Safety Data Sheet Methanol - SAL Chem

1 Safety Data Sheet Methanol Version Date: 10/14/2014 MSDS Number: 100000002748 1 / 20 Methanol SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name:MethanolProduct Use Descrip-tion :Industrial chemical Manufacturer or supplier's details Company:Nexeo Solutions LLCA ddress 3 Waterway Square Place Suite 1000 Woodlands, Tx. 77380 United States of AmericaEmergency telephone number: Health North America: 1-855-NEXEO4U (1-855-639-3648) Health International: 1-855-NEXEO4U (1-855-639-3648) Transport North America: CHEMTREC Informa-tion: :Responsible Party: Product Safety Group E-Mail: SDS Requests: 1-855-429-2661 SDS Requests Fax: 1-281-500-2370 Website: 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids :Category 2 Acute toxicity (Oral) :Category 3 Acute toxicity (Inhalation):Category 3 Acute toxicity (Dermal) :Category 3 Carcinogenicity :Category 2 Reproductive toxicity :Category 2 Specific target organ tox-icity - single exposure :Category 1 (Eyes, Central nervous system) GHS Label element Distributed by:SAL Chemical3036 Birch DriveWeirton, WV 26062304-748-8200 Safety Data Sheet Methanol Version Date: 10/14/2014 MSDS Number: 100000002748 2 / 20 Methanol Hazard pictograms :Signal word :Danger Hazard statements :H225 Highly flammable liquid and vapour.

2 H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaledH351 Suspected of causing cancer. H361 Suspected of damaging fertility or the unborn Causes damage to organs (Eyes, Central nervous system).Precautionary statements :Prevention: P201 Obtain special instructions before use. P202 Do not handle until all Safety precautions have been read and Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ Use only non-sparking tools. P243 Take precautionary measures against static Do not breathe dust/ fume/ gas/ mist/ vapours/ Wash skin thoroughly after handling.

3 P270 Do not eat, drink or smoke when using this Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ eye protection/ face Use personal protective equipment as required. Response: P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Rinse + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ + P340 + P311 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician. P307 + P311 IF exposed: Call a POISON CENTER or doctor/ Wash contaminated clothing before reuse. Safety Data Sheet Methanol Version Date: 10/14/2014 MSDS Number: 100000002748 3 / 20 Methanol P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.

4 Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal Health Effects Carcinogenicity: IARCNo component of this product present at levels greater than or equal to is identified as probable, possible or confirmed human carcinogen by component of this product present at levels greater than or equal to is identified as a carcinogen or potential carcinogen by component of this product present at levels greater than or equal to is identified as a carcinogen or potential carcinogen by component of this product present at levels greater than or equal to is identified as a known or antic-ipated carcinogen by Overview Appearance liquid Colour colourless, clear Odour mild, alcohol-like Hazard Summary No information available.

5 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture :Pure substance Hazardous components CAS-No. Chemical Name Concentration (%) 67-56-1 Methanol90 - 100 Safety Data Sheet Methanol Version Date: 10/14/2014 MSDS Number: 100000002748 4 / 20 Methanol Molecular formula :C-H4-O Synonyms :Methyl alcohol,SECTION 4. FIRST AID MEASURES General advice :Move out of dangerous area. Consult a this Safety data Sheet to the doctor in not leave the victim a inhaled :If unconscious place in recovery position and seek medical symptoms persist, call a case of skin contact :If on skin, rinse well with water. If on clothes, remove off contaminated clothing and shoes victim immediately to case of eye contact :Flush eyes with water as a precaution.

6 Remove contact unharmed eye wide open while eye irritation persists, consult a swallowed :Keep respiratory tract clear. Do not give milk or alcoholic give anything by mouth to an unconscious symptoms persist, call a victim immediately to give anything by mouth to an unconscious accidentally swallowed obtain immediate medical 5. FIREFIGHTING MEASURES Suitable extinguishing media :Alcohol-resistant foam Carbon dioxide (CO2) Safety Data Sheet Methanol Version Date: 10/14/2014 MSDS Number: 100000002748 5 / 20 Methanol Dry chemical Unsuitable extinguishing media:High volume water jet Specific hazards during firefighting:Do not allow run-off from fire fighting to enter drains or water not use a solid water stream as it may scatter and spread closed containers exposed to fire with water combustion products:No hazardous combustion products are known Specific extinguishing methods:Use a water spray to cool fully closed containers.

7 Further information :Collect contaminated fire extinguishing water sepa-rately. This must not be discharged into residues and contaminated fire extinguishing wa-ter must be disposed of in accordance with local Safety reasons in case of fire, cans should be stored separately in closed residues and contaminated fire extinguishing wa-ter must be disposed of in accordance with local protective equip-ment for firefighters:Wear self-contained breathing apparatus for firefight-ing if the event of fire, wear self-contained breathing apparatus. NFPA Flammable and Combustible Liquids Classification: Flammable Liquid Class IB SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures:Use personal protective equipment.

8 Ensure adequate all sources of personnel to safe areas. Safety Data Sheet Methanol Version Date: 10/14/2014 MSDS Number: 100000002748 6 / 20 Methanol Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. :Use personal protective equipment. Ensure adequate all sources of personnel to safe can create slippery precau-tions:Prevent product from entering drains. Prevent further leakage or spillage if safe to do the product contaminates rivers and lakes or drains inform respective authorities should be advised if significant spil-lages cannot be and materials for containment and cleaning up:Contain spillage, and then collect with non-combustible absorbent material, ( sand, earth, diatomaceous earth, vermiculite) and place in con-tainer for disposal according to local / national regula-tions (see section 13).

9 Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental 7. HANDLING AND STORAGE Advice on safe handling :Avoid formation of aerosol. Do not breathe exposure - obtain special instructions before contact with skin and personal protection see section , eating and drinking should be prohibited in the application precautionary measures against static dis-charges. Provide sufficient air exchange and/or exhaust in work may be opened only under exhaust ventila-tion drum carefully as content may be under of rinse water in accordance with local and national contact with skin and eyes. Safety Data Sheet Methanol Version Date: 10/14/2014 MSDS Number: 100000002748 7 / 20 Methanol For personal protection see section 8.

10 Smoking, eating and drinking should be prohibited in the application away from for safe sto-rage:No smoking. Keep container tightly closed in a dry and well-ventilated which are opened must be carefully re-sealed and kept upright to prevent label installations / working materials must comp-ly with the technological Safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parametersCAS-No. Components Value type (Form of exposure)Control parame-ters / Permissi-ble concentra-tion Basis 67-56-1 MethanolTWA200 ppmACGIHSTEL250 ppmACGIHTWA200 ppm 260 mg/m3 NIOSH RELST250 ppm 325 mg/m3 NIOSH RELTWA200 ppm 260 mg/m3 OSHA Z-1 STEL250 ppm 325 mg/m3 OSHA P0 TWA200 ppm 260 mg/m3 OSHA P0 Biological occupational exposure limits Components CAS-No.