SAFETY DATA SHEET R600a Code: TR600 / TR600BB5P / …

1 SAFETY DATA SHEET R600a code : TR600 / TR600BB5P / TR600BB25 PMaterial SAFETY data SHEET according regulation (UE) 2015/830 Version 4 Date: 22nd May, 2019 Page 1 of 9 of the substance/mixture and of the Product identifier Commercial name Chemical description R600a Isobutane, I-Butane No. CAS: 75-28-5 No. CE: 200-857-2 EU Index number: 601-004-00-0 REACH registration number: 01-2119485395-27 Relevant identified uses of substance or mixture and uses advised against Industrial sector Refrigeration and air-conditioning Relevant identified uses Refrigerant gas for refrigeration and air-conditioners systems Application Industrial and professional Details of the supplier of the SAFETY data SHEET Emergency telephone number CAV-CNIT Anti-Poison (toxicological) National Information Centre +39 0382 24444 Hours: 24 h / 24 h Classification of the substance or mixture Classification under Regulation (EC) 1272/2008 (CLP) Flammable gases Category 1 Danger (H220) Gases under pressure Liquefied gas Warning (H280) Classification under Directive EC 67/548/EEC and 1999/45/ECF+.

2 R12 Label elements Dangerous pictogram GHS04 GHS02 Signal word Warning - Danger Hazard statements (H) H220: Extremely flammable gas H280: Contains gas under pressure; may explode if heated Precautionary statements (P) P210: Keep away from heat/sparks/open flames/hot surfaces No smoking P377: Leaking gas fire: Do not extinguish unless leak can be stopped safely P381: Eliminate all ignition sources if safe to do so P403: Store in a well ventilated place P410+P403: Protect from sunlight. Store in a well ventilated place. REFRIGERANT BOYS XX Settembre21052 - Busto Arsizio VAtel: +39 329 1858456mail: SAFETY DATA SHEET R600a code : TR600 / TR600BB5P / TR600BB25 PMaterial SAFETY data SHEET according regulation (UE) 2015/830 Version 4 Date: 22nd May, 2019 Page 2 of 9 Symbol(s) F+: Extremely flammable List of R-phrases R12: Extremely flammable List of S-phrases S2: Keep out of the reach of children S9: Keep container in a well-ventilated place S16: Keep away from sources of ignition - No smoking Other hazards Contact with liquid can cause frostbite and severe damage to the eyes.

3 3. Composition/information on Substances Substance name % CAS No. EC No. REACH No. Classification Reg. (CE) 1272/2008 (CLP) and Directive 67/548/EEC Isobutano > 97%75-28-5200-857-201-2119485395-27 Flam. Gas 1, H220 Press. Gas (Liq.), H280 F+ ; R12 For more information, see sections 8, 11, 12 and 16. aid measuresGeneral information: If the person is unconscious, place it in the recovery position and get immediately medical attention. Do not give anything to an unconscious person. If breathing is irregular, give oxygen. If breathing stopped, administer artificial respiration. If symptoms persist, call a physician. Note to physician: Do not give adrenaline-ephedrine or similar drugs group. Description of first aid measures Inhalation Remove patience from exposure to fresh air. Administer oxygen if necessary. Obtain immediate medical attention.

4 Skin contact In case of contact with skin, warm immediately with plenty of water. Remove contaminated clothing. If irritation or blistering occurs, call a physician. Eye contact Remove contact lenses, if present. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Ingestion Unlikely route of exposure. As this product is a gas, refer to the section Inhalation . Do not induce vomiting without medical advice. Obtain immediate medical attention. Most important symptoms and effects, both acute and delayed In high concentrations may cause asphyxiation. Symptoms may include loss of mobility/consciousness. Victim may not be aware of asphyxiation. In low concentrations may cause narcotic effects. Symptoms may include dizziness, headache, nausea and loss of coordination. Extinguishing media Suitable extinguishing media Dry powder, water spray, alcohol-resistant foam and CO2 No suitable extinguishing media High water jet.

5 Special hazards arising from the substance or mixture Specific hazards Contents under pressure. On heating: heating will cause a rise in pressure with a risk of bursting. Toxic and corrosive vapours are released. Cool down the containers exposed to heat with a water spray. Vapours are heavier than air and can cause rapid suffocation by reducing oxygen available for breathing. Hazardous combustion In case of fire, decomposition products may include the following materials: carbon dioxide and DATA SHEET R600a code : TR600 / TR600BB5P / TR600BB25 PMaterial SAFETY data SHEET according regulation (UE) 2015/830 Version 4 Date: 22nd May, 2019 Page 3 of 9 Advice for firefighters Specific methods Coordinate fire measure to the surrounding fire. Exposure to flames and heat can cause the container to rupture. From protected position, cool endangered containers with water spray jet.

6 Do not discharge contaminated water into drains. If possible, stop flow of the product. If possible, use water spray to knock down the fumes. Explosive re-ignition may occur, turn off all the other fire. Move containers from fire area if this can be done without risk. Protective equipment Firefighters must use standard protective equipment including SCBA. Avoid contact with eyes and skin. Do breath the fumes. Other information Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. For more information, see section 10. 6. Accidental release Personal precautions, protective equipment and emergency procedures Immediately contact emergency personnel. Immediately evacuate personnel to safe areas. Unprotected persons must be kept away. Wear personal protective equipment refer to section 8 "Exposure controls/personal protection".

7 Remove all sources of ignition. Avoid contact with skin (possible frostbite). Ventilate the area/local. In case of insufficient ventilation, wear self-contained breathing apparatus. Environmental precautions Do not allow product to spread into the environment. Avoid spillage and prevent possible losses. Methods and material for containment and cleaning up Ventilate / aerate the area or local. Reference to other sections For more information, see section 8 and 13. 7. Handling and Precautions for safe handling Technical measures Use only properly specified equipment that is suitable for this product, its supply pressure and temperature. In case of doubt, refer to supplier's handling instructions. Only experienced and properly instructed persons should handle gases under pressure. Service technician must check regularly your entire gas system to ensure that it is leak-free.

8 Safe handling The substance must be handled in accordance with good industrial hygiene and SAFETY procedures. Refer to supplier's / manufacturer s handling instructions. Handle and open container with care. Caution when opening, pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 C (122 F). Do not spray on a naked flame or any incandescent material. Do not use in area without adequate ventilation. Protect containers from physical damage; do not drag, roll, slide or drop. Do not pierce or burn, even after use. Leave valve protection caps in place until the container is ready for use. Close container valve after each use and when empty, even if still connected to equipment. Do not remove or deface labels provided by the supplier for the identification of the container contents. Industrial hygiene Ensure adequate ventilation of the working area.

9 Do not drink, eat or smoke in the working area. SAFETY DATA SHEET R600a code : TR600 / TR600BB5P / TR600BB25 PMaterial SAFETY data SHEET according regulation (UE) 2015/830 Version 4 Date: 22nd May, 2019 Page 4 of 9 Conditions for safe storage, including any incompatibility Requirements for storage areas and containers Keep containers tightly closed in a dry, cool and well-ventilated place, away from any ignition or heat sources. Store in original container. Container valves or caps should be in place. Incompatible materials Avoid storage with oxidizing products, acids and, in general, with chemicals. Avoid storage with tools or equipment that may cause sparks. Specific end use(s) For professional and industrial use only. controls/personal Control parameters OEL (Occupational Exposure Limit): No data available. Components CAS Nr.

10 TLV-TWA Control parameters Font Year Isobutane 75-28-58 h 800 ppm 1900 mg/m AGCIH 2010 DNEL and DMEL = the substance have no harmful effect on human health. PNEC = the substance have no harmful effect on the environmental. Exposure controls Ensure adequate ventilation. In case of insufficient ventilation, wear self-contained breathing apparatus. Wash the hands before and after using the gas. Do not smoke. Personal protective equipment must comply with EU directives: respiratory protective equipment EN 136, 140, 149; eye protection (protective goggles or SAFETY glasses) EN 166; skin protection EN 340, 463, 468, 943-1, 943-2; hands protection (protective gloves) EN374, SAFETY boots EN ISO 20345. Individual protection measures, such as personal protective equipment a) Eye/face protection SAFETY glasses with side-shields (according to directive EN 166).