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SAFETY DATA SHEET - ICL-IP

Supersedes31/03/2014_____SAFETY data SHEET_____Product nameFYRQUEL EHC PLUSP roduct id7080 Revision date30/05/2016 Revision: 82. Hazards identificationGHSP roduct is not subject to classification according to GHS. No label Ratings (Scale 0-4)Health = 1, Fire = 1, Reactivity = 03. Composition / information on ingredientsComponentsWeight %Index ClassificationTriphenyl phosphate 115-86-60-4204-112-2 Aquatic Acute 1,H400 Aquatic Chronic 2,H411t-Butylphenyl diphenylphosphate 56803-37-332-78260-391-0-Bis(t-butylphen yl)phenylphosphate 65652-41-710-40265-859-8-1. Identification of the substance & the companyChemical namePhenol, isobutylenated, phosphate (3:1)Synonym(s)Butylated triphenyl phosphate familyAryl phosphateType of product and useFire-resistant hydraulic fluidCompanyICL-IP America Emerson Road - Suite 500St Louis, Missouri 63141, USAP hone - 1 800 666 1200 Emergency telephone number:- For Europe+32 (0) 3 575 5555 SGS- For USAC hemtrec (800) 424-9300- For Asia - PacificALERT-SGS24 hr Toll Free Number : +800 ALERTSGS (+800-2537-8747)24 hr Singapore Exchange Number : +65 65

Supersedes 31/03/2014 SAFETY DATA SHEET _____ Product name FYRQUEL EHC PLUS Product id 7080 Revision date 30/05/2016 Revision: 8 Methods for cleaning upSoak up with sand or other suitable absorbent and dispose of as solid waste. Collect in suitable and properly labeled containers.

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Transcription of SAFETY DATA SHEET - ICL-IP

1 Supersedes31/03/2014_____SAFETY data SHEET_____Product nameFYRQUEL EHC PLUSP roduct id7080 Revision date30/05/2016 Revision: 82. Hazards identificationGHSP roduct is not subject to classification according to GHS. No label Ratings (Scale 0-4)Health = 1, Fire = 1, Reactivity = 03. Composition / information on ingredientsComponentsWeight %Index ClassificationTriphenyl phosphate 115-86-60-4204-112-2 Aquatic Acute 1,H400 Aquatic Chronic 2,H411t-Butylphenyl diphenylphosphate 56803-37-332-78260-391-0-Bis(t-butylphen yl)phenylphosphate 65652-41-710-40265-859-8-1. Identification of the substance & the companyChemical namePhenol, isobutylenated, phosphate (3:1)Synonym(s)Butylated triphenyl phosphate familyAryl phosphateType of product and useFire-resistant hydraulic fluidCompanyICL-IP America Emerson Road - Suite 500St Louis, Missouri 63141, USAP hone - 1 800 666 1200 Emergency telephone number:- For Europe+32 (0) 3 575 5555 SGS- For USAC hemtrec (800) 424-9300- For Asia - PacificALERT-SGS24 hr Toll Free Number : +800 ALERTSGS (+800-2537-8747)24 hr Singapore Exchange Number : +65 6542-9595{ Page 1 of 7 }- For JapanTel: 03-6801 8430: 03-6801 6970 Supersedes31/03/2014_____SAFETY data SHEET_____Product nameFYRQUEL EHC PLUSP roduct id7080 Revision date30/05/2016 Revision.

2 8tri(t-butylphenyl) phosphate 78-33-10-10-This product can also be described as: CAS No. 68937-40-6 , Phenol, isobutylenated, phosphate (3:1)6. Accidental release measuresPersonal precautionsWear appropriate SAFETY clothing and eye/face protection (see Section 8)4. First-aid measuresEye contactHolding the eyelids apart, flush eyes promptly with copious flowing water for atleast 20 minutes. Get medical attention contactRemove contaminated clothing. Wash skin thoroughly with mild soap and plenty ofwater for at least 15 minutes. Wash clothing before reuse. Get medical attention ifirritation case of mist inhalation or breathing fumes released from heated material,remove person to fresh air. Keep him quiet and warm. Apply artificial respiration ifnecessary and get medical attention swallowed, wash mouth thoroughly with plenty of water.

3 Get medical : Never give an unconscious person anything to drink----------------------------------- ---------------------------------------- -----------Symptoms / Effects, Acute andDelayedNo specific information availableMost important symptoms and effects, acute or delayedNone knownNotes to the physicianTreat symptomatically and specific Fire - fighting measuresSuitable extinguishing mediaUse extinguishing media appropriate to surrounding fire fire and explosionhazardsWhen heated to decomposition, may release poisonous and corrosive fumes ofcarbon dioxide, carbon monoxide and phosphorus fighting procedure{ Page 2 of 7 }Fire fighters should wear full protective clothing and self-contained breathingapparatus (SCBA). Contain runoff to prevent entry into water or drainage data SHEET_____Product nameFYRQUEL EHC PLUSP roduct id7080 Revision date30/05/2016 Revision: 8 Methods for cleaning upSoak up with sand or other suitable absorbent and dispose of as solid in suitable and properly labeled containers.

4 Ventilate area and wash spillsite after material pickup is precautionsPrevent product from entering drains, ditches and Physical and chemical propertiesAppearanceClear liquid7. Handling and storageHandlingAvoid bodily contact. Keep containers tightly in a dry, cool, well-ventilated area away from incompatible materials (see"materials to avoid"). Maximum recommended storage temperature of 50 C(122 F) Store above C (40 F) for improved pumping rates. Temperaturesbetween 27 - C (80 - 100 F) provide good flow Exposure controls / personal protectionExposure Limits :ComponentsACGIH-TLV DataOSHA (PEL) DataTriphenyl phosphate 115-86-63 mg/m33 mg/m3t-Butylphenyl diphenyl phosphate 56803-37-3 Not determinedNot determinedBis(t-butylphenyl)phenyl phosphate 65652-41-7 Not determinedNot determinedtri(t-butylphenyl) phosphate 78-33-1 Not determinedNot determinedVentilation requirementsVentilation must be sufficient to maintain atmospheric concentration belowrecommended exposure protective equipment.

5 - Respiratory protectionIn case of insufficient ventilation wear suitable respiratory Hand protectionNeoprene gloves- Eye protectionChemical splash goggles and/or face shield if splash hazard exists- Skin and body protectionBody covering clothes and boots{ Page 3 of 7 }Hygiene measuresDo not eat, smoke or drink where material is handled, processed or stored. Washhands thoroughly after handling and before eating or smoking. SAFETY shower andeye bath should be data SHEET_____Product nameFYRQUEL EHC PLUSP roduct id7080 Revision date30/05/2016 Revision: point/range-21 CBoiling point/range>400 C (762mmHg)Flash point>246 C (>475 F) (closed cup)Evaporation rate (ether=1)Not availableFlammability (solid, gas)Not applicableFlammable/Explosion limitsNot flammable/Not explosiveVapor (-3)Pa (20 C)Vapor densityNot g/mL (25 C)Solubility:- Solubility in water121 g/l (20 C)Based on primary componentPartition coefficient(n-octanol/water)Log Pow : temperatureNot self-ignitableViscosity42-46 cSt.

6 (40 C)Ignition temperature593 C (1100 F)Explosive propertiesThere are no chemical groups associated with explosive properties present in themoleculeOxidising propertiesThe structure indicates non oxidizing properties10. Stability and reactivityReactivityNo reactive hazards under normal conditionsPossibility of hazardousreactionsNot expected to occurConditions to avoidHeating above decomposition to avoidStrong oxidizers, strong acids and strong hydrolyzes slowly at normal temperatures in acidic or alkaline decompositionproductsPhosphorus oxides Carbon dioxide and carbon monoxide11. Toxicological informationNote:The toxicological data refer to a similar productAcute toxicity:- Rat oral LD50> 5000 mg/kg- Rabbit dermal LD50> 2000 mg/kg{ Page 4 of 7 }- Rat inhalation LC50> mg/lSupersedes31/03/2014_____SAFETY data SHEET_____Product nameFYRQUEL EHC PLUSP roduct id7080 Revision date30/05/2016 Revision.

7 8- Dermal irritation (rabbit)Not irritant- Eye irritation (rabbit)Not irritantDermal sensitizationNot a sensitizerMutagenicityNot mutagenic by the Ames Test and by mouse lymphoma in chromosome aberration and sister chromatid exchange tests in mouselymphoma included in NTP 13th Report on CarcinogensNot classified by IARCR eproductive toxicityButylated triphenyl phosphate did not demonstrate reproductive a rat reproduction study, male and female animals received either 50, 250 or1000 mg/kg/day for several weeks after which they mated. There was noreproductive toxicity observed at any dose level. Diagnostic pathology confirmedno alterations to the reproductive organs. There was no effect on mating index,litter size, survival of the offspring or on any other measured teratogenic when administered orally up to 1000 mg/kgSpecific Target Organ Toxicity(STOT) - Single exposureNo effects on specific target organs have been identifiedSpecific Target Organ Toxicity(STOT) - Repeat exposureNOAEL mg/kg bw /day (90 days oral, male rat) NOAEL mg/kg bw/day (90 days oral, female rat)Aspiration hazardNot expected to occurNeurotoxicityNo signs of acute delayed neurotoxicity when administered orally to hens at Ecological informationAquatic toxicity.

8 No effects on aquatic organisms occured at concentrations up to the substanceswater biodegradableBioaccumulative potentialNot bioaccumulativeThe wholefish BCF was found to be in soilNot relevant{ Page 5 of 7 }Note:Not considered to be PBT or vPvBSupersedes31/03/2014_____SAFETY data SHEET_____Product nameFYRQUEL EHC PLUSP roduct id7080 Revision date30/05/2016 Revision: 814. Transportation informationIMDGNot regulatedADR/RIDNot regulatedICAO/IATANot regulatedDOTNot regulated13. Disposal considerationsWaste disposalDispose of in a safe manner in accordance with local/national of PackagingDispose of in a safe manner in accordance with local/national Regulatory informationEUReported in EINECSEC in the EPA TSCA in AICSC anadaListed in DSLC hina- China inventory Listed in IECSC- Hazardous Chemicals ListThe substance is not included- Toxic Chemicals ListThe substance is not includedJapanListed in ENCSK oreaListed in ECLNew Zealand InventoryListed in NZIoCPhilippinesListed in PICCST aiwan{ Page 6 of 7 }ListedSupersedes31/03/2014_____SAFETY data SHEET_____Product nameFYRQUEL EHC PLUSP roduct id7080 Revision date30/05/2016 Revision: 816.

9 Other informationThis data SHEET contains changes from the previous version in section(s)1, 3, 8, 11, 12, 15 Health, SAFETY & Environment PolicyWe will strive to ensure that our operations and products meet the needs of the present global community withoutcompromising the ability of future generations to meet their needs We accept that the success of our business isdependent on the supply of products and services that will benefit society whilst ensuring human SAFETY and protectionof the environment and natural resources Within the framework of our commitment to the Responsible Care program,we will provide a healthy and safe work environment for employees and will responsibly manage our products at allstages of their life cycle in order to protect human health and the environment whilst maintaining high productionstandards of operationTO MEET THIS COMMITMENT WE WILL.

10 Comply with or exceed applicable national and international regulatoryrequirements and other requirements to which we subscribe Communicate openly and actively encourage dialoguewith employees, customers and community concerning our products and operations Implement documentedmanagement systems consistent with and for promotion of the Responsible Care ethicsDevelop and supply products that can be manufactured, transported, used and disposed of safely whilst best meetingthe needs of our customers Regularly assess, continually improve and responsibly manage health, SAFETY andenvironmental risks associated with products and processes throughout their life-cycles Share knowledge andexpertise with others and seek to learn from and incorporate improved practices into our own operationsEducate and train employees, contractors and customers to improve their HSE performance Communicate up-to-dateinformation to enable our workers, customers and other interested parties to handle our products in a safe andenvironmentally responsible manner Endeavor to work with customers, suppliers, distributors and contractors to fosterthe safe use, transport and disposal of our chemicals Support Product Stewardship programs in cooperation withcustomers.