SAFETY DATA SHEET - Ribbond

1 Unit ed S tates Ribbond Inc SAFETY data S HEETR ibbond fiber reinforce ments Original, Triaxial, THM, Ultra-THM Sectio n entif ication GHS p roduct identifie rOther means of id entificatio nProduct type :Ri bbond Fibers:Not available. :Solid. Rele vantid entifie dusesofthesubstanceormixtureandusesadvis edagain stProduct u se:Denta l p roduct: Reinforced dental r of applicatio n:Professionalapplications. Manufacturer: Ribbond , THIRDAVE STE 330 Seattl e WA 98101 Telephone n o.: 1-206-340-8870 e-mail address of person responsible for t his S DS:Conta ct c ustomer s ervice a t 1-800-624-4554 for any questi ons Emergencytele phonenumber (with hours of operation) :Ri bbond, In c. ( 8:00 16:30 Pacific) : 1-800-624-4554In te rnati onal: +1-206-340-8870 Sectio n id entificatio n OSHA/H CS status:This mate rial i s NOT c onsidered h azardous b y the OSHA Hazard C ommunicati on Standard(29 CFR ).

2 Classif icatio n of the substance or mix ture:SKIN IRRITATIO N Not Cl assifiedEYE I RRITATIO N Not ClassifiedSENSITIZ ATIO N Not ClassifiedPercenta ge of the mixtu re c onsisti ng o f ingredient( s) o f unknown t oxicit y: 0% GHSla bele le mentsHazard p ic tograms: Signal word:W arni ngHazard s tatements:Do not handle wi th f ingers p rior to applic ati on o f r esin. Finger oils c an compromise Date of issue/Date of revision:10/28/ 16 Date of previous issue :04/ 06/ 16 Version :11/11 United States Ribbond fibers Section 2. Hazards identification Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Dispose of contents and container in accordance with all l ocal, regional, national and international regulations. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Substance/mixture Other means of identification : Ultra High Molecular Weight Polyethelene : UHMWP.

3 CAS number/other id entifiers CAS number : Not applicable. Product code : Not available. Ingredient name Other names % CAS number Polyethylene Various brand names 100% 9002-88-4 There are no additional ingredients present which, w ithin the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Section 4. First aid measures Description of necessary first aid measures Eye contact Inhalation Skin contact : No special measures are require d. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if symptoms occur. : No special measures required. If inhaled, remove to fresh air. Get medical attention if symptoms occur. : No special measures required. In case of contact, immediately flush skin with plenty of water. Get medical attention if symptoms occur. Ingestion : Not a probably route of exposure.

4 Get medical attention if adverse health effects persist or are severe. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Can cause mechanical irritation. Date of issue/Date of revision : 10/28/16 Date of previous issue : 04/06/16 Version : 1 2/11 United States Ribbond fibers Section 4. First aid measures Inhalation : No known signif icant effects or critical hazards. Skin contact : No known signif icant effects or critical : No known signif icant effects or critical hazards. Over-e xposure signs/symptoms Eye contact : Adverse symptoms may include the following mechanical irritation: pain or irritation watering redness Inhalation Skin contact Ingestion : No specific data . : No specific data . : No specific data . Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.

5 The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-a iders : No specific precautions. See toxicological information (Section 11) Section 5. Fire-fi ghting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire. : Not applicable. Specific hazards arising from the chemical Hazardous thermal decomposition products : No specific fire or explosion hazard. : Decomposition products may include the follo wing materials: carbon dioxide carbon monoxides Special protective actions for fire-fighters Special protective equipment for fire -fighters : No specific precautions. Normal quantities are minimal. : Fire-f ighters should wear appropriate protective equipment and self- contained breathing apparatus (SCBA) with a full face- piece operated in positive pressure mode.

6 Date of issue/Date of revision : 10/28/16 Date of previous issue : 04/06/16 Version : 1 3/11 United States Ribbond fibers Section 6. Accidental release measures Personal pre cautions, protective equipment and emergency procedures For non-emergency personnel : Low release. For professional use only. Handling of product in very small amounts or in situations where release is highly unlik ely For emergency responders : Low release. See also the information in "For non-emergency personnel". Environmental precautions : Low release. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Large spill : Small Quantity. For professional use only. Place in an appropriate waste disposal container. Small Quantity. For professional use only. Pl ace in an appropriate waste disposal container.

7 Section 7. Handling and storage Precautions for safe handling Protective measures Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities : No special measures are required for small quantities under normal and intended conditions of product use. For professional use only. Handle with care and dispose in a safe manner. : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, dri nking and smoking. See also Section 8 for additional information on hygiene measures. : Store in accordance with local regulations. Store in original container protected from dir ect sunlight in a dry, cool and well-v entilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use.

8 Containers that have been opened must be carefully closed with a clip. Do not store in unlabeled containers. Use appropriate containment to avoid enviro nmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None. Appropriate engineering controls Environmental exposure controls : No special measures are required for small quantities under normal and intended conditions of product use. : No special measures are required for small quantities under normal and intended conditions of product use. Indivi dual protection measures Hygiene measures : No special measures are required for small quantities under normal and intended conditions of product use. Date of issue/Date of revision : 10/28/16 Date of previous issue : 04/06/16 Version : 1 4/11 United States Ribbond fibers Section 8. Exposure controls/personal protection Eye/face protection Skin protection Hand protection Body protection : No special measures are required for small quantities under normal and intended conditions of product use.

9 : No special measures are required for small quantities under normal and intended conditions of product use. : No special measures are required for small quantities under normal and intended conditions of product use. Other skin protection : No special measures are required for small quantities under normal and intended conditions of product Respiratory protection : No special measures are required for small quantities under normal and intended conditions of product use. Section 9. Physical and chemical properties Appearance Physical state Color Odor Odor threshold pH Melting point : Solid. [Woven fibers] : W hite. Natural. : None. : Not available. : Not available. : 147 F Boiling point : Not available. Flash point Evaporation rate : Not available. : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Vapor pressure Vapor density Relative density Solubility : Not available.

10 : Not available. : g at 77 F : Insoluble in the following materials: cold water and hot water. Solubility in w ater : Not available. Partition coefficient: n- octanol/water Auto-ignition temperature : Not available. : Not available. Decomposition temperature : Not available. SADT Viscosity : Not available. : Not available. Date of issue/Date of revision : 10/28/16 Date of previous issue : 04/06/16 Version : 1 5/11 United States Ribbond fibers Section 10. Stability and reactiv ity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : Prevent product contamination. Product from long term ambient air exposure. Incompatible materials : Strong oxidizing agents.