Safety Data Sheet (SDS) - Brasseler USA

1 P1/9 Issued onRevised on1. IdentificationProductDescriptionOrder codeCompany InformationCompany contact Hazard identificationSignificant hazards and effectsSpecific hazardsGHS classificationPhysical and Chemical hazardsExplosivesFlammable/Ignitable gasFlammable/Ignitable aerosolBurnable/oxidized gasHigh-pressure gasIgnitable liquidFlammable solidAutoreactive chemicalPyrophoric liquidPyrophoric solidSelf-heating chemicalWater-reactive flammable chemicalOxidizing liquidOxidizing solidOrganic peroxideMetal-corrosive chemicalHazards to healthAcute toxicity (oral)Acute toxicity (percutaneous)Acute toxicity (inhalation : gas)Acute toxicity (inhalation : vapor)Acute toxicity (inhalation : dust, mist)Skin corrosivity/IrritationSerious damage to eyes/Eye irritationRespiratory sensitizationSkin sensitizationGermline mutagenicityCarcinogenicityNSK-SDS-003US (E) Safety data Sheet (SDS)2015-05-072014-04-09 PANA SPRAY PLUSZ182600 NAKANISHI Shimohinata Kamuna-shi Tochigi 322-8666, Japan (HQ) Recommended use and usage restrictionsLubricantN/AQuality Assurance Dept.

2 +81(0)289-64-3380 (HQ)+81(0)289-64-7277 (QA)+81(0)289-62-5636 (HQ)+81(0)289-64-3890 (QA)Classification 2N/AN/AN/AN/AN/AN/AClassification 1N/AN/Aunclassifiableunclassifiableuncla ssifiableOut of categoryunclassifiableunclassifiableuncl assifiableunclassifiableN/Aunclassifiabl eClassification 1 Bunclassifiableunclassifiableunclassifia bleClassification 2 AunclassifiableunclassifiableP2/9 ReproductivityEffects on breast-feedingTarget organ/Systemic toxicity (single exposure)Target organ/Systemic toxicity (repeated exposure)Hazards to suction aspirationHazards to environmentHazards to water environment (acute)Hazards to water environment (chronic)Labeling elementsPictogramSignal wordHazard statementsHazard and toxicity informationPrecautionary statementPreventionResponseClassificatio n 1 AunclassifiableClassification 3 (Airway irritation, Anesthetic action)Classification 1 (Liver)Classification 2 (Nerve)unclassifiableunclassifiableuncla ssifiableDanger(Airway irritation)Possibility of irritation to airway/(AnestheticPossibility of sleepiness or dizinessPossibility of inherited disordersHighly-ignitable liquid and vaporHighly flammable/ignitable aerosolSerious eye irritationPossibility of adverse effect on reproductivity/fetusOrgan <liver> damage from long-term/repeated exposurePossibility of organ <nerve> damage from long-term/repeatedexposureWear protective globes and an explosive-proof electrical/ventilation/lighting the container and eating and smoking at the time of Safety precautions before it in the open air/well-ventilated container.)

3 Do not punctuate/burn the a non-sparkling the operation manual before hands thoroughly after preventive measures against electrostatic heat, spark, flame and ignition source - No protective equipment if not inhale the gas/mist/ the not spray the lubricant toward a fire, high-temperatureincandescent the event of fire, use carbon dioxide/powder/foam fire-extinguisher or drying contact : Thoroughly wash eyes for several mins. If youwear lenses, remove them, and continue to wash the the pain persists, seek the help of a feeling sick, contact a feeling sick, seek the help of a hazardsCategoryHazardEnvironment3. Composition/information on ingredientsSubstance / MixtureSubstanceGeneral product descriptionLubrication oilIngredients and compositionEster lubricantEthanolPropanen-butanei-butane4 . First-aid measuresInhalation Skin contact Chemical name(another name)CAS No.(mass %)Chemical/StructuralformulaNotice No. fromgovernmentgazette (CSCL) (2) (2)-202 (2)-3(2)-4CH3CH2CH3 Inhalation : Move the affected person to a place with fresh airand keep him/her at rest in a comfortable position for hands after (hair) contact : Immediately take off/remove thecontaminated clothing.

4 Wash the affected skin with In the event of exposure/concern about exposure : Seekmedical the container and store it in a well-ventilated move the affected person to a place with fresh air andkeep him/her warm with a blanket and quiet. Give rescue breathing ifbreathing has been irregular/stopped. Keep him/her from swallowingIn case of sickness-producing when inhaled vapor/gas, move theaffected person to a place with fresh air and keep him/her quiet. Seekmedical wash the site with soap and water after wiping it off with adry cloth. Take off the contaminated cloth and wash the exposed areaof skin thoroughly with soap and it off by taking a shower/bath in case of whole-body case of cryogenic burn by gas exposure, rinse with plenty ofwarm/cold water without taking off the medical attention if there is pain/change in it under lock and direct sunlight. It should not be subjected totemperatures exceeding 40 CStore it in a well-ventilated/cool of the component/container by requesting an industrialwaste disposal professional according to the desposalregulations of local liquid, High-pressure gasHazards to aquatic organism, if it's high at ordinary temperature, since ignitable liquied isThe vapor and air generate explosive gas is contained.

5 Explosive when the gas , if come in contact with , if swallowed orinhaled high levels of contact Ingestion No information No information No information5. Fire-fighting measures (Fire in the surrounding area) 6. Accidental release measures ::Do not discharge leakage into sewers, drains, of waste in accordance with applicable the leakage in an airtight container and absorb the residue in ainer absorbent. Move them in a safe case of small amountIn case of large amountSupply earth sand/waste cloth to absorbthe lubricant. Collect it in an emptyUse soil and sand to stop the flow ofleaking lubricant and lead the lubricant to asafe area. Cover the liquid surface withfoam and collect as much of the liquid aspossible in an empty people on the downwind and close the area to allunauthorized a fire extinguisher in case of the requid by using an equipment which is not made of spark-producing materials on impact/with case of massive generation of vapor, reduce the generation byPersonal precautions,protective equipment andemergency proceduresWear a proper protective action from the windward side.

6 Turn the leakage site of containerup and let the gas out remove any inflammable items from the surrounding move the container to a safe the container is not movable, sprinkle water on it and the surrounding Wear a proper protective cloth (heat-resistant cloth, protective glassesetc.) and use a protectiveequipment for firefightersImmediately remove any inflammable items from the surrounding the fire from the windward side not to inhale toxic the fire at a distance for the possibility of producing anexplosion with aerosol container at a fire site. Pour water and cool theproduct container that is subjected to high case of a larger fire, it is effective to use a foam fire extinguisherand block out the extinguishingmethodsSuitable extinguishing mediCarbon dioxide, foam/powder fire-fighting agent, dry with an aerosol container at a fire a fire with fire the specified fire the person vomit by giving him/her a prenty of not give him/her anything when he/she is unconscious.

7 Seekmedical to physicianProtection of first-aidersMost important symptomsand effects, both acuteand delayedWash eyes with clean water for several mins. If you wear contactlenses, remove them, and continue to wash the eyes. If the painpersists, seek the help remove them, and continue to wash the eyes. Ifthe pain persists, seek the help of a Handling and storageHandling Storage 8. Exposure controls/personal protection Components with workplace control parametersEquipment measuresEquipment must be explosionproof an exhaust system for air heat and ignition source away from the handling case of indoor work, provide a specific equipment such as localexhaust system to prevent an operator from being directly (SHA)N/An-butane 500ppmJapan society foroccupational healthN/An-butane 800ppmACGIH(TLV-TWA)1,000ppmN/AACGIH(TLV -STEL)N/AN/AThe container may explode under high temperature hands thoroughly after it away from a general rule, handled at room temperature. Keep liquid/foreignparticle materialsConditionsKeep out of reach of direct sunlight and store it in a well-ventilated it away from moisture because of fear of liquid leakage orexplosion from/of rusty it away from perchloric acid/hydrogen peroxide water/sodiumperoxide/chromic acid/nitric acid/oxidant flame and not be subjected to temperatures exceeding 40 CElectric(al) apparatus used in the storage area must be explosionproofstructured.

8 Earth the apparatus on the ground when other relevant regulations such as Fire defense law, IndustrialSafety and Health should be in accordance wiwth High Pressure Gas SafetyAllowable concentrationComponentGeneral PrecautionsAdvice on safe handlingHandle it in a well-ventilated flame, spark and high-temperature substance around the not roll over/drop/impact on the container. Also, do not drag the instructions for use before the instructions carefully until you fully understand eating and smoking when using this not spray the lubricant toward a fire, high-temperatureincandescent container : Do not punctuate/burn the the product with user's back to the wind to prevent him/her frombeing flame, spark and high-temperature substance around the a spark-unproducing to countermeasures against static electricity, earth equipments onthe ground. Electric(al) apparatus must be explosionproof a proper protective Physical and chemical properties10. Stability and reactivity11.

9 Toxicological information (Product data )N/A(Ingredient data : ethanol)RatLD60 >5/kgRatLD50 (Product data )N/An-butane 800ppm (Product data )N/A(Ingredient data : propane)Guinea-pigAcute toxicity (oral)Acute toxicity(percutaneous)Acute toxicity (inhalation :gas)LC50(2hrs)>55000ppmPossibility of hazardousreactionsHazardous decompositionproductConditions to avoidExplosion-producing at 40 C or in the container at room temperature : approx. with incompatible hazardous substances such as oxidant,and posing a risk of with plastic, rubber, coating in conditions of heat and humidity. Use close to with incompatible hazardous acid, Strong alkali, Oxidant, Calcium hypochlorite, Silver hazardous gas ( CO, nitrogen oxide) by rangeVapor pressureVapor densitySpecific gravitySolubilityOctanol/water partition coefficientDecomposition temperatureOthersChemical stabilityStatusAppearanceOdorpHMelting pointBoiling pointFiring pointIgnition pointLiquidFluidClear and C(as ethanol) C( )(as ethanol)13 C(airtight-type)(as ethanol)SprayGas (under atmosphericpressure)/ Fluid (in a pressureClear and CWear a (organic) gas mask, dust mask, air-supplied respirator (in anenclosed space)Solution-resistant protective glovesProtective glasses/maskProtective cloth, Boots, (solution-resistant) Apron, eating and smoking while hands thoroughly after (if necessary)For respirationFor handsFor eyesFor skin/bodyProper hygiene measureNo (20 C)easily soluble in (lowPow)(as ethanol)No dataNo (1 MPa, C) (15 C))

10 Soluble in waterNo dataNo dataNo dataIncompatible materials439 C(as ethanol)No dataNo data405 550 (40 C)P7/9 Guinea-pig(Ingredient data : n-butane)Rat (Product data )N/A(Ingredient data : ethanol)Rat (Product data )N/A(Ingredient data : ethanol)Rat (Product data )N/A(Ingredient data : ethanol)OECD TAG404 testRabbitnot irritatingAmerican guidelinesRabbitnot irritating(Ingredient data : propane) (Product data )N/A(Ingredient data : ethanol)OECD TAG404 testRabbitmoderateDraize testRabbitmoderately (Product data )N/A (Product data )N/ACarcinogenicity (Product data )N/AReproductivity (Product data )N/A (Product data )N/AACGIH classifies ethanol of adverse factorin a working environment as A4(noncarcinogenic to humans).Specific target organ /Systemic toxicity (singleexposure)Many cases of fetal harm/malformationcaused by habitual intake of alchol arebeing reported.(Ingredient data :ethanol)(Ingredient data :ethanol)(Ingredient data :propane)ACGIH refers to anesthetic action aboutthe impact on ethanol intake could cause acutepoisoning to central nerve system, whichresults in of 5000ppm ( ) causesairway irritation, stupor, sleep from daamage to the corneal epithelium and conjunctivalcongestion in 1-2 sensitizationor Skin sensitizationNo skin sensitization detected by animaltestingDominant lethality of rat/mouse andaneuploidy induction of mouse germ cell (Ingredient data :ethanol)(Ingredient data :ethanol)(Ingredient data :ethanol)Germline mutagenicityAccording to IARC, classified as "group 1"for the reason of being carcinogenic as analcoholic beverage, however, thisrecognizes the relationship betweenalchhol and esophageal/liver cancer basedon the epidemiological studies of peoplewho have habitual intake of :63000ppm/4h(118mg/L)Acute toxicity (inhalation :vapor)Acute toxicity (inhalation.)