SAFETY DATA SHEET - Fluoride

1 Conforms to 2001/58/EC and ISO 11014-1 SAFETY DATA SHEETURANUSIDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF name:URANUST rifluralin (ISO): , , -trifluoro-2,6-dinitro-N, (ISO) : 3-(3,4-Dichlorophenyl) name of activeingredient(s)::ManufacturerAgan Chemical Manufacturers Industrial Zone, 262, Ashdod, Israel.:Makhteshim-Agan (UK) 16, Thatcham Business VillageColthrop Way, ThatchamBerkshire RG19 4LW, :National Chemical Emergency Centre, Tel : 0870 ON INGREDIENTSP reparation:Substance/preparationInformat ion on hazardous ingredients *SymbolR-PhrasesCAS name%EC NumberTrifluralin (ISO)1582-09-8R36-43-50/53216-428-822 - 24Xi,NLinuron (ISO)330-55-2R22-40-48/22-50/-53206-356- 511 - 12Xn,NIsophorone78-59-1R21/22-36/37-4020 1-126-016 - 18 XnXylene1330-20-7R10-20/21-38215-535-735 - 38Xn * Occupational Exposure Limit(s), if available, are listed in section 8 HAZARDS Irritating to eyes. Limited evidence of a carcinogenic cause sensitization by skin contact.

2 Harmful: danger of seriousdamage to health by prolonged exposure if swallowed. Very toxic toaquatic organisms, may cause long-term adverse effects in the aquaticenvironment.:Most important hazardsFIRST-AID and symptomsInhalationVapours - headache, dizziness, collapse.:Ingestion:nausea, headache, cramps, vomiting.:May cause sensitization by skin contact:Eye contactIrritating to eyes.:First-aid measuresRemove victim from area of exposure. Wash off remaining material withplenty of water.:InhalationRemove victim to fresh air. If breathing is difficult: artificial medical 1 of 7 Version: Date of issue: 12/01/2004 Conforms to 2001/58/EC and ISO 11014-1 SAFETY DATA SHEETURANUS:Wash out mouth with plenty of water. Get medical attention. Never giveanything by mouth to an unconscious contact:Remove contaminated away remainder with water out with plenty of water with the eyelid held wide open for at least15 minutes. Get medical contact:There is no specific antidote.

3 Treat symptomatically and give to a physician::Use appropriate protection (see section 8).Protection of first-aidersFIRE-FIGHTING media:Dry chemical, water spray, foam, carbon fire/explosionhazards:Flashback may occur along vapour trail.:Chloride compounds, Fluoride compounds and nitrogen thermal(de)composition products:Protection of fire-fightersSelf-contained breathing apparatus and total protection required inenclosed RELEASE MEASURES:Wear suitable protective precautionsEnvironmental precautions:Do not discharge into drains or the environment.:Keep away from: open flame, sparks and heat. Absorb remainder insand or other inert material. Dispose of in an authorized waste for cleaning AND STORAGE:HandlingAvoid contact with skin and eyes. Ventilation required. Keep away from:sparks, open flame and direct :Keep only in the original container. Keep in a cool, dry, well ventilatedplace away from direct materials:Plastic metal CONTROLS/PERSONAL PROTECTION:Engineering measuresVentilation handling do not eat, drink or smoke.

4 Wash hands thoroughly afterhandling. Wash clothing separately before re-use.:Hygiene measuresOccupational ExposureLimitsTrifluralin (ISO)Common name:Not established:Linuron (ISO)Common name:Not established:IsophoroneCommon name:Page 2 of 7 Version: Date of issue: 12/01/2004 Conforms to 2001/58/EC and ISO 11014-1 SAFETY DATA SHEETURANUSTLV (USA)2 ppm or 11 mg/m3:"MAK" (Germany):2 ppmXyleneCommon name:TLV (USA)100 ppm:"MAK" (Germany):100 ppmOEL (United Kingdom)100 ppm:Personal protectiveequipment:Respiratory protection is not required if good ventilation is systemWear suitable protective clothing. Chemical resistant and body:Hands:Chemical resistant : SAFETY goggles or face AND CHEMICAL PROPERTIES:LiquidPhysical stateReddishColour:Odour:Characteristic odourBoiling point:137-143oC (Xylene) g/mL @ 20oC: mPa @ 25oC (Trifluralin (ISO)) mPa @ 25oC (Linuron (ISO))Vapour ppm @ 25oC (Trifluralin (ISO)) mg/L @ 20oC (Linuron (ISO))Solubility in waterlog = (Trifluralin (ISO))log = (Linuron (ISO))Octanol/water partitioncoefficient:pH:5 - 7 Flash point:37oC:FlammableFlammability:450oC (Xylene)Autoignition temperatureXylene (vapours) - May form explosive mixture with properties:Lower explosion limit1 volume %:7 volume %Upper explosion AND REACTIVITYNot subject to polymerization.

5 :Stability:Oxidizing agents, acids and to avoidFlashback may occur along vapour reactions::Chloride compounds, Fluoride compounds and nitrogen INFORMATIONP reparation:LD50 (rat) > 2,000 mg/kgAcute toxicity - OralAcute toxicity - Dermal:LD50 (rat) > 2,000 mg/kg:Acute toxicity - InhalationLC50 > mg/LSkin irritation:Not irritating (rabbit)Eye irritationModerately irritating (rabbit):Page 3 of 7 Version: Date of issue: 12/01/2004 Conforms to 2001/58/EC and ISO 11014-1 SAFETY DATA SHEETURANUSE xtreme sensitizer (guinea-pig)Sensitization::Trifluralin (ISO)Common nameNOEL (rat) = mg/kg/day (2 years).NOEL (mice) = 73 mg/kg/day (2 years).:Chronic toxicityCarcinogenicity:EPA : Group C EU : Not classifiedIARC : Group 3 Not mutagenic:Mutagenicity:Reproduction toxicityNOEL (rat) = 50 ppm (2 generation).Teratogenicity - NOAEL (rabbit): 20 mg/kg/day (Maternal) ; 50mg/kg/day (Fetal).Other information::Linuron (ISO)Common nameNOAEL (rat) = 25 ppm or mg/kg/day (2 years)NOAEL (mouse) = 50 ppm or mg/kg/day (2 years):Chronic toxicityCarcinogenicity:EPA : Group CEU : Category 3 IARC : Not classifiedNot mutagenic:Mutagenicity:Reproduction toxicityNOAEL (rat) = 125 ppm (3 generation)Teratogenicity - NOAEL (rat) = 20 mg/kg/day (Maternal and Fetal)NOAEL (rabbit) = 10 mg/kg/day (Maternal) ; 25 mg/kg/day (Fetal)Other information:ECOLOGICAL (96 hours) Trout = mg/LDaphnia magnaEC50 (48 hours) = mg/LAlgae (scenedesmus subspicatus)EC50 (72 hours) = mg/LBirdsBobwhite quail (colinus virginianus) LD50 = 1,230 mg/kgMallard duck (anas platyrhynchos) LD50 > 1,650 mg/kgToxic to fish.

6 Low toxicity: birds.::Common nameTrifluralin (ISO):MobilitySoilNot on soils with high organic = 6,414 - 13,414 mL/g:Persistence/degradabilitySoilModera tely time (t ): ~ 45 is primarily via: product is not rapidly in aquatic systems with DT50 risk of underground water potential:Low bioaccumulation 4 of 7 Version: Date of issue: 12/01/2004 Conforms to 2001/58/EC and ISO 11014-1 SAFETY DATA SHEETURANUSE cotoxicity:FishLC50 (96 hours) rainbow trout (oncorhynchus mykiss) = mg/L bluegill sunfish (lepomis macrochirus) = mg/LNOEC (35 days) fat head minnow = g/LDaphnia magna EC50 (48 hours) = mg/LNOEC (21 days) = mg/LAlgae (selenastrum capricornutun)EC50 (72 hours) = mg/LBirdsMallard duck (anas platyrhynchos) LD50 > 2,000 mg/kgBobwhite quail (colinus virginianus) LD50 > 2,250 mg/kgMallard duck (anas platyrhynchos) and Bobwhite quail (colinusvirginianus) LC50 > 5,000 ppm (5 day feeding)BeesOral and Contact LD50 (48 hours) > 100 g/beeToxic to aquatic organisms Low toxicity: birds and bees.

7 :Common nameLinuron (ISO):MobilitySoilNot mobile. Adsorbed on organic matter and = - 18 mL/gKoc = 362 - 877 mL/gWaterLow risk of underground water contamination.:Persistence/degradability SoilLab. - Half-life time (t ): 38-135 days (15-25o)Field - DT50: 13-82 is primarily via: : 48 potential:BCF : :FishLC50 (96 hours) rainbow trout (oncorhynchus mykiss) = mg/LNOEC (21 days) rainbow trout (oncorhynchus mykiss) = mg/LDaphnia magnaEC50 (24 hours) = mg/LNOEC (21 days) = mg/LAlgae (scenedesmus subspicatus)EC50 (72 hours) = mg/LBirdsBobwhite quail (colinus virginianus) LD50 = 314 mg/kgBobwhite quail (colinus virginianus) LC50 = 1,250 ppm (8-day feeding)BeesOral LD50 > 160 g/bee Contact LD50 > 1,600 g/bee Very toxic to aquatic organisms. Low toxicity: birds. Non toxic: 5 of 7 Version: Date of issue: 12/01/2004 Conforms to 2001/58/EC and ISO 11014-1 SAFETY DATA CONSIDERATIONSM ethods of disposal:Dispose of in a pesticide approved landfill, or in a chemical incineratorequipped with scrubbers, In accordance with national and transport regulations:1993UN numberLand - Road/RailwayProper shipping name:Flammable Liquid, , Xylene3, F1, PG III:ADR/RID ClassHazard IdentificationNumber:30 Inland waterwaysProper shipping name:Flammable Liquid, , XyleneADNR Class:3, F1, PG IIISea:Flammable Liquid, , XyleneProper shipping nameIMDG Class:3, Label 3 Packing group:III:Emergency Schedules(EmS)F-E, S-EAirProper shipping name:Flammable Liquid, , XyleneUN/ID Number:19933.

8 IATA-DGR ClassNational transport regulationsNo additional national transport regulations are known to the INFORMATIONThis product is provisionally labelled by the supplier in accordance with thesuppliers understanding of the EU regulations (Directives 67/548/EEC,1999/45/EC).Classification:Xn , NHazard symbol(s):HARMFULDANGEROUS FOR THEENVIRONMENTPage 6 of 7 Version: Date of issue: 12/01/2004 Conforms to 2001/58/EC and ISO 11014-1 SAFETY DATA SHEETURANUSRisk phrases:R10: : Irritating to : Limited evidence of a carcinogenic : May cause sensitization by skin : Harmful: danger of serious damage to health by prolongedexposure if : Very toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic : Keep out of the reach of : Keep away from food, drink and animal : When using do not eat, drink or : In case of contact with eyes, rinse immediately with plenty of waterand seek medical : Wear suitable protective clothing, gloves and : If swallowed, seek medical advice immediately and show thiscontainer or : This material and its container must be disposed of as : Avoid release to the environment.

9 Refer to special instructions/Safetydata phrases:OTHER information contained in the SAFETY Data SHEET is correct to the best of our knowledge at the date ofissue. It is intended as a guide for the safe use, handling, disposal, storage and transportation and is notintended as a warranty or as a specification. The information relates only to the product specified and maynot be suitable for combinations with other materials or in processes other than those specifically :Date of printing12/01/2004 Date previous issue::12/01/2004 Date of issueVersion:001 The version-number is made up of three parts; part 1 is a general information code, part 2 acountry-specific code and part 3 a language-specific codePage 7 of 7 Version: Date of issue: 12/01/2004