SAFETY DATA SHEET NALCO® 71D5 PLUS - Emerald

1 SAFETY data SHEET . nalco 71d5 plus . Section: 1. PRODUCT AND COMPANY IDENTIFICATION. Product name : nalco 71d5 plus . Other means of identification : Not applicable. Recommended use : ANTIFOAM. Restrictions on use : Refer to available product literature or ask your local Sales Representative for restrictions on use and dose limits. Company : nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198. USA. TEL: (630)305-1000. Emergency telephone : (800) 424-9300 (24 Hours) CHEMTREC. number Issuing date : 01/06/2014. Section: 2. HAZARDS IDENTIFICATION. Emergency Overview WARNING. Combustible. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. Keep away from heat. Keep away from sources of ignition - No smoking. Keep container tightly closed. Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid breathing vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

2 After contact with skin, wash immediately with plenty of water. Use a mild soap if available. Wear suitable protective clothing, gloves and eye/face protection. Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Potential Health Effects Eyes : Health injuries are not known or expected under normal use. Skin : May be harmful in contact with skin. Ingestion : May be fatal if swallowed and enters airways. Inhalation : Health injuries are not known or expected under normal use. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS. Chemical Name CAS-No. Concentration: (%). Straight Run Middle Distillate 64741-44-2 - Paraffin Wax 8002-74-2 - Aliphatic alcohol Proprietary - Aliphatic alcohol Proprietary - Hydrotreated Light Distillate 64742-47-8 - 1 / 11. SAFETY data SHEET . nalco 71d5 plus . Section: 4. FIRST AID MEASURES. In case of eye contact : Rinse with plenty of water. Get medical attention if symptoms occur.

3 In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists. If swallowed : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Aspiration hazard if swallowed - can enter lungs and cause damage. Get medical attention immediately. If inhaled : Get medical attention if symptoms occur. Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency personal protective equipment as required. Notes to physician : Treat symptomatically. See toxicological information (Section 11). Section: 5. FIREFIGHTING MEASURES. Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing : High volume water jet media Specific hazards during : Fire Hazard firefighting.

4 Keep away from heat and sources of ignition. Flash back possible over considerable distance. Hazardous combustion : Carbon oxides products Special protective equipment : Use personal protective equipment for firefighters Specific extinguishing : Use water spray to cool unopened containers. Fire residues methods and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Section: 6. ACCIDENTAL RELEASE MEASURES. Personal precautions, : Remove all sources of ignition. Ensure clean-up is conducted by protective equipment and trained personnel only. Refer to protective measures listed in emergency procedures sections 7 and 8. Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for : Eliminate all ignition sources if safe to do so. Stop leak if safe to do containment and cleaning up so. Contain spillage, and then collect with non-combustible absorbent material, ( sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local /.

5 National regulations (see section 13). Flush away traces with water. 2 / 11. SAFETY data SHEET . nalco 71d5 plus . For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Do not flush into surface water or sanitary sewer system. Section: 7. HANDLING AND STORAGE. Advice on safe handling : Avoid contact with skin and eyes. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Keep away from fire, sparks and heated surfaces. Wash hands thoroughly after handling. Use only with adequate ventilation. Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well- ventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Packaging material : Suitable material: Keep in properly labelled containers. Unsuitable material: not determined Section: 8.

6 EXPOSURE CONTROLS/PERSONAL PROTECTION. Components with workplace control parameters Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Basis Components CAS-No. Form of Permissible exposure concentration Oil Mist TWA 5 mg/m3 OSHA Z1. TWA 5 mg/m3 ACGIH. (Inhalable fraction). TWA (Mist) 5 mg/m3 NIOSH REL. STEL (Mist) 10 mg/m3 NIOSH REL. Paraffin Wax Fume 8002-74-2 TWA 2 mg/m3 ACGIH. TWA 2 mg/m3 NIOSH REL. (Fumes). Hydrotreated Light Distillate 64742-47-8 TWA 500 ppm OSHA Z1. 2,000 mg/m3. TWA 200 mg/m3 ACGIH. Polypropylene Glycol 25322-69-4 TWA 10 mg/m3 WEEL. 1-Octanol 111-87-5 TWA 50 ppm WEEL. Paraffin Wax 8002-74-2 TWA 2 mg/m3 ACGIH. TWA 2 mg/m3 NIOSH REL. (Fumes). Heavy Aromatic Naphtha 64742-94-5 TWA 500 ppm OSHA Z1. 2,000 mg/m3. TWA 200 mg/m3 ACGIH. Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.

7 Personal protective equipment Eye protection : SAFETY glasses 3 / 11. SAFETY data SHEET . nalco 71d5 plus . Hand protection : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Skin protection : Wear suitable protective clothing. Respiratory protection : No personal respiratory protective equipment normally required. Hygiene measures : Handle in accordance with good industrial hygiene and SAFETY practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. HUMAN EXPOSURE CHARACTERIZATION : Based on our recommended product application and personal protective equipment, the potential human exposure is: Moderate Section: 9. PHYSICAL AND CHEMICAL PROPERTIES. Appearance : Liquid Colour : Clear Light yellow Odour : Hydrocarbon Flash point : 92 C. Method: ASTM D 93, Pensky-Martens closed cup pH : Not applicable.

8 Odour Threshold : no data available Melting point/freezing point : 10 C. -45 C ASTM D-1177. Initial boiling point and boiling : C Method: ASTM D 86. range Evaporation rate : no data available Flammability (solid, gas) : no data available Upper explosion limit : no data available Lower explosion limit : no data available Vapour pressure : mm Hg ( C). Relative vapour density : no data available Relative density : (25 C) ASTM D-1298. Density : no data available Water solubility : insoluble Solubility in other solvents : no data available Partition coefficient: n- : no data available octanol/water Auto-ignition temperature : no data available Thermal decomposition : Carbon oxides 4 / 11. SAFETY data SHEET . nalco 71d5 plus . Viscosity, dynamic : 10 ( C). Method: ASTM D 2983. Viscosity, kinematic : mm2/s (40 C). Method: ASTM D 445. VOC : %. Section: 10. STABILITY AND REACTIVITY. Chemical stability : Stable under normal conditions. Possibility of hazardous : No dangerous reaction known under conditions of normal use.

9 Reactions Conditions to avoid : Heat, flames and sparks. Incompatible materials : Contact with strong oxidizers ( chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Bases Contact with strong alkalies ( ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites). may generate heat, splattering or boiling and toxic vapors. Hazardous decomposition : Oxides of carbon products Section: 11. TOXICOLOGICAL INFORMATION. Information on likely routes of : Inhalation, Eye contact, Skin contact exposure Potential Health Effects Eyes : Health injuries are not known or expected under normal use. Skin : May be harmful in contact with skin. Ingestion : May be fatal if swallowed and enters airways. Inhalation : Health injuries are not known or expected under normal use.

10 Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : No symptoms known or expected Skin contact : Redness, Irritation Ingestion : Vomiting Inhalation : No symptoms known or expected Toxicity Product 5 / 11. SAFETY data SHEET . nalco 71d5 plus . Acute oral toxicity : LD50 rat: > 15,380 mg/kg Test substance: Product Acute inhalation toxicity : no data available Acute dermal toxicity : LD50 rabbit: > 3,038 mg/kg Test substance: Product Skin corrosion/irritation : Species: Rabbit Result: Method: Draize Test Test substance:Product Serious eye damage/eye : Species: rabbit irritation Result: Method: Draize Test Test substance: Product Respiratory or skin : no data available sensitization Carcinogenicity IARC No component of this product present at levels greater than or equal to is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to is identified as a carcinogen or potential carcinogen by OSHA.