SAFETY DATA SHEET Pine-Sol® Multi-Surface Cleaner - …

1 SAFETY DATA SHEETPine-Sol Multi-Surface Cleaner - Lemon Fresh - USRevision date: 16/05/2014 Supersedes date: 01/12/2011 Revision: 3 According to Regulation (EC) No 1907/2006, Annex II, as amended by Regulation (EU) No 453/2010 SECTION 1: Identification of the substance/mixture and of the Product identifierProduct namePine-Sol Multi-Surface Cleaner - Lemon Fresh - USProduct numberPS40187US, Relevant identified uses of the substance or mixture and uses advised againstIdentified usesAll purpose advised againstNo specific uses advised against are Details of the supplier of the SAFETY data sheetSupplierCbee Europe LtdEton House2nd Floor18-24 Paradise RoadRichmondTW9 1SE, UKTel: +44 (0) 208 614 7120 Fax: +44 (0) 208 940 Emergency telephone numberEmergency telephone+44 (0) 208 614 7120 Monday - Thursday:- 09:00 - 17:30 Friday:- 09:00 - 17:00 SECTION 2: Hazards Classification of the substance or mixtureClassificationPhysical hazardsNot ClassifiedHealth hazardsEye Irrit.

2 2 - H319 Elicitation - EUH208 Environmental hazardsNot ClassifiedClassification (67/548/EEC or 1999/45/EC)Xi; Label elementsPictogramSignal wordWarning1/11 Pine-Sol Multi-Surface Cleaner - Lemon Fresh - USSupersedes date: 01/12/2011 Revision date: 16/05/2014 Revision: 3 Hazard statementsH319 Causes serious eye Contains p-mentha-1,4(8)-diene. May produce an allergic statementsP102 Keep out of reach of Wash contaminated skin thoroughly after Wear eye and face +P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue +P313 If eye irritation persists: Get medical labelling< 5% non-ionic surfactants, < 5% perfumes, Contains CITRAL, GERANIOL, Other hazardsThis product does not contain any substances classified as PBT or 3: Composition/information on MixturesAlcohols, C10-14, ethoxylated1 - < number: 66455-15-0 EC number: ClassificationClassification (67/548/EEC or 1999/45/EC)Eye Irrit.

3 2 - H319Xi; R36/37 STOT SE 3 - H335p-mentha-1,4(8) - < number: 586-62-9 EC number: 209-578-0 ClassificationClassification (67/548/EEC or 1999/45/EC)Flam. Liq. 3 - H226Xn; R65. Xi; R38. N; R51/53. R10, R43 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 4: First aid Description of first aid measuresInhalationMove affected person to fresh air and keep warm and at rest in a position comfortable for mouth thoroughly with water. Give plenty of water to drink. Move affected person to fresh air and keep warm and at rest ina position comfortable for contactWash skin thoroughly with soap and contactRemove any contact lenses and open eyelids wide apart. Continue to Most important symptoms and effects, both acute and delayedInhalationIrritation of nose, throat and Multi-Surface Cleaner - Lemon Fresh - USSupersedes date: 01/12/2011 Revision date: 16/05/2014 Revision: 3 IngestionMay cause discomfort if contactProlonged skin contact may cause redness and irritation.

4 Allergic contactIrritation of eyes and mucous membranes. Prolonged contact may cause redness and/or Indication of any immediate medical attention and special treatment neededNotes for the doctorThe severity of the symptoms described will vary dependent on the concentration and the length of 5: Firefighting Extinguishing mediaSuitable extinguishing mediaExtinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for thesurrounding extinguishing mediaDo not use water jet as an extinguisher, as this will spread the Special hazards arising from the substance or mixtureHazardous combustion productsThermal decomposition or combustion products may include the following substances: Oxides of carbon. Toxic gases Advice for firefightersSpecial protective equipment for firefightersUse protective equipment appropriate for surrounding 6: Accidental release Personal precautions, protective equipment and emergency proceduresPersonal precautionsAvoid contact with eyes and prolonged skin contact.

5 Wear protective clothing as described in Section 8 of this SAFETY data Environmental precautionsEnvironmental precautionsAvoid discharge into drains or watercourses or onto the Methods and material for containment and cleaning upMethods for cleaning upAbsorb in vermiculite, dry sand or earth and place into containers. Containers with collected spillage must be properly labelledwith correct contents and hazard Reference to other sectionsReference to other sectionsSee Section 11 for additional information on health hazards. For waste disposal, see Section 7: Handling and Precautions for safe handlingUsage precautionsRead and follow manufacturer's on general occupational hygieneAvoid contact with eyes and prolonged skin Conditions for safe storage, including any incompatibilities3/11 Pine-Sol Multi-Surface Cleaner - Lemon Fresh - USSupersedes date: 01/12/2011 Revision date: 16/05/2014 Revision: 3 Storage precautionsStore in a cool and well-ventilated Specific end use(s)Specific end use(s)The identified uses for this product are detailed in Section 8: Exposure Controls/personal Control parametersOccupational exposure limitsIngredient commentsNo exposure limits known for ingredient(s).

6 Exposure controlsEye/face protectionWear chemical splash protectionNo specific hand protection measuresNo specific hygiene procedures recommended but good personal hygiene practices should always be observed when workingwith chemical 9: Physical and Chemical Information on basic physical and chemical propertiesAppearanceClear liquid. Viscous Grapefruit. thresholdNot (concentrated solution): 10 -11 Melting pointNot boiling point and rangeNot point> 93 C CC (Closed cup).Evaporation rateNot factorNot (solid, gas)Not flammability or explosive limitsNot pressureNot Multi-Surface Cleaner - Lemon Fresh - USSupersedes date: 01/12/2011 Revision date: 16/05/2014 Revision: 3 Vapour densityNot density1 Bulk densityNot (ies)Soluble in coefficientNot temperatureNot TemperatureNot cPExplosive propertiesNot considered to be propertiesThe mixture itself has not been tested but none of the ingredient substances meet the criteria for classification as Other informationOther informationNo information 10.

7 Stability and ReactivityThere are no known reactivity hazards associated with this Chemical stabilityStabilityStable at normal ambient temperatures and when used as Possibility of hazardous reactionsWill not Conditions to avoidAvoid excessive heat for prolonged periods of Incompatible materialsMaterials to avoidNo specific material or group of materials is likely to react with the product to produce a hazardous Hazardous decomposition productsNone at ambient temperatures. Thermal decomposition or combustion products may include the following substances: Oxides ofcarbon. Oxides of 11: Toxicological Information on toxicological effectsAcute toxicity - oralBased on available data the classification criteria are not toxicity - dermalBased on available data the classification criteria are not Multi-Surface Cleaner - Lemon Fresh - USSupersedes date: 01/12/2011 Revision date: 16/05/2014 Revision: 3 Acute toxicity - inhalationBased on available data the classification criteria are not corrosion/irritationAnimal dataBased on available data the classification criteria are not eye damage/irritationEye Irrit.

8 2 - H319 May cause severe eye sensitisationBased on available data the classification criteria are not sensitisationBased on available data the classification criteria are not cell mutagenicityGenotoxicity - in vitroBased on available data the classification criteria are not - in vivoBased on available data the classification criteria are not on available data the classification criteria are not toxicityReproductive toxicity - fertilityBased on available data the classification criteria are not toxicity - developmentBased on available data the classification criteria are not target organ toxicity - single exposureSTOT - single exposureBased on available data the classification criteria are not target organ toxicity - repeated exposureSTOT - repeated exposureBased on available data the classification criteria are not hazardNot anticipated to present an aspiration hazard, based on chemical information on Multi-Surface Cleaner - Lemon Fresh - USSupersedes date: 01/12/2011 Revision date: 16/05/2014 Revision: 3 Alcohols, C10-14, ethoxylatedAcute toxicity - oralAcute toxicity oral (LD50 mg/kg)3, on available data the classification criteria are not oral (mg/kg)3, toxicity - dermalAcute toxicity dermal (LD50 mg/kg) on available data the classification criteria are not dermal (mg/kg) eye damage/irritationEye Irrit.

9 2 - H319 Specific target organ toxicity - single exposureSTOT - single exposureSTOT SE 3 - H3357/11 Pine-Sol Multi-Surface Cleaner - Lemon Fresh - USSupersedes date: 01/12/2011 Revision date: 16/05/2014 Revision: 3p-mentha-1,4(8)-dieneAcute toxicity - oralAcute toxicity oral (LD50 mg/kg)3, dossier oral (mg/kg)3, toxicity - dermalAcute toxicity dermal (LD50 mg/kg) dossier dermal (mg/kg) corrosion/irritationAnimal dataSkin Irrit. 2 - H315 Causes skin eye damage/irritationDose: ml, 24 hours, Rabbit REACH dossier information. Not sensitisationLocal Lymph Node Assay (LLNA) - Mouse: Sensitising. REACH dossier cell mutagenicityGenotoxicity - in vitroChromosome aberration : Negative. REACH dossier - in vivoChromosome aberration : Negative. REACH dossier toxicityReproductive toxicity - fertilityScreening - NOAEL mg/kg/day, Oral, Rat P REACH dossier 12: Ecological ToxicityNot considered toxic to Multi-Surface Cleaner - Lemon Fresh - USSupersedes date: 01/12/2011 Revision date: 16/05/2014 Revision: 3 Ecological information on , C10-14, ethoxylatedAcute toxicity - fishLC , 96 hours: mg/l, Brachydanio rerio (Zebra Fish) REACH dossier toxicity - aquatic invertebratesEC , 48 hours: mg/l, Daphnia magna REACH dossier toxicity - aquatic plantsEC , 72 hours: mg/l, Pseudokirchneriella subcapitata REACH dossier toxicity - microorganismsEC , 3 hours: 46 mg/l, Activated sludge REACH dossier ,4(8)-dieneAcute toxicity - fishLC , 96 hours: mg/l, Brachydanio rerio (Zebra Fish) REACH dossier toxicity - aquatic invertebratesEC , 48 hours: mg/l, Daphnia magna REACH dossier toxicity - aquatic plantsEC , 72 hours.

10 Mg/l, Pseudokirchneriella subcapitata REACH dossier toxicity - microorganismsEC , 3 hours: 69 mg/l, Activated sludge REACH dossier Persistence and degradabilityPersistence and degradabilityThe surfactant(s) contained in this product complies(comply) with the biodegradability criteria as laid down in Regulation (EC)No. 648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the MemberStates and will be made available to them at their direct request, or at the request of a detergent information on , C10-14, ethoxylatedBiodegradationWater - Degradation (81%): 28 days REACH dossier ,4(8)-dieneBiodegradationWater - Degradation (81%): 28 days REACH dossier information. The substance is readily Bioaccumulative potentialNo data available on coefficientNot Mobility in soilMobilityThe product is soluble in Results of PBT and vPvB assessmentThis product does not contain any substances classified as PBT or Other adverse effectsNot 13: Disposal Waste treatment methods9/11 Pine-Sol Multi-Surface Cleaner - Lemon Fresh - USSupersedes date: 01/12/2011 Revision date: 16/05/2014 Revision: 3 General informationDispose of waste product or used containers in accordance with local regulationsSECTION 14: Transport informationGeneralThe product is not covered by international regulations on the transport of dangerous goods(IMDG, IATA, ADR/RID).