SAFETY DATA SHEET POLYAMINE B - Alliance …

1 SAFETY data SHEET according to Regulation (EC) No. 1907/2006 POLYAMINE B Version 1 Revision Date Print Date GB / EN 1/125 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name : POLYAMINE B Index-No. : 612-121-00-1 REACH Registration Number : 01-2119485823-28 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Specific use(s): Refer to attached exposure scenario Annex. Details of the supplier of the SAFETY data SHEET Company : Akzo Nobel Functional Chemicals AB Ethylene Amines ANC Stenungsund Stenunge All 3 SE 444 85 Stenungsund Sweden Telephone : 4630385000 Telefax : 46303770551 E-mail address : Emergency telephone number Emergency telephone number : 020 99 60 00 Kemiakuten, SE +31 57 06 79 211 AkzoNobel, NL SECTION 2: HAZARDS IDENTIFICATION Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Acute toxicity, 4, H302 Acute toxicity, 4, H312 Skin corrosion, 1B, H314 Skin sensitisation, 1, H317 Acute aquatic toxicity, 1, H400 Chronic aquatic toxicity, 1, H410 POLYAMINE B Version 1 Revision Date Print Date GB / EN 2 / 125 For the full text of the H-Statements mentioned in this Section, see Section 16.

2 Classification (67/548/EEC, 1999/45/EC) Corrosive, C, R34 Harmful, Xn, R21/22 Sensitising, Xi, R43 Dangerous for the environment, N, R50/53 For the full text of the R-phrases mentioned in this Section, see Section 16. Label elements Labelling (REGULATION (EC) No 1272/2008) Symbol(s) : Signal word : Danger Hazard statements : H302 + H312 Harmful if swallowed or in contact with skin H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.

3 Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ physician. Hazardous components which must be listed on the label: Polyethyleneamines 68131-73-7 Other hazards No further data available. POLYAMINE B Version 1 Revision Date Print Date GB / EN 3 / 125 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Substances Hazardous substance Chemical Name PBT vPvB OEL CAS-No. EC-No. REACH No. Classification (REGULATION (EC) No 1272/2008) Classification (67/548/EEC) Concentration [%] Polyethyleneamines 68131-73-7 268-626-9 01-2119485823-28 Acute Tox. 4; H302 Acute Tox. 4; H312 Skin Corr. 1B; H314 Skin Sens. 1; H317 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 M-Factor (Acute): 1 C; R34 Xn; R21/22 R43 N; R50-R53 100 The following substances have multiple CAS-number Polyethyleneamines : 29320-38-5 For the full text of the H-Statements mentioned in this Section, see Section 16.

4 For the full text of the R-phrases mentioned in this Section, see Section 16. REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : This product does not contain substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57). SECTION 4: FIRST AID MEASURES Description of first aid measures General advice : Immediate medical attention is required. Move out of dangerous area. Show this SAFETY data SHEET to the doctor in attendance. If inhaled : If breathed in, move person into fresh air. Consult a physician after significant exposure. In case of skin contact : Take off contaminated clothing and shoes immediately. Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If skin irritation persists, call a physician.

5 In case of eye contact : Rinse with plenty of water. Get medical attention immediately. Continue to rinse during transport. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. Small amounts splashed into eyes can cause irreversible POLYAMINE B Version 1 Revision Date Print Date GB / EN 4 / 125 tissue damage and blindness. If swallowed : Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Take victim immediately to hospital. Do not induce vomiting! May cause chemical burns in mouth and throat. Most important symptoms and effects, both acute and delayed Symptoms : corrosive effects sensitising effects Risks : No information available. Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

6 Special hazards arising from the substance or mixture Specific hazards during firefighting / Specific hazards arising from the chemical : Do not allow run-off from fire fighting to enter drains or water courses. Combustion products : Carbon oxides nitrogen oxides (NOx) Advice for firefighters Special protective equipment for firefighters : Wear self-contained breathing apparatus and protective suit. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. Wear respiratory protection. Ensure adequate ventilation. Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system.

7 If the product contaminates rivers and lakes or drains inform respective authorities. POLYAMINE B Version 1 Revision Date Print Date GB / EN 5 / 125 Methods and materials for containment and cleaning up Methods for cleaning up / Methods for containment : Soak up with inert absorbent material ( sand, silica gel, acid binder, universal binder). Keep in suitable, closed containers for disposal. Reference to other sections Additional advice : For personal protection see section 8. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling : For personal protection see section 8. Avoid formation of aerosol. Do not breathe vapours or spray mist. Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Smoking, eating and drinking should be prohibited in the application area.

8 Dispose of rinse water in accordance with local and national regulations. Avoid contact with skin, eyes and clothing. Advice on protection against fire and explosion : Normal measures for preventive fire protection. Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep container tightly closed in a dry and well-ventilated place. Reacts with copper, aluminium, zinc and their alloys. Other data : No decomposition if stored and applied as directed. Specific end use(s) Specific use(s) : Refer to attached exposure scenario Annex. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Contains no substances with occupational exposure limit values. Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006 Substance name End Use Exposure routes Potential health effects Value Polyethyleneamines Workers Skin contact Long-term systemic effects mg/kg bw/day POLYAMINE B Version 1 Revision Date Print Date GB / EN 6 / 125 Workers Inhalation Long-term systemic effects mg/m3 Consumers Skin contact Long-term systemic effects mg/kg bw/day Consumers Inhalation Long-term systemic effects mg/m3 Consumers Ingestion Long-term systemic effects mg/kg bw/day Workers Inhalation Acute systemic effects 8550 mg/m3 Workers Skin contact Long-term local eff ects m g/cm2 Consumers Skin contact Acute systemic effects 13 mg/kg bw/day Consumers Inhalation Acute systemic effects 2542 mg/m3 Consumers Ingestion Acute systemic effects 32 mg/kg bw/day Consumers Skin contact Acute local effects mg/kg bw/day Consumers Skin contact Long-term local eff ects mg/cm2

9 Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006 Substance name Environmental Compartment Value Polyethyleneamines Fresh water mg/l Marine water mg/l Fresh water sediment mg/kg dry weight Marine sediment mg/kg dry weight Sewage treatment plant mg/l Soil 10 mg/kg dry weight Intermittent water mg/l Secondary Poisoning mg/kg food Exposure controls Engineering Controls Effective exhaust ventilation system Ensure that eyewash stations and SAFETY showers are close to the workstation location. Personal protective equipment Respiratory protection : In the case of vapour formation use a respirator with an approved filter. Wear full face mask supplied with: Gas cartridge K (ammonia, green). Hand protection : butyl-rubber Eye protection : Tightly fitting SAFETY goggles Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Protective suit Hygiene measures : Handle in accordance with good industrial hygiene and SAFETY practice.

10 POLYAMINE B Version 1 Revision Date Print Date GB / EN 7 / 125 When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. Wash contaminated clothing before re-use. Environmental exposure controlsGeneral advice : Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Form : liquid Colour : amber Odour : ammoniacal Odour Threshold : no data available SAFETY data pH : Melting point/freezing point : < -20 C Boiling point/boiling range : > 320 C Flash point : > 150 C Method: Pensky-Martens closed cup Evaporation rate : no data available Flammability (solid, gas) : not applicable Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : < hPa at 20 C Relative vapour density : no data available Relative density : ca.