SAFETY DATA SHEET - Rustoleum Direct

1 2120 Galva-Plus +Identification of the preparation and of the companySAFETY data SHEETP roduct name and/or code2120 Galva-Plus +This SAFETY data SHEET is prepared in accordance with EU Directive 91/155/EC, as amended by Directive 2001/58/EC1.:Product usePaint.:Manufacturer:Rust-Oleum Netherlands BV, PO. Box 138, NL-4700 AC Roosendaal, The NetherlandsNV Martin Mathys, Kolenbergstraat 23, B-3545 Zelem, BelgiumEmergency phone::Rust-Oleum: (+31)165-593636; Fax (+31)165-593600 Martin Mathys: (+32)13-460200; Fax (+32)13-460201 Composition/information on presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive67/548 name*Dimethyl ether115-10-625 - 50204-065-8 F+; R12 Xylene (mixture of isomeres)1330-20-7 10 - 25215-535-7 R10Xn; R20/21Xi; R38 Zinc powder, stabilized7440-66-6 10 - 25231-175-3 N; R50/53 Solvent naphtha (petroleum), medium aliphatic64742-88-7 - 5265-191-7 Xn; R65R66 Solvent naphtha (petroleum), light aromatic64742-95-6 - 5265-199-0 R10Xn; R65Xi; R37R66N; R51/531,2,4-Trimethylbenzene95-63-61 - R10Xn; R20Xi; R36/37/38N; R51/53 Zinc oxide1314-13-2 0 - 1215-222-5 N; R50/53 Mesitylene108-67-80 - 1203-604-4 R10Xi; R37N; R51/53 Isopropylbenzene (cumene)98-82-80 - 1202-704-5 R10Xn; R65Xi.

2 R37N; R51/53 Antistatic - 1269-662-8 Xn; R22C; R35N; R50 United Kingdom (UK)See section 16 for the full text of the R-phrasesdeclared aboveOccupational exposure limits, if available, are listed in section health hazardsHarmful by inhalation and in contact with skin.:The preparation is classified as dangerous according to Directive 1999/45/EC and its hazards:Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic hazards :Extremely :F+; R12Xn; R20/21N; R51/53 Additional warning phrases :Pressurized container: protect from sunlight and do not expose to temperatures exceeding50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or anyincandescent material. Keep away from sources of ignition - No of : 1/72120 Galva-Plus +If swallowed, seek medical advice immediately and show this container or label. Keep personwarm and at rest. Do not induce contactCheck for and remove any contact lenses. Immediately flush eyes with running water for at least15 minutes, keeping eyelids contaminated clothing and shoes.

3 Wash skin thoroughly with soap and water or userecognized skin cleanser. Do not use solvents or aid measuresRemove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Givenothing by mouth. If unconscious, place in recovery position and seek medical contact::::First aid measuresGeneralIn all cases of doubt, or when symptoms persist, seek medical attention. Never give anything bymouth to an unconscious person.:Fire-fighting : alcohol-resistant foam, CO2, powders, water to be used : water media:Recommendations:Fire will produce dense black smoke. Exposure to decomposition products may cause a healthhazard. Appropriate breathing apparatus may be required. Cool closed containers exposed tofire with water. Do not release runoff from fire to sewers or combustionproducts:Decomposition products may include the following materials:carbon oxidesmetal oxide/oxidesPersonal precautionsExclude sources of ignition and ventilate the area.

4 Avoid breathing vapor or mist. Refer toprotective measures listed in sections 7 and Accidental release measures::SpillContain and collect spillage with non-combustible, absorbent material sand, earth,vermiculite or diatomaceous earth and place in container for disposal according to localregulations (see section 13). Do not allow to enter drains or watercourses. Preferably clean witha detergent. Avoid using solvents. If the product contaminates lakes, rivers, or sewers, informthe appropriate authorities in accordance with local : see section 8 for personal protective equipment and section 13 for waste and are heavier than air and may spread along floors. Vapors may form explosive mixtureswith air. Prevent the creation of flammable or explosive concentrations of vapors in air and avoidvapor concentrations higher than the occupational exposure container tightly closed. Keep away from heat, sparks and flame. No sparking tools shouldbe addition, the product should only be used in areas from which all naked lights and othersources of ignition have been excluded.

5 Electrical equipment should be protected to theappropriate contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arisingfrom the application of this preparation. Avoid inhalation of dust from , drinking and smoking should be prohibited in area where this material is handled, storedand processed. Workers should wash hands and face before eating, drinking and on appropriate personal protective equipment (see section 8).Comply with the health and SAFETY at work in accordance with local regulations. Observe label precautions. Do not store above thefollowing temperature: 35 C (95 F). Store in a cool, well-ventilated area away from incompatiblematerials and ignition away from: oxidizing agents, strong alkalis, strong smoking. Prevent unauthorized access. Containers that have been opened must be carefullyresealed and kept upright to prevent not empty into drains.::Date of : 2/72120 Galva-Plus +Engineering measuresProvide adequate ventilation.

6 Where reasonably practicable, this should be achieved by the useof local exhaust ventilation and good general extraction. If these are not sufficient to maintainconcentrations of particulates and solvent vapors below the OEL, suitable respiratory protectionmust be Exposure controls/personal protection:Ingredient nameOccupational exposure limitsDimethyl etherEH40-WEL (United Kingdom (UK), 1/2005). STEL: 958 mg/m , 0 times per shift, 15 minute(s). Form: All forms STEL: 500 ppm, 0 times per shift, 15 minute(s). Form: All forms TWA: 766 mg/m , 0 times per shift, 8 hour(s). Form: All forms TWA: 400 ppm, 0 times per shift, 8 hour(s). Form: All formsXylene (mixture of isomeres)EH40-WEL (United Kingdom (UK), 1/2005). Skin STEL: 441 mg/m 15 minute(s). Form: All forms STEL: 100 ppm 15 minute(s). Form: All forms TWA: 220 mg/m 8 hour(s). Form: All forms TWA: 50 ppm 8 hour(s). Form: All formsSolvent naphtha (petroleum), mediumaliphaticEH40-WEL (United Kingdom (UK), 6/2005).

7 Notes: as Turpentine (150 ppm) STEL: 850 mg/m , 4 times per shift, 15 minute(s).EH40-WEL (United Kingdom (UK), 6/2005). Notes: as Turpentine (100 ppm) TWA: 566 mg/m , 0 times per shift, 8 hour(s).Solvent naphtha (petroleum), lightaromaticEH40-WEL (United Kingdom (UK), 6/2005). Notes: Trimethylbenzene, allisomers TWA: 125 mg/m 8 hour(s). TWA: 25 ppm 8 hour(s).1,2,4-TrimethylbenzeneEH40-WEL (United Kingdom (UK), 1/2005). TWA: 125 mg/m 8 hour(s). TWA: 25 ppm 8 hour(s).MesityleneEH40-WEL (United Kingdom (UK), 1/2005). TWA: 125 mg/m 8 hour(s). TWA: 25 ppm 8 hour(s).Isopropylbenzene (cumene)EH40-WEL (United Kingdom (UK), 1/2005). Skin STEL: 250 mg/m 15 minute(s). Form: All forms STEL: 50 ppm 15 minute(s). Form: All forms TWA: 125 mg/m 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All formsUnited Kingdom (UK)Environmental exposure controlsDo not allow to enter drains or controlsOccupational exposurecontrols:Use only with adequate ventilation.

8 If user operations generate dust, fumes, gas, vapor or mist,use process enclosures, local exhaust ventilation or other engineering controls to keep workerexposure to airborne contaminants below any recommended or statutory limits. Theengineering controls also need to keep gas, vapor or dust concentrations below any lowerexplosive limits. Use explosion-proof ventilation hands, forearms and face thoroughly after handling chemical products, before eating,smoking and using the lavatory and at the end of the working period. Appropriate techniquesshould be used to remove potentially contaminated clothing. Wash contaminated clothingbefore reusing. Ensure that eyewash stations and SAFETY showers are close to the measuresRespiratory protection::Recommended: organic vapor (Type A) and particulate filter>8 hours (breakthrough time): Gloves , polyvinyl alcohol (PVA) or Viton .:Hand protectionEye protection:Recommended: SAFETY glasses with side-shields (EN 166) .Skin protection:Recommended: exposurecontrols:Emissions from ventilation or work process equipment should be checked to ensure they complywith the requirements of environmental protection legislation.

9 In some cases, fume scrubbers,filters or engineering modifications to the process equipment will be necessary to reduceemissions to acceptable of : 3/72120 Galva-Plus +Physical and chemical stateVapor density>1 [Air = 1]:Liquid. [Aerosol.] pointClosed cup: -40 C (-40 F)Lower: 3%Upper: 18%Explosion limits:::::Relative density0,9:Evaporation rate (butylacetate = 1):>1 (Butyl acetate. = 1)Vapor pressure:420 kPa (3150,26 mm Hg)Volatility %74% (w/w):VOC content w/w663 (g/l).:Stability and reactivityStable under recommended storage and handling conditions (see section 7).Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of away from the following materials to prevent strong exothermic reactions: oxidizing agents, strong alkalis, strong is no data available on the preparation itself. The preparation has been assessed following the conventional method of theDangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly.

10 See sections 2 and 15 to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adversehealth effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and centralnervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs includeheadache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated orprolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitisand absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible toxicityDimethyl etherLC50 mg/m 1 hoursLC50 ppm0,5 hoursXylene (mixture of isomeres)LD50 DermalRabbit>1700 mg/kg-LD50 OralRat4300 mg/kg-LC50 InhalationVaporRat5000 ppm4 hoursZinc powder, stabilizedLDLo mg/kg-TDLo Intratracheal Rat25 mg/kg-Solvent naphtha (petroleum), medium aliphatic LD50 DermalRat>3052 mg/kg-LD50 OralRat>6040 mg/kg-LC50 InhalationVaporCat10000 mg/m 8 hoursLC50 InhalationVaporRat>8200 mg/m 8 hoursSolvent naphtha (petroleum), light aromatic LD50 DermalRabbit>2000 mg/kg-LD50 OralQuail>2150 mg/kg-LD50 OralMouse8400 mg/kg-LC50 InhalationVaporRat29 mg/L4 hours1,2,4-TrimethylbenzeneLD50 OralRat5000 mg/kg-LC50 InhalationVaporRat18000 mg/m 4 hoursZinc oxideLD50 OralRat>14700 mg/kg-LD50 OralMouse7950 mg/kg-LDLo OralHuman/30 min500 mg/kg-LC50 InhalationDusts and mistsMouse2500 mg/m 4 hoursMesityleneLC50 InhalationVaporRat24000 mg/m 4 hoursIsopropylbenzene (cumene)