SAFETY DATA SHEET - marichem

1 1 SAFETY data SHEET In compliance with EC Regulations No.: 1907/2006 and 453/2010. Date last modified: 03 January 2018 - Version 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY Product Identifier Product Name: PRELOAD 300 Product Code #: 923004 (30 lts), 922104 (210 lts) Relevant identified uses of the substance or mixture and uses advised against Intended Use: Industrial applications; Coating for cargo holds. Uses advised against: This product is not recommended for any industrial, professional or consumer use other than the Intended Uses above. Details of the supplier of the SAFETY data SHEET Company/undertaking identification Supplier/Manufacturer: marichem Marigases Hellas SA Sfaktirias 64, 185 45 Piraeus, Greece Tel.

2 No.: ++30 210 4148800 Fax No.: ++30 210 4133985 e-mail: Emergency telephone number Tel. No.: ++30 210 4148800 (including working hours) Emergency Information: Inside and Canada: (800)-424-9300 (CHEMTREC) Outside and Canada: 1-703-527-3887 (CHEMTREC) National Emergency Centre (Greece): ++30 210 7793777 2 2. HAZARDS IDENTIFICATION Classification of the mixture Classification under EC 1272/2008 regulation - GHS classification. No need for classification according to GHS criteria for this product. Label Elements Labelling according to Regulation (EC) No. 1272/2008. The substance is classified and labelled according to the CLP Regulation.

3 The product does not require a hazard warning label in accordance with GHS criteria. Product classification and labelling according to Directive 67/548/EEC, European Dangerous Preparations Directive (1999/45/EC), European Regulation 648/2004 and their amendments. The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments. No special labeling information required according to EU directives. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Composition: Ingredients CAS Number Proportion Classification* Preparation based on: (2-Methoxymethylethoxy) propanol Mixture 5% - 10% - Ingredients that do not contribute to the classification of the substance - 90% - 95% - *See section 16 for the full text of the Hazard Code(s) declared above.

4 Occupational Exposure Limits, if available, are listed in section 8. 4. FIRST AID MEASURES Description of first aid measures Remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. 3 On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth immediately and then drink plenty of water, seek medical attention. Most important symptoms and effects, both acute and delayed Symptoms: No significant symptoms are expected due to the non-classification of the product.

5 Hazards: No hazard is expected under intended use and appropriate handling. Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions) - no known specific antidote. 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable extinguishing media: water spray, dry powder, foam, carbon dioxide Special hazards arising from the substance or mixture The product is combustible. Cool endangered containers with water-spray. Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information: Contaminated extinguishing water must be disposed of in accordance with official regulations.

6 Keep containers cool by spraying with water if exposed to fire. Foam should be applied in large quantities as it is broken down to some extent by the product. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Handle in accordance with good industrial hygiene and SAFETY practice. Environmental precautions Discharge into the environment must be avoided. Methods and material for containment and cleaning up For large amounts: Pump off product. For residues: Pick up with suitable absorbent material ( sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.

7 Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13. 4 7. HANDLING AND STORAGE Precautions for safe handling Ensure thorough ventilation of stores and work areas. Prevent contact with air/oxygen (formation of peroxide). Protection against fire and explosion: Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy. Conditions for safe storage, including any incompatibilities Further information on storage conditions: Containers should be stored tightly sealed in a dry place. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

8 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with occupational exposure limits: 34590-94-8: (2-Methoxymethylethoxy) propanol TWA value 308 mg/m3 ; 50 ppm (OEL (EU)) indicative Skin Designation (OEL (EU)) The substance can be absorbed through the skin. 57-55-6: Propane-1,2-diol PNEC freshwater: 19 mg/l marine water: mg/l intermittent release: 190 mg/l STP: 4168 mg/l sediment (freshwater): mg/kg sediment (marine water): mg/kg soil: mg/kg oral (secondary poisoning): No PNEC oral derived, as accumulation in organisms is not to be expected. DNEL worker: Long-term exposure- systemic effects, dermal: 65 mg/kg worker: Long-term exposure- systemic effects, Inhalation: 310 mg/m3 consumer: Long-term exposure- systemic effects, dermal: 15 mg/kg consumer: Long-term exposure- systemic effects, Inhalation: mg/m3 consumer: 5 Long-term exposure- systemic effects, oral: mg/kg Exposure controls Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate.

9 Gas filter for gases/vapours of organic compounds (boiling point >65 C, e. g. EN 14387 Type A) Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): butyl rubber (butyl) - mm coating thickness Manufacturer's directions for use should be observed because of great diversity of types. Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions ( temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

10 Eye protection: SAFETY glasses with side-shields (frame goggles) ( EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust). General SAFETY and hygiene measures: Handle in accordance with good industrial hygiene and SAFETY practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Physical State: Clear liquid Color: Pale Odor: Slight ethereal Basic data Melting Point Range: Not Determined 6 Solubility in water: Soluble Flash Point: Not Applicable Autoignition Temperature: Not Available Lower Explosion Limit (vol %): Not Applicable Upper Explosion Limit (vol %): Not Applicable Relative vapor density (air=1): Not Available Specific Gravity: gr/cm3 at 15oC pH.