Safety Data Sheet (SDS) Formic Acid, 85% - CIRS

1 Safety data Sheet (SDS) Formic acid , 85% According to Regulation (EC) No 1907/2006 (REACH) SDS Record Number: CSSS-TCO-010-00001 Version Print date: 11/11/2010 Revision date: 11/11/2010 We prepare good SDS (200 Euros only, Page 1 of 10 1 IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY/UNDERTAKING Product identifier: Identification on the label/Trade name: Formic acid , 85% CAS: 64-18-6 EC: 200-579-1 Index Number: 607-001-00-0 REACH registration No.)

2 : 05-2114596xxx-32-0000 Additional identification: N/A Relevant identified uses of the substance and uses advised against: Identified uses: General chemical reagent Uses advised against: Not available. Details of the supplier of the Safety data Sheet : xxxx Chemicals xxxx, France xxx , Tel: 003x-652549xxx Emergency telephone Number: #3x-xxxx Available outside office hours? YES NO X 2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification: The substance is classified as following according to 67/548/EEC and REGULATION (EC) No 1272/2008(CLP). EU CLP 1272/2008 Hazard classes/Hazard categories Hazard statement Skin Corrosion 1B H314 For full text of H- phrases: see section 67/548/EEC(DSD) Hazards characteristics R-Phrases Xn R34 The most important adverse effects The most important adverse physicochemical effects: Not applicable.

3 The most important adverse human health effects: Safety data Sheet (SDS) Formic acid , 85% According to Regulation (EC) No 1907/2006 (REACH) SDS Record Number: CSSS-TCO-010-00001 Version Print date: 11/11/2010 Revision date: 11/11/2010 We prepare good SDS (200 Euros only, Page 2 of 10 Causes severe skin burns and eye damage The most important adverse environmental effects: Not applicable.)

4 Label elements Hazard Pictograms: GHS05 Signal Word(S): Danger Hazard Statement: H314 Causes severe skin burns and eye damage Precautionary Statement: P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash hand/clothing thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Other hazards Not available. 3 COMPOSITION/INFORMATION ON INGREDIENTS Substance/Mixture: Mixture Ingredient(s): Substance Name CAS# % by weight REACH No. Classification Formic acid 64-18-6 85 05-2114596428-32-0000 H314 Water 7732-18-5 15 N/A 4 FIRST AID MEASURES Description of first aid measures: In case of inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

5 In case of skin contact: Remove contaminated clothing immediately. Rinse skin with water/shower. Wash contaminated clothing before reuse. In case of eyes contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to rinsing. In case of ingestion: Safety data Sheet (SDS) Formic acid , 85% According to Regulation (EC) No 1907/2006 (REACH) SDS Record Number: CSSS-TCO-010-00001 Version Print date: 11/11/2010 Revision date.

6 11/11/2010 We prepare good SDS (200 Euros only, Page 3 of 10 If swallowed: Rinse mouth. Do not induce vomiting. Most important symptoms and effects, both acute and delayed Skin burns. Symptoms can include redness, swelling, pain and tearing. Indication of any immediate medical attention and special treatment needed Immediately call a POISON CENTER or doctor/physician. 5 FIRE-FIGHTING MEASURES Extinguishing media: Suitable extinguishing media: Carbon dioxide, appropriate foam or dry chemical, water pray, water mist.)

7 Unsuitable extinguishing media: Water jet. Special hazards arising from the substance or mixture Emits toxic fumes under fire conditions: Carbon monoxide (CO) Advice for fire-fighters: Firefighters must wear fire resistant protective equipment. Wear self contained breathing apparatus and protective gloves. 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: For non-emergency personnel: Remove ignition sources. Provide adequate ventilation. Avoid inhalation of vapour or dust. Avoid skin and eye contact. Wear protective gloves/protective clothing/eye protection/face protection. For emergency responders: Wear an appropriate NIOSH/MSHA approved respirator if mist, vapor or dust is generated.

8 Environmental precautions: Avoid disposing into drainage/sewer system or directly into the aquatic environment. Keep away from drains, surface-and ground-water and soil. Methods for containment and cleaning up: For small spills, dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate. For large spills, keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift.

9 Prevent entry into sewers, basements or confined areas Reference to other sections: Safety data Sheet (SDS) Formic acid , 85% According to Regulation (EC) No 1907/2006 (REACH) SDS Record Number: CSSS-TCO-010-00001 Version Print date: 11/11/2010 Revision date: 11/11/2010 We prepare good SDS (200 Euros only, Page 4 of 10 See Section 7 for information on safe handling.)

10 See section 8 for information on personal protection equipment. See Section 13 for information on disposal. Additional information: Not available 7 HANDLING AND STORAGE Precautions for safe handling: Protective measures: Do not breathe dusts/vapor. Handle in well ventilated areas. Eliminate all sources of ignition, and do not generate flames or sparks. Take precautionary measures against static discharges. Advice on general occupational hygiene Do not eat, drink and smoke in work areas. Wash hands after use. Remove contaminated clothing and protective equipment before entering eating areas. Conditions for safe storage, including any incompatibilities Store locked up. Further information on storage conditions: Keep container tightly closed and dry in a cool, well-ventilated place.