SAFETY DATA SHEET - Hammerite UK

1 SAFETY data SHEETC onforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Product Details of the supplier of the SAFETY data Relevant identified uses of the substance or mixture and uses advised againstSECTION 1: Identification of the substance/mixture and of the company/undertakingDate of previous issue27-9-2016:ICI Paints AkzoNobel,Wexham Road,Slough,Berkshire,SL2 5DS, : +44 (0) 333 222 71 address of person responsible for this Emergency telephone numberTelephone number:Emergency Telephone : Slough +44 (0) 1753 550000 name: DIRECT TO RUST METAL PAINT SATINP roduct use: Solvent borne coating for interior and exterior use. DIRECT TO RUST METAL PAINT SATINC lassification according to Regulation (EC) No. 1272/2008 [CLP/GHS]SECTION 2: Hazards Classification of the substance or mixtureProduct definition:MixtureIngredients of unknown toxicity:Ingredients of unknown ecotoxicity:Flam. Liq. 3, H226 STOT SE 3, H336 Aquatic Chronic 3, H4120%0%Date of issue/Date of revision:Page: 1/1412-12-2016 DIRECT TO RUST METAL PAINT SATINPage: 2/14 SECTION 2: Hazards identificationHazardous ingredients:Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics:Other hazards which do not result in classificationNone Section 11 for more detailed information on health effects and Section 16 for the full text of the H statements declared Label elementsHazard pictograms:Signal word:Hazard statements:Prevention:Precautionary statementsResponse:StorageDisposal:Warni ngH226 - Flammable liquid and - May cause drowsiness or - Harmful to aquatic life with long lasting - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.

2 No - Keep container tightly - Do not get in eyes, on skin, or on + P340 - IF INHALED: Remove person to fresh air and keep comfortable for - Call a POISON CENTER or doctor if you feel - Keep - Dispose of contents and container in accordance with all local, regional,national or international label elementsContainers to be fitted with child-resistant fasteningsNot warning of dangerNot applicable.:::Contains 2-butanone oxime. May produce an allergic reaction. Repeated exposure may cause skin dryness or packaging Other hazardsGeneral:P102 - Keep out of reach of - If medical advice is needed, have product container or label at XVII - Restrictions on the manufacture,placing on the market and use of certain dangerous substances, mixtures and articles:Not 3: Composition/information on ingredientsIdentifiersProduct/ingredient name% (w/w)TypeRegulation (EC) No. 1272/2008 [CLP] Mixtures:MixtureDate of issue/Date of revision:Page: 2/1412-12-2016 DIRECT TO RUST METAL PAINT SATINPage: 3/14 SECTION 3: Composition/information on ingredientsHydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics,< 2% aromaticsREACH #:01-2119463258-33 25 - <50 Flam.

3 Liq. 3, H226[1]EC: 919-857-5 STOT SE 3, H336 Asp. Tox. 1, H304 EUH066trizinc bis(orthophosphate)REACH #:01-2119485044-40 1 - < Acute 1, H400[1]EC: 231-944-3 Aquatic Chronic 1, H410 CAS: 7779-90-0 Index:030-011-00-6 Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics,<2% aromaticsREACH #:01-2119471843-32 1 - <3 Flam. Liq. 3, H226[1]STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 3, H412 Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics,< 2% aromaticsREACH #:01-2119457273-39 - <1 Asp. Tox. 1, H304[1]EC: 918-481-9 EUH0662-butanone oximeREACH #:01-2119539477-28 - <1 Acute Tox. 4, H312[1]EC: 202-496-6 Eye Dam. 1, H318 CAS: 96-29-7 Skin Sens. 1, H317 Index:616-014-00-0 Carc. 2, H351 See Section 16 for the full text of the H statements declared exposure limits, if available, are listed in Section are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

4 [1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII[5] Substance of equivalent concernTypeIf swallowed, seek medical advice immediately and show the container or person warm and at rest. Do NOT induce contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained 4: First aid measuresGeneralIn all cases of doubt, or when symptoms persist, seek medical attention.

5 Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice.:Skin Description of first aid measuresIngestionInhalationEye contact::::Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth of issue/Date of revision:Page: 3/1412-12-2016 DIRECT TO RUST METAL PAINT SATINPage: 4/14 SECTION 4: First aid measuresSee toxicological information (Section 11)There are no data available on the mixture itself. The mixture has been assessed following the conventional method of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2 and 3 for to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.

6 Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the splashed in the eyes, the liquid may cause irritation and reversible may cause nausea, diarrhea and takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye 2-butanone oxime. May produce an allergic to physicianTreat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.:Specific Most important symptoms and effects, both acute and Indication of any immediate medical attention and special treatment neededNo specific treatment.

7 :SECTION 5: Firefighting measuresRecommended: alcohol-resistant foam, CO , powders, water not use water thermal decomposition productsHazards from the substance or mixtureSpecial protective equipment for Extinguishing media:::Suitable extinguishing media:Unsuitable extinguishing Special hazards arising from the substance or Advice for firefightersSpecial protective actions for fire-fighters:Fire will produce dense black smoke. Exposure to decomposition products may cause a health closed containers exposed to fire with water. Do not release runoff from fire to drains or breathing apparatus may be products may include the following materials: carbon monoxide,carbon dioxide, smoke, oxides of sources of ignition and ventilate the area. Avoid breathing vapour or to protective measures listed in sections 7 and 6: Accidental release measuresDo not allow to enter drains or watercourses. If the product contaminates lakes,rivers, or sewers, inform the appropriate authorities in accordance with local Environmental Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel:For emergency responders:If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials.

8 See also the information in "For non-emergency personnel".:Date of issue/Date of revision:Page: 4/1412-12-2016 DIRECT TO RUST METAL PAINT SATINPage: 5/14 SECTION 6: Accidental release measuresContain and collect spillage with non-combustible, absorbent material sand,earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Preferably clean with a using Methods and material for containment and cleaning Reference to other sectionsSee Section 1 for emergency contact Section 8 for information on appropriate personal protective Section 13 for additional waste treatment information.::SECTION 7: Handling and storagePrevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations higher than the occupational exposure addition, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded.

9 Electrical equipment should be protected to the appropriate may charge electrostatically: always use earthing leads when transferring from one container to should wear antistatic footwear and clothing and floors should be of the conducting away from heat, sparks and flame. No sparking tools should be contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of this mixture. Avoid inhalation of dust from , drinking and smoking should be prohibited in areas where this material is handled, stored and on appropriate personal protective equipment (see Section 8).Never use pressure to empty. Container is not a pressure keep in containers made from the same material as the original with the health and SAFETY at work not allow to enter drains or on fire and explosion protectionVapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with information in this section contains generic advice and guidance.

10 The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). Specific end use(s)Recommendations::Industrial sector specific solutionsNot Precautions for safe handling:Seveso Directive - Reporting thresholds (in tonnes)Danger criteriaCategoryP5c: Flammable liquids 2 and 3 not falling under P5a or P5b500050000C6: Flammable (R10)500050000 Notification and MAPP thresholdSafety report Conditions for safe storage, including any incompatibilitiesStore in accordance with local on joint storageKeep away from: oxidising agents, strong alkalis, strong information on storage conditionsObserve label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed and kept upright to prevent of issue/Date of revision:Page: 5/1412-12-2016 DIRECT TO RUST METAL PAINT SATINPage: 6/14 Use SAFETY eyewear designed to protect against splash of adequate ventilation.