SAFETY DATA SHEET MarClean SC - TECO Maritime

1 Revision date The SAFETY data SHEET complies with Commission Regulation (EU) 2017/1000 of 14 June 2017 amending the European Parliament and Council Regulation (EC) No 1907/2006 on the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) 1. Identification of the substance/preparation and of the company/responsible party Date issued Revision date Product name MarClean SC Product group Detergent. Use of the substance/preparation Heavy duty, Alkaline tank cleaning and degreasing agents. For removal of for IG soot, mineral oils, petroleum products hydrocarbons, palm and vegetable oils. Manufacturer Distributor AS EIVIND BROSSTAD 1215 Oslo Norway TECO CHEMICALS AS Lysaker torg 12 1326 Lysaker Oslo NORWAY +47 67 200 300 966 091 029 Gaurav Saini / Thomas Bertel / Magnor M.

2 Skogvold National Institute of Technology as, Norway v/ Knut Finsveen Norwegian poison information center:+47 22 59 13 00 2. Hazards identification Eye Dam,. 1;H318 / Skin irrit 2; H315 See section 16 for complete hazards 3. Composition/information on ingredients Substance Identification Classification Contents Sodium metasilicate 5 aq CAS no.: 10213-79-3 C; R34 Xi; R37 1 - 5 % SAFETY data SHEET MarClean SC Tetrapotassium pyrophosphate CAS no.: 7320-34-5 Xi; R36 5 - 10 % Company name Postcode City Country Company name Postal address Postcode City Country Tel E-mail Website Enterprise no. Contact person Prepared by Emergency telephone Classification according to CLP (EC) No 1272/2008 [CLP/GHS] Additional Information about classification Revision date EC no.

3 : 230-785-7 Eye Irrit. 2;H319 Alkylglucocide, C6 CAS no.: 54549-24-5 EC no.: 259-217-6 Xi; R41 Eye Dam. 1; H318; 5 - 10 % Alcohols, C9-11, ethoxylated CAS no.: 68439-46-3 Xi; R41 Eye Dam. 1;H318 10 - 30 % Water CAS no.: 7732-18-5 EC no.: 231-791-2 60 - 100 % Column headings CAS no. = Chemical Abstracts Service; EU (Einecs or Elincs number) = European inventory of Existing Commercial Chemical Substances; Ingredient name = Name as specified in the substance list (substances that are not included in the substance list must be translated, if possible). Contents given in; %, %wt/wt, %vol/wt, %vol/vol, mg/m3, ppb, ppm, weight%, vol% HH/HF/HE T+ = Very toxic, T = Toxic, C = Explosive, O = Oxidizing, N = Environmental hazard = Corrosive, Xn = Harmful, Xi F+ = Extremly flammable, F = V = Irritating, E ery flammable, Substance comments See section 16 for explanation of Risk-phrases listed above.

4 4. First aid measures If in doubt, seek medical advice. Fresh air and rest. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Immediately remove contaminated clothing. Flush skin thoroughly with water. Get medical attention if irritation persists after washing. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Obtain medical attention and bring these instructions. Continue rinsing during transportation to a physician. By prolonged rinsing, use luke warm water to avoid damage to the eye. Do not induce vomiting. Drink a few glasses of water or milk. Seek medical attention. 5. Firefighting measures Foam, carbon dioxide or dry powder. Dry chemicals, sand, dolomite etc. Do not use water jet.

5 The chemical is non-combustible. Fire or high temperatures create: Carbon dioxide (CO2). Carbon monoxide (CO). Containers close to fire should be removed or cooled with water. 6. Accidental release measures Use protective equipment as referred to in section 8. Do not allow to enter into sewer, water system or soil. Remove spillage with absorbent materials. Collect in a suitable container and dispose as hazardous waste according to section 13. Flush area with water. 7. Handling and storage Avoid contact with skin and eyes. Change contaminated clothing. Store above freezing. Store in original container at room temperature. Store in tightly closed container. 8. Exposure controls/personal protection General Inhalation Skin contact Eye contact Ingestion Suitable extinguishing media Improper extinguishing media Fire and explosion hazards Fire fighting procedures Personal protection measures Environmental precautionary measures Cleaning method Handling Storage Revision date Exposure controls Provide adequate ventilation.

6 Do not eat, drink or smoke during work. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Normally not required. When spraying: In case of aerosol formation, use mask with filter P2. Use gloves from resistant material, eg.: PVC or rubber gloves are recommended. Penetration time is not known. The recommended material of gloves is recommended after a study of the single components in the chemical. If risk of splashing, wear SAFETY goggles or face shield. If the product is to be sprayed: Wear suitable protective clothing as protection against splashing or contamination. Wear rubber footwear. Eye wash facilities and emergency shower should be available when handling this chemical. The listed protective equipment is a recommendation.

7 A risk assessment of the actual risk may lead to other requirements. 9. Physical and chemical properties Fluid. Slight. Characteristic. Lightly coloured. Yellow. Easily soluble. Value: 1,078 g/ml at 15 C Value: 100 C Value: 12,5-13 5% solution: pH 11,8 1% solution: pH 10,7 0,5% solution: pH 9,8 Value: 26 cP 10. Stability and reactivity Avoid frost. Strong oxidizing agents. Do not mix with other detergents. Fire or high temperatures create: Carbon monoxide (CO). Carbon dioxide (CO2). Stable under normal temperature conditions and recommended use. 11. Toxicological information Other information regarding health hazards Spray mist may irritate the respiratory system. Irritating to skin. May be degreasing after frequent contact. Risk of serious damage to eyes. The product causes irritation of mucous membranes and may cause abdominal discomfort if swallowed.

8 No known chronic or acute health hazards. Sensitizing properties are not known. Carcinogenic properties are not known. Effects on fetus development are not known. Effects harmful to reproduction are not known. Mutagenic properties are not known. Occupational exposure limits Respiratory protection Hand protection Eye protection Skin protection (except hands) Other Information Physical state Odour Colour Solubility in water Specific gravity Comments, Specific gravity Boiling point / boiling range pH (as supplied) Comments, pH (aqueous solution) Viscosity Conditions to avoid Materials to avoid Hazardous decomposition products Stability Inhalation Skin contact Eye contact Ingestion Chronic effects Sensitisation Carcinogenicity Teratogenic properties Reproductive toxicity Mutagenicity Revision date 12.

9 Ecological information Toxicological Information: Sodium metasilicate 5 aq: Acute fish (LC50) > 2320 mg/l, 96h (CESIOs) Tetrapotassium pyrophosphate: Acute fish (LC50) > 750 mg/l, 48h, (CESIOs) Alcohols, C9-11, ethoxylated: Acute fish (LC50) 10-100 mg/l, 96h, (CESIOs) alkylglucocide, C6: Acute Daphnia (EC50) > 490 mg/l, 48h, (CESIOs) Other environmental information Large amounts of the product may affect the acidity (pH-factor) in water with possible risk of harmful effects to aquatic organisms. Soluble in water. The product contains surfactants with an average biodegradability of 90% or more. Not expected to bioaccumulate. With phosphate. Content of phosphorous: < 2,5% 13. Disposal considerations EWC: 07 06 01 aqueous washing liquids and mother liquors Yes Disposed of as hazardous waste by approved contractor.

10 The waste code (EWC-Code) is intented as a guide. The code must be chosen by the user, if the use differs from the one mentioned below. 14. Transport information Not considered as dangerous goods under UN, IMO, ADR/RID or IATA/ICAO regulations. 15. Regulatory information Hazard symbol R-phrases R38 Irritating to skin. R41 Risk of serious damage to eyes. S-phrases S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 Wear suitable gloves and eye/face protection. WITH PHOSPHATE. Content of phosphorous: < 2,5%%. Other Label Information Content according to Regulation (EC) No 648/2004 on detergents: 15-30% non-ionic surfactants. 5-15% phosphates. Aquatic, comments Additional information. Ecotoxicity Mobility Persistence and degradability Bioaccumulative potential Other adverse effects / Remarks EWC waste code Product classified as hazardous waste Specify the appropriate methods of disposal Revision date FOR 2002-07-16 nr 1139; Norwegian regulation on classification and labelling of dangerous chemicals with later amendments.