingredientsIngredients:CAS 64-19-7 Acetic Acid5 %CAS 7732-18-5 Deionized Water95 %Percentages are by weightSECTION 4 : First aid measuresDescription of first aid measuresAfter inhalation: Move exposed individual to fresh air. Loosen clothing as necessary and position individual ina comfortable medical advice if discomfort or irritation artificial respiration ifnecessary.

3 If breathing persists give skin contact: Wash affected area with soap and water. Rinse thoroughly. Seek medical attention ifirritation, discomfort or vomiting with water for 15 eye contact: Protect unexposed eye. Rinse/flush exposed eye(s) gently using water for 15-20 contact lens(es) if able to do so during rinsing. Immediately get medical assistance if irritation persistsor if swallowing: Rinse mouth thoroughly. Do not induce vomiting. Have exposed individual drink sips ofwater. Seek medical attention if irritation, discomfort or vomiting important symptoms and effects, both acute and delayed:Irritation, Nausea,Headache, Shortness of breath.;Indication of any immediate medical attention and special treatment needed:If seeking medical attention, provide SDS document to to Physician: Treat data Sheetaccording to 29 CFR1910/1200 and GHS Rev. 3 Effective date : 3 of 7 VinegarCreated by Global Safety Management, 1-813-435-5161 - 5 : Firefighting measuresExtinguishing mediaSuitable extinguishing agents: If in laboratory setting, follow laboratory fire suppression procedures.

4 Useappropriate fire suppression agents for adjacent combustible materials or sources of ignitionFor Safety reasons unsuitable extinguishing agents:Special hazards arising from the substance or mixture:Combustion products may include carbon oxides or other toxic for firefighters:Protective equipment:Additional information (precautions): Move product containers away from fire or keep cool with waterspray as a protective measure, where 6 : Accidental release measuresPersonal precautions, protective equipment and emergency procedures:Wear protective equipment. Avoid contact with skin, eyes and from all sources of protective device against the effects of fumes/dust/aerosol. Keep unprotected persons away. Ensureadequate away from ignition sources. Protect from the spill, if possible. Containspilled material by diking or using inert absorbent. Transfer to a disposal or recovery precautions:Prevent from reaching drains, sewer or waterway.

5 Collect contaminated soil for characterization per Section 13 Methods and material for containment and cleaning up:If in a laboratory setting, follow Chemical Hygiene Plan liquids using vacuum or by use ofabsorbents. Place into properly labeled containers for recovery or disposal. If necessary, use trained from all sources of with inert spark-proof tools andexplosion-proof obey local to other sections:SECTION 7 : Handling and storagePrecautions for safe handling:Prevent formation of aerosols. Follow good hygiene procedures when handling chemical materials. Do not eat,drink, smoke, or use personal products when handling chemical substances. If in a laboratory setting, followChemical Hygiene only in well ventilated splashes or spray in enclosed handsafter contact with skin and for safe storage, including any incompatibilities:Store in a cool location. Provide ventilation for containers.

6 Avoid storage near extreme heat, ignition sources oropen flame. Store away from foodstuffs. Store away from oxidizing in cool, dry conditions in wellsealed containers. Keep container tightly from 8 : Exposure controls/personal protectionControl Parameters:64-19-7, Acetic Acid, ACGIH TLV: 25mg/m3, OSHA PEL: 25mg/m3 Safety data Sheetaccording to 29 CFR1910/1200 and GHS Rev. 3 Effective date : 4 of 7 VinegarCreated by Global Safety Management, 1-813-435-5161 - Engineering controls:Emergency eye wash fountains and Safety showers should be available inthe immediate vicinity of exhaust ventilation orother engineering controls to keep the airborne concentrations of vaporor mists below the applicable workplace exposure limits (OccupationalExposure Limits-OELs) indicated protection:Not required under normal conditions of use. Use suitable respiratoryprotective device when high concentrations are present.

7 Use suitablerespiratory protective device when aerosol or mist is formed. For spills,respiratory protection may be of skin:The glove material has to be impermeable and resistant to the product/the substance/ the preparation being of the glovematerial on consideration of the penetration times, rates of diffusion andthe protection: Safety glasses with side shields or hygienic measures:The usual precautionary measures are to be adhered to when handlingchemicals. Keep away from food, beverages and feed remove all soiled and contaminated clothing. Wash handsbefore breaks and at the end of work. Do not inhalegases/fumes/dust/mist/vapor/aeroso ls. Avoid contact with the eyes 9 : Physical and chemical propertiesAppearance (physicalstate,color):Clear, colorless liquidExplosion limit lower:Explosion limit upper:0 Vol %0 Vol %Odor:Vinegar-likeVapor kPa (@ 20 C) or 23 hPa (17mm Hg) at 20 C (68 F)Odor threshold:Not determinedVapor (Air = 1)pH-value:Not determinedRelative density:1 (Water = 1)Melting/Freezing point:0 C (32 F)Solubilities:Soluble in WaterBoiling point/Boilingrange:100 C (212 F)Partition coefficient (n-octanol/water):Not determinedFlash point (closedcup):Not applicableAuto/Self-ignitiontemperature: Not determinedEvaporation rate:Not determinedDecompositiontemperature:Not determinedFlammability(solid,gaseous):No t applicableViscosity:a.

8 Kinematic:Not determinedb. Dynamic: mPas at 20 C (68 F)Density: 1 g/cm ( lbs/gal) at 20 C (68 F)SECTION 10 : Stability and reactivityReactivity:Chemical stability:No decomposition if used and stored according to hazardous reactions:Conditions to avoid:Store away from oxidizing agents, strong acids or materials:Strong MetalsSafety data Sheetaccording to 29 CFR1910/1200 and GHS Rev. 3 Effective date : 5 of 7 VinegarCreated by Global Safety Management, 1-813-435-5161 - decomposition products:Carbon oxides (CO, CO2).Irritating fumesSECTION 11 : Toxicological informationAcute Toxicity:Oral:LD50 orl-rat: 3310 mg/kg (Acetic Acid)Dermal:LC50 inhalation-rat: 5620 ppm/ 1hr. (AceticAcid)Chronic Toxicity: No additional Irritation:Dermal:Section 2 Classified as a skin irritantOcular:Section 2 Classified as an eye irritantSensitization:No additional Target Organ (STOT):No additional Measures:No additional :No additional :No additional Toxicity:No additional 12 : Ecological informationEcotoxicityEcotoxicity: Acetic Acid has high biochemical oxygen demand, and a potential to cause oxygen depletion inaquatic and degradability: Readily degradable in the potential:Mobility in soil: Aqueous solution has high mobility in adverse effects:SECTION 13 : Disposal considerationsWaste disposal recommendations:Product/containers must not be disposed together with household garbage.

9 Do not allow product to reachsewage system or open is the responsibility of the waste generator to properly characterize all wastematerials according to applicable regulatory entities (US ). Consult federal state/ provincial andlocal regulations regarding the proper disposal of waste material that may incorporate some amount of as a hazardous 14 : Transport informationUN-NumberUN2790UN proper shipping nameSafety data Sheetaccording to 29 CFR1910/1200 and GHS Rev. 3 Effective date : 6 of 7 VinegarCreated by Global Safety Management, 1-813-435-5161 - Acid SolutionTransport hazard class(es)Class:8 Corrosive substancesPacking group:IIIE nvironmental hazard:Transport in bulk:Special precautions for user:SECTION 15 : Regulatory informationUnited States (USA)SARA Section 311/312 (Specific toxic chemical listings):AcuteSARA Section 313 (Specific toxic chemical listings):None of the ingredients is listedRCRA (hazardous waste code):None of the ingredients is listedTSCA (Toxic Substances Control Act):All ingredients are (Comprehensive Environmental Response, Compensation, and Liability Act):64-19-7 Acetic Acid 5000 lbProposition 65 (California):Chemicals known to cause cancer:None of the ingredients is listedChemicals known to cause reproductive toxicity for females.

10 None of the ingredients is listedChemicals known to cause reproductive toxicity for males:None of the ingredients is listedChemicals known to cause developmental toxicity:None of the ingredients is listedCanadaCanadian Domestic Substances List (DSL):All ingredients are NPRI Ingredient Disclosure list (limit ):None of the ingredients is listedCanadian NPRI Ingredient Disclosure list (limit 1%):None of the ingredients is listedSECTION 16 : Other informationThis product has been classified in accordance with hazard criteria of the Controlled Products Regulations and theSDS contains all the information required by the Controlled Products :. The responsibility toSafety data Sheetaccording to 29 CFR1910/1200 and GHS Rev. 3 Effective date : 7 of 7 VinegarCreated by Global Safety Management, 1-813-435-5161 - a safe workplace remains with the user should consider the health hazards and Safety informationcontained herein as a guide and should take those precautions required in an individual operation to instructemployees and develop work practice procedures for a safe work information contained herein is,to the best of our knowledge and belief, , since the conditions of handling and use are beyondour control, we make no guarantee of results, and assume no liability for damages incurred by the use of is the responsibility of the user to comply with all applicable laws and regulations applicable to Full Text Phrases:Abbreviations and acronyms:IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationGHS.