SAFETY DATA SHEET - Maksal

1 SAFETY data SHEETSECTION 1: Identification of the substance/mixture and of the Product identifierTrade name or designationof the mixtureECO Smart Boric Acid Free Flux - Powder-Registration date23-July-2013 Version number01 Revision date-Supersedes Relevant identified uses of the substance or mixture and uses advised againstIdentified usesFlux Brazing or SolderingUses advised againstNone Details of the supplier of the SAFETY data sheetManufacturer/SupplierHarris Products Group4501 Quality PlaceMason, Ohio 45040 Emergency telephonenumber(+) 44 808 189 0979 (United Kingdom)(+) 1-760-476-3962 Please quote 333895 SECTION 2: Hazards Classification of the substance or mixtureClassification according to Directive 67/548/EEC or 1999/45/EC as amendedClassificationXn;R20/21/22 Classification according to Regulation (EC) No 1272/2008 as amendedH302 - Harmful if 4 Acute toxicity, oralHealth hazardsH312 - Harmful in contact with 4 Acute toxicity, dermalH332 - Harmful if 4 Acute toxicity, inhalationHazard summaryPhysical hazardsNot classified for physical hazardsHarmful by inhalation, in contact with skin and if hazardsNot classified for hazards to the hazardsProlonged overexposure to fluorides may increase fluoride content of bones and teeth, and mayresult in fluorosis, with mottling of teeth (in children) and brittleness of symptomsAbsorbed fluoride can cause metabolic imbalances with irregular heartbeat, nausea, dizziness,vomiting and Label elementsLabel according to Regulation (EC) No.

2 1272/2008 as amendedContains:Boron, Potassium fluorosili cate Hazard pictogramsSignal wordWarningECO Smart Boric Acid Free Flux - PowderSDS UK914077 Version No.: 01 Revision date: - Issue date: 23-July-20131 / 7 Hazard statementsH302 - Harmful if - Harmful in contact with - Harmful if statementsPreventionP261 - Avoid breathing - Wash thoroughly after - Do not eat, drink or smoke when using this - Use only outdoors or in a well-ventilated - Wear protective gloves/protective clothing/eye protection/face + P312 - IF SWALLOWED: Call a POISON CENTRE or doctor/physician if you feel - Rinse + P352 - IF ON SKIN: Wash with plenty of soap and - Call a POISON CENTRE or doctor/physician if you feel - Wash contaminated clothing before + P312 - IF INHALED: Call a POISON CENTRE or doctor/physician if you feel away from incompatible - Dispose of contents/container in accordance with local/regional/ label informationNot Other hazardsNot a PBT or vPvB substance or 3: Composition/information on MixturesNotesINDEX Registration / EC nameGeneral informationClassification:DSD:--CLP.

3 #--14075-53-7237-928-2 Potassium fluoborate< 70 Classification:DSD:Xn;R22 Acute Tox. 4;H302 CLP:--7440-42-8231-151-2 Boron< 3 Classification:DSD:T;R23/24/25 Acute Tox. 3;H301, Acute Tox. 3;H311, Acute Tox. 3;H331 CLP:#009-012-00-0-16871-90-2240-896-2 Potassium fluorosilicate < 3#: This substance has been assigned Community workplace exposure limit(s).Composition commentsAll concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume. The full text for all R- and H-phrases is displayed in section 4: First aid measuresGeneral informationShow this SAFETY data SHEET to the doctor in Description of first aid measuresInhalationRemove person from contaminated area to fresh air. Apply artificial respiration if needed. Getmedical attention if discomfort develops or contactRemove contaminated clothes and rinse skin thoroughly with water for at least 15 minutes. Getmedical attention if irritation develops and contactImmediately flush with plenty of water for up to 15 minutes.

4 Remove any contact lenses and openeyelids wide apart. Get medical attention if irritation develops or NOT induce vomiting. Immediately rinse mouth and drink a cupful of water. Never give anythingby mouth to an unconscious person. Seek medical Most important symptomsand effects, both acute anddelayedAbsorbed fluoride can cause metabolic imbalances with irregular heartbeat, nausea, dizziness,vomiting and Indication of anyimmediate medical attentionand special treatment neededTreat symptomatically. Symptoms may be Smart Boric Acid Free Flux - PowderSDS UK914077 Version No.: 01 Revision date: - Issue date: 23-July-20132 / 7 SECTION 5: Firefighting measuresGeneral fire hazardsThis product is not Extinguishing mediaSuitable extinguishingmediaUse fire-extinguishing media appropriate for surrounding materials. Water spray, foam, dry powderor carbon extinguishingmediaNone Special hazards arisingfrom the substance or mixtureHydrogen fluoride, a corrosive and toxic gas, and other potentially hazardous fluorine-containingcompounds may be released upon Advice for firefightersSpecial protectiveequipment for firefightersSelf-contained breathing apparatus and full protective clothing must be worn in case of fire fightingproceduresMove containers from fire area if you can do so without 6: Accidental release Personal precautions, protective equipment and emergency proceduresFor non-emergencypersonnelAvoid inhalation of dust from the spilled material.

5 Wear protective clothing as described in Section8 of this SDS. Do not touch damaged containers or spilled material unless wearing appropriateprotective emergency respondersKeep unnecessary personnel away. Use personal protection recommended in section 8 of Environmental precautionsDo not allow to enter drains, sewers or watercourses. Reporting of releases to appropriateregulatory agencies may be Methods and material forcontainment and cleaning upStop the flow of material, if this is without risk. Avoid release to the Spills: Sweep or vacuum up spillage and collect in suitable container for disposal. Avoid thegeneration of dusts during Spills: Wipe up spilled material and place in a suitable container for return spills in original containers for re-use. Following product recovery, flush area withwater. Clean surface thoroughly to remove residual contamination. This material and its containermust be disposed of as hazardous waste. For waste disposal, see section 13 of the Reference to othersectionsFor waste disposal, see section 13 of the 7: Handling and Precautions for safehandlingKeep formation of airborne dusts to a minimum.

6 Provide appropriate exhaust ventilation at placeswhere dust is formed. Avoid inhalation of dust. Avoid inhalation of fumes from heated contact with skin and eyes. Wear appropriate personal protective equipment (See Section8). Do not eat, drink or smoke when using the product. Avoid release to the Conditions for safestorage, including anyincompatibilitiesStore in tightly closed original container in a dry, cool and well-ventilated place. Keep away fromfood, drink and animal feeding stuffs. Store away from incompatible Specific end use(s)Flux Brazing or SolderingSECTION 8: Exposure controls/personal Control parametersOccupational exposure limitsUK. EH40 Workplace Exposure Limits (WELs) mg/m3 Potassium fluoborate (CAS14075-53-7) mg/m3 Potassium fluorosili cate (CAS 16871-90-2)EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161 mg/m3 Potassium fluoborate (CAS14075-53-7) mg/m3 Potassium fluorosili cate (CAS 16871-90-2)ECO Smart Boric Acid Free Flux - PowderSDS UK914077 Version No.

7 : 01 Revision date: - Issue date: 23-July-20133 / 7 Biological limit valuesNo biological exposure limits noted for the ingredient(s).Recommended monitoringproceduresFollow standard monitoring no-effect level (DNEL)Not no effectconcentrations (PNECs)Not Exposure controlsAppropriate engineeringcontrolsProvide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk ofinhalation of dust. Shower, hand and eye washing facilities near the workplace are protection measures, such as personal protective equipmentGeneral informationPersonal protective equipment should be chosen according to the CEN standards and indiscussion with the supplier of the personal protective protectionWear SAFETY glasses with side shields (or goggles).Skin protection- Hand protectionWear chemical-resistant, impervious gloves. Suitable gloves can be recommended by the OtherWear appropriate chemical resistant protectionIf engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be hazardsWear appropriate thermal protective clothing, when measuresAlways observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking.

8 Routinely wash work clothing and protectiveequipment to remove exposurecontrolsContain spills and prevent releases and observe national regulations on 9: Physical and chemical Information on basic physical and chemical propertiesAppearancePhysical thresholdNot point/freezing pointNot boiling point and boilingrangeNot pointNot rateNot (solid, gas)Non flammability or explosive limitsFlammability limit - lower(%) Not limit - upper(%) Not pressureNot densityNot densityNot (ies)Not coefficient(n-octanol/water) No data temperatureNot temperatureNot Smart Boric Acid Free Flux - PowderSDS UK914077 Version No.: 01 Revision date: - Issue date: 23-July-20134 / 7 ViscosityNot propertiesNot propertiesNot Other informationNo relevant additional information 10: Stability and ReactivityStable at normal Chemical stabilityStable under normal storage and handling Possibility of hazardousreactionsMay be corrosive to Conditions to avoidContact with incompatible Incompatible materialsStrong acids.

9 Reactive Hazardousdecomposition productsHydrogen fluoride, fluorine-, boron- and potassium-containing 11: Toxicological informationGeneral informationOccupational exposure to the substance or mixture may cause adverse on likely routes of exposureIngestionHarmful if by inhalation. Dust may irritate respiratory system. When heated, the vapours/fumesgiven off may cause respiratory tract contactHarmful in contact with contactMay cause eye irritation on direct fluoride can cause metabolic imbalances with irregular heartbeat, nausea, dizziness,vomiting and Information on toxicological effectsAcute toxicityHarmful by inhalation, in contact with skin and if resultsComponentsSpeciesBoron (CAS 7440-42-8)LD50 RatOralAcute650 mg/kgSkin corrosion/irritationMay cause skin eye damage/eyeirritationMay cause eye irritation on direct sensitisationNo data sensitisationThis product is not expected to cause skin cell mutagenicityNo data toxicityDue to lack of data the classification is not target organ toxicity -single exposureInhalation of dusts may cause respiratory target organ toxicity -repeated exposureNot hazardNot applicable for versus substanceinformationNot informationRepeated exposure to fluorides may cause excessive calcification of the bone and calcification ofligaments of the ribs, pelvis and spinal column.

10 Exposure to extremely high levels of fluorides cancause abdominal pain, diarrhea, muscular weakness, and convulsions. In extreme cases it cancause loss of consciousness and 12: Ecological ToxicityNo toxicity data noted for the ingredient(s). Persistence anddegradabilityNo data is available on the degradability of this Bioaccumulative potentialNo data Smart Boric Acid Free Flux - PowderSDS UK914077 Version No.: 01 Revision date: - Issue date: 23-July-20135 / 7 Partition coefficientn-octanol/water (log Kow)No data factor (BCF)Not Mobility in soilThis product is water soluble and may disperse in Results of PBTand vPvBassessmentNot a PBT or vPvB substance or Other adverse effectsAn environmental hazard cannot be excluded in the event of unprofessional handling or 13: Disposal Waste treatment methodsResidual wasteDispose of in accordance with local packagingSince emptied containers may retain product residue, follow label warnings even after container waste codeWaste codes should be assigned by the user based on the application for which the product methods/informationThis material and its container must be disposed of as hazardous waste.