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SAFETY DATA SHEET - Hill Brothers Chemical Co.

SAFETY data SHEET . 1. Identification Product identifier COPERLATE . Other means of identification Product registration 65109-1. number Synonyms COPERLATE II NON-CROP. Recommended use Algaecide/Bactericide Recommended restrictions None known. Manufacturer/Importer/Supplier/Distribut or information Company Name SSI Corporation Address 210 S. Cedar Street Julesburg, CO 80737. Telephone 970-474-0974. Emergency Telephone 1-800-424-9300 24 Hours Number 2. Hazard(s) identification Physical hazards Not classified. Health hazards Acute toxicity, oral Category 4. Serious eye damage/eye irritation Category 1. Environmental hazards Hazardous to the aquatic environment, acute Not applicable hazard Hazardous to the aquatic environment, Not applicable long-term hazard OSHA defined hazards Not classified.

8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value

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Transcription of SAFETY DATA SHEET - Hill Brothers Chemical Co.

1 SAFETY data SHEET . 1. Identification Product identifier COPERLATE . Other means of identification Product registration 65109-1. number Synonyms COPERLATE II NON-CROP. Recommended use Algaecide/Bactericide Recommended restrictions None known. Manufacturer/Importer/Supplier/Distribut or information Company Name SSI Corporation Address 210 S. Cedar Street Julesburg, CO 80737. Telephone 970-474-0974. Emergency Telephone 1-800-424-9300 24 Hours Number 2. Hazard(s) identification Physical hazards Not classified. Health hazards Acute toxicity, oral Category 4. Serious eye damage/eye irritation Category 1. Environmental hazards Hazardous to the aquatic environment, acute Not applicable hazard Hazardous to the aquatic environment, Not applicable long-term hazard OSHA defined hazards Not classified.

2 Label elements Signal word Danger Hazard statement Harmful if swallowed. Causes serious eye damage. Precautionary statement Prevention Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear eye/face protection. Response Rinse mouth. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Storage Store away from incompatible materials. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC). 3. Composition/information on ingredients Mixtures Chemical name CAS number %.

3 Copper Sulfate Pentahydrate 7758-99-8 20. COPERLATE SDS US. 923864 Version #: 02 Revision date: 18-December-2014 Issue date: 15-December-2014 1/8. Sulfuric acid 7664-93-9 8. Other components below reportable levels *Designates that a specific Chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Skin contact Wash off with soap and water. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Ingestion If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.

4 Get medical advice/attention if you feel unwell. Most important Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred symptoms/effects, acute and vision. Permanent eye damage including blindness could result. delayed Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim medical attention and special under observation. Symptoms may be delayed. treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this SAFETY data SHEET to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials.

5 Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. the Chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting Move containers from fire area if you can do so without risk. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away.

6 Keep people away from and upwind of spill/leak. Wear protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Should not be released into the environment. containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic SHEET to prevent spreading.

7 Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material ( cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Do not get this material in contact with eyes. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke.

8 Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials (see Section 10. including any incompatibilities of the SDS). COPERLATE SDS US. 923864 Version #: 02 Revision date: 18-December-2014 Issue date: 15-December-2014 2/8. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ). Components Type Value Sulfuric acid (CAS PEL 1 mg/m3. 7664-93-9). US. ACGIH Threshold Limit Values Components Type Value Form Sulfuric acid (CAS TWA mg/m3 Thoracic fraction.)

9 7664-93-9). US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form Copper Sulfate TWA 1 mg/m3 Dust and mist. Pentahydrate (CAS. 7758-99-8). Sulfuric acid (CAS TWA 1 mg/m3. 7664-93-9). Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

10 Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear SAFETY glasses with side shields (or goggles) and a face shield. Skin protection Hand protection Wear appropriate Chemical resistant gloves. Other Wear suitable protective clothing such as long-sleeved shirt, pants, and shoes with socks. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Wash hands after handling and before eating. Keep away from food and drink. considerations 9. Physical and Chemical properties Appearance Physical state Liquid.


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