SAFETY DATA SHEET - Palmer Holland

1 STABAXOL I LFSAFETY data SHEETP roduct identifierIn case of emergencySection 1. Identification::Chemical name:bis(2,6-diisopropylphenyl)carbodimi deIdentified usesAntihydrolysis AgentMaterial Number:56380799:Supplier/Manufacturer:LA NXESS CorporationRhein Chemie Additives111 RIDC Park West DrivePittsburgh, PA 15275-1112 USAFor information: US/Canada (800) LANXESSI nternational +1 412 809 1000 Chemtrec (800) 424-9300 International (703) 527-3887 Lanxess Emergency Phone (800) 2. Hazards identificationACUTE TOXICITY (oral) - Category 4 TOXIC TO REPRODUCTION (Fertility) - Category 1 BTOXIC TO REPRODUCTION (Unborn child) - Category 1 BSPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood system,gastrointestinal tract, heart, kidneys and lymphatic system) - Category 1 Classification of the substance or mixture:Signal word:DangerHazard statements:Harmful if swallowed. May damage fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure.

2 (blood system, gastrointestinal tract,heart, kidneys, lymphatic system)Hazard pictograms:Precautionary statementsPrevention:Obtain special instructions before use. Do not handle until all SAFETY precautions have been read and understood. Wear protective gloves/clothing and eye/face not breathe dust. Do not eat, drink or smoke when using this product. Wash hands thoroughly after :Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF SWALLOWED: Rinse :Store locked :Dispose of contents and container in accordance with all local, regional, national and international Standard Status:This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ).Physical :Colorless to light Not Otherwise Classified (HNOC):None I LF1/9563807995 VersionSection 2. Hazards identificationSupplemental label elements:Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and 3.

3 Composition/information on ingredients2,2',6,6'-Tetraisopropyldiphe nyl Carbodiimide1002162-74-5 Ingredient nameCAS number%There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this name:bis(2,6-diisopropylphenyl)carbodimi deCAS number:2162-74-5 Substance/mixture:Occupational exposure limits, if available, are listed in Section concentration shown as a range is to protect confidentiality or is due to batch out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs.

4 Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed.

5 The exposed person may need to be kept under medical surveillance for 48 hours. If not breathing, if breathing is irregulor or respiratory arrest occurs, provide artifical respiration, or oxygen by a trained professional, using a pocket type 4. First aid measuresEye contactSkin contactInhalationIngestion::::Descriptio n of first aid measuresInhalation:No known significant effects or critical if swallowed.:IngestionSkin contact:No known significant effects or critical known significant effects or critical hazards.:Eye contactOver-exposure signs/symptomsSkin contactIngestionInhalationNo specific of ingestion may include abdominal pain, nausea, vomiting, and specific data .:::Eye contact:No specific acute health effectsPotential chronic health effectsSTABAXOL I LF2/9563807995 VersionSection 4. First aid measuresProtection of first-aiders:No special measures to physician:Treat symptomatically. No specific toxicological information (Section 11)Causes damage to organs through prolonged or repeated exposure.

6 May damage fertility or the unborn 5. Fire-fighting measuresPromptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable thermal decomposition productsSpecific hazards arising from the chemicalIn the event of fire, carbon monoxide, nitrogen oxides, isocyanate vapour, and traces of hydrogen cyanide may be specific fire or explosion should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure protective equipment for fire-fightersUse an extinguishing agent suitable for the surrounding fire. In case of fire, use water spray (fog), foam or dry media:::None extinguishing media:Unsuitable extinguishing media:Special protective actions for fire-fighters:Section 6. Accidental release measuresEnvironmental precautionsPersonal precautions,protective equipment and emergency proceduresMove containers from spill area.

7 Approach release from upwind. Avoid dust not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal : see Section 1 for emergency contact information and Section 13 for waste disposal. Prevent entry into sewers, water courses, basements or confined areas.:No action shall be taken involving any personal risk or without suitable surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate appropriate respirator when ventilation is inadequate. Put on appropriate personal protective dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).Methods and materials for containment and cleaning up::Section 7.

8 Handling and storageProtective measuresAvoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all SAFETY precautions have been read and not get in eyes or on skin or clothing. Do not ingest. Use only with adequate ventilation. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Remove contaminated clothing and protective equipment before entering eating areas. Workers should wash hands and face before eating, drinking and smoking. Put on appropriate personal protection equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed.:Precautions for safe handlingSTABAXOL I LF3/9563807995 VersionSection 7. Handling and storageConditions for safe storageStore in accordance with local regulations.

9 Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Empty containers retain product residue and can be hazardous. Do not reuse container.:2,2',6,6'-Tetraisopropyldiphe nyl CarbodiimideNoneSection 8. Exposure controls/personal protectionIngredient nameExposure limitsOccupational exposure limitsThe type of respiratory protection selected must comply with the requirements set forth in OSHA's Respiratory Protection Standard (29 CFR ). Whenever vapor or mist of isocyanate is present, it is mandatory to use a full-face positive pressure,supplied-air respirator or a self-contained breathing apparatus (SCBA) if the recommended exposure limit is exceeded or the airborne concentrations are not protection:Appropriate engineering controls:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working techniques should be used to remove potentially contaminated contaminated clothing before reusing.

10 Ensure that eyewash stations and SAFETY showers are close to the workstation measures:Personal protectionSkin protection:Wear suitable protective clothing and gloves. Suitable protective protection:If contact with product is possible, wear SAFETY glasses with side SurveillanceVapours with isocyanate content may be released in processing at high applicants who are assigned to an isocyanate work area should undergo a pre-placement medical evaluation. A history of eczema or respiratory allergies such as hay fever, are possible reasons for medical exclusion from isocyanate areas. Applicants who have a history of adult asthma should be restricted from work with with a history of prior isocyanate sensitization should be excluded from further work with isocyanates. A comprehensive annual medical surveillance program should be instituted for all employees who are potentially exposed to a worker has been diagnosed as sensitized to any isocyanate, no further exposure can be permitted.