SAFETY DATA SHEET - Stepan Company

1 SAFETY DATA SHEET1. IdentificationProduct identifierSTEPAN BIO-DIESEL SB-DOther means of identificationProduct code0866 Recommended useSurfactantRecommended restrictionsFor industrial use informationManufacturerStepan CompanyAddress22 West Frontage RoadCompany nameTelephoneGeneral1-847-446-7500 Emergency phone numberMedical1-800-228-5635 Chemtrec1-800-424-9300 Chemtrec Int'l +1 703-527-3887E-mailUSANot , IL 600932. Hazard(s) identificationNot hazardsCategory 2 BSerious eye damage/eye irritationHealth hazardsNot hazardsNot defined hazardsLabel symbolSignal wordWarningHazard statementMay be harmful in contact with skin. Causes eye thoroughly after in eyes: Rinse cautiously with water for several minutes.

2 Remove contact lenses, if present andeasy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If eye irritation persists:Get medical away from incompatible of waste and residues in accordance with local authority (s) not otherwiseclassified (HNOC)None Composition/information on ingredientsMixturesCAS number%Chemical nameCommon name and synonyms67784-80-9 Methyl ester, soybean oil (Alt CAS68919-53-9)90 - 1004. First-aid measuresInhalationMove to fresh air. Call a physician if symptoms develop or contactWash off with soap and water. Call a POISON CENTER or doctor/physician if you feel unwell. Getmedical attention if irritation develops and contactImmediately flush eyes with plenty of water for at least 15 minutes.

3 Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and mouth. Call a POISON CENTER or doctor/physician if you feel importantsymptoms/effects, acute anddelayedExposed individuals may experience eye tearing, redness, and / 6 Material name: Stepan BIO-DIESEL SB-DMaterial ID: 6300 Product code: 0866 Version #: 01 Revision date: 09-01-2014 Print date: 09-01-2014 SDS USIndication of immediatemedical attention and specialtreatment neededProvide general supportive measures and treat symptomatically. Keep victim under may be informationEnsure that medical personnel are aware of the material(s) involved, and take precautions toprotect Fire-fighting measuresSuitable extinguishing mediaWater fog.

4 Foam. Dry chemical powder. Carbon dioxide (CO2).Unsuitable extinguishingmediaDo not use water jet as an extinguisher, as this will spread the hazards arising fromthe chemicalPorous material such as rags, paper, insulation, or organic clay may spontaneously combust whenwetted with this material. During fire, gases hazardous to health may be protective equipmentand precautions for firefightersSelf-contained breathing apparatus and full protective clothing must be worn in case of containers from fire area if you can do so without methodsUse standard firefighting procedures and consider the hazards of other involved fire hazardsNo unusual fire or explosion hazards Accidental release measuresPersonal precautions,protective equipment andemergency proceduresKeep unnecessary personnel away.

5 Keep people away from and upwind of spill/leak. Wearappropriate protective equipment and clothing during clean-up. Do not touch damaged containersor spilled material unless wearing appropriate protective clothing. Ensure adequate authorities should be advised if significant spillages cannot be contained. For personalprotection, see section 8 of the and materials forcontainment and cleaning upThe product is immiscible with water and will spread on the water Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic SHEET to prevent spreading. Absorb in vermiculite, dry sand or earthand place into containers. Use clean non-sparking tools to collect absorbed material.

6 Followingproduct recovery, flush area with Spills: Wipe up with absorbent material ( cloth, fleece). Clean surface thoroughly toremove residual return spills to original containers for re-use. For waste disposal, see section 13 of the precautionsAvoid discharge into drains, water courses or onto the Handling and storagePrecautions for safe handlingDo not handle, store or open near an open flame, sources of heat or sources of ignition. Protectmaterial from direct sunlight. Avoid contact with eyes. Avoid prolonged exposure. Provideadequate ventilation. Wear appropriate personal protective equipment. Observe good industrialhygiene practices. Wash contaminated clothing before for safe storage,including any incompatibilitiesDo not handle or store near an open flame, heat or other sources of ignition.

7 Prevent electrostaticcharge build-up by using common bonding and grounding techniques. Store in original tightlyclosed container. Store away from incompatible materials (see Section 10 of the SDS).8. Exposure controls/personal protectionOccupational exposure limitsNo exposure limits noted for ingredient(s).Biological limit valuesNo biological exposure limits noted for the ingredient(s).Appropriate engineeringcontrolsGood general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level.

8 Provideeyewash protection measures, such as personal protective equipmentEye/face protectionWear eye/face protection. Wear SAFETY glasses with side shields (or goggles).Hand protectionFor prolonged or repeated skin contact use suitable protective protectionOtherWear suitable protective protectionIn case of insufficient ventilation, wear suitable respiratory hazardsWear appropriate thermal protective clothing, when / 6 Material name: Stepan BIO-DIESEL SB-DMaterial ID: 6300 Product code: 0866 Version #: 01 Revision date: 09-01-2014 Print date: 09-01-2014 SDS USGeneral hygieneconsiderationsAlways observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking.

9 Routinely wash work clothing and protectiveequipment to remove contaminants. Eye wash fountain and emergency showers Physical and chemical propertiesAppearanceNot thresholdNot point/freezing pointNot boiling point and boilingrange> 600 F (> C)Flash point> 201 F (> C) Pensky-Martens Closed CupEvaporation rateEstimated slower than ethyl (solid, gas)Not flammability or explosive limitsFlammability limit - upper(%)NOT limit - lower (%)Not limit - upper (%)Not pressure< mmHgVapor densityEstimated heavier than densityNot (ies)Solubility (water)Not temperatureNot temperatureNot cps @ 25 COther lbs/gal (@ 25C)VOC (Weight %)4 %10. Stability and reactivityReactivityThe product is stable and non-reactive under normal conditions of use, storage and stabilityMaterial is stable under normal of hazardousreactionsNo dangerous reaction known under conditions of normal to avoidAvoid temperatures exceeding the flash point.

10 Contact with incompatible materialsStrong oxidizing decompositionproductsNo hazardous decomposition products are Toxicological informationInformation on likely routes of exposureIngestionExpected to be a low ingestion inhalation may be contactMay be harmful in contact with contactCauses eye related to thephysical, chemical andtoxicological characteristicsExposed individuals may experience eye tearing, redness, and on toxicological effectsAcute toxicityMay be harmful in contact with / 6 Material name: Stepan BIO-DIESEL SB-DMaterial ID: 6300 Product code: 0866 Version #: 01 Revision date: 09-01-2014 Print date: 09-01-2014 SDS USTest ResultsProductSpeciesSTEPAN BIO-DIESEL SB-DLD50 RabbitDermalAcute2000 - 20000 mg/kgLD50 RatOral5000 - 15000 mg/kgSkin corrosion/irritationProlonged skin contact may cause temporary eye damage/eyeirritationCauses eye or skin sensitizationRespiratory sensitizationNot sensitizationThis product is not expected to cause skin cell mutagenicityNo data available to indicate product or any components present at greater than aremutagenic or product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA Specifically Regulated Substances (29 CFR )