SAFETY DATA SHEET - Stepan Company

1 SAFETY data SHEET1. IdentificationSTEOL CS-460 product identifierOther means of identification1808 product codeSurfactantRecommended useFor industrial use restrictionsManufacturer/Importer/Suppli er/Distributor informationManufacturerStepan CompanyAddress22 West Frontage RoadCompany nameTelephoneGeneral1-847-446-7500 Emergency phone numberMedical1-800-228-5635 Chemtrec1-800-424-9300 Chemtrec Int'l +1 703-527-3887E-mailUSANot , IL 600932. Hazard(s) identificationCategory 3 Flammable liquidsPhysical hazardsCategory 2 Skin corrosion/irritationHealth hazardsCategory 1 Serious eye damage/eye irritationCategory 2 Hazardous to the aquatic environment, acutehazardEnvironmental hazardsCategory 3 Hazardous to the aquatic environment,long-term hazardNot defined hazardsLabel elementsSignal wordDangerHazard statementFlammable liquid and vapor. Causes skin irritation. Causes serious eye damage. Toxic to aquaticlife. Harmful to aquatic life with long lasting statementPreventionKeep container tightly closed.

2 Keep away from heat/sparks/open flames/hot surfaces. - Nosmoking. Ground/bond container and receiving equipment. Use explosion-proofelectrical/ventilating/li ghting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge. Wash thoroughly after handling. Avoid release to theenvironment. Wear protective gloves/eye protection/face on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment (seethis label). If skin irritation occurs: Get medical advice/attention. Take off contaminated clothingand wash before reuse. In case of fire: Use appropriate media to in a well-ventilated place. Keep of contents/container in accordance with local/regional/national/international (s) not otherwiseclassified (HNOC)Static accumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment.

3 Sparks may ignite liquid and vapor. May cause flash fire or / 8 Material name: STEOL CS-460 Material ID: 1211 product code: 1808 Version #: 04 Revision date: 08-09-2016 Print date: 08-09-2016 SDS US3. Composition/information on ingredientsMixturesCAS number%Common name and synonymsChemical name9004-82-458 - < 61_Sodium laureth (n=>3) sulfate7732-18-523 - < 27 Water64-17-513 - < 16 EthanolOther components below reportable levels< 168131-39-50 - 3 Alcohols (c12-15 Ln. Saturated)Ethoxylate4. First-aid measuresMove to fresh air. Call a physician if symptoms develop or off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritationoccurs: Get medical advice/attention. Take off contaminated clothing and wash before contactImmediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and contactRinse mouth.

4 Get medical attention if symptoms occur. Do not induce vomiting without advice frompoison control may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. Maycause redness and importantsymptoms/effects, acute anddelayedProvide general supportive measures and treat symptomatically. Thermal burns: Flush with waterimmediately. While flushing, remove clothes which do not adhere to affected area. Call anambulance. Continue flushing during transport to hospital. Keep victim under may be of immediatemedical attention and specialtreatment neededTake off all contaminated clothing immediately. Ensure that medical personnel are aware of thematerial(s) involved, and take precautions to protect themselves. Wash contaminated clothingbefore information5. Fire-fighting measuresAlcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,sand or earth may be used for small fires extinguishing mediaDo not use water jet as an extinguisher, as this will spread the extinguishingmediaVapors may form explosive mixtures with air.

5 Vapors may travel considerable distance to a sourceof ignition and flash back. This product is a poor conductor of electricity and can becomeelectrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures canoccur. To reduce potential for static discharge, use proper bonding and grounding liquid may accumulate static electricity when filling properly grounded containers. Staticelectricity accumulation may be significantly increased by the presence of small quantities of wateror other contaminants. Material will float and may ignite on surface of water. During fire, gaseshazardous to health may be hazards arising fromthe chemicalSelf-contained breathing apparatus and full protective clothing must be worn in case of protective equipmentand precautions for firefightersIn case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can doso without fightingequipment/instructionsUse standard firefighting procedures and consider the hazards of other involved methodsFlammable liquid and fire hazards6.

6 Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).Wear appropriate protective equipment and clothing during clean-up. Do not touch damagedcontainers or spilled material unless wearing appropriate protective clothing. Ventilate closedspaces before entering them. Use appropriate containment to avoid environmental authorities should be advised if significant spillages cannot be contained. For personalprotection, see section 8 of the precautions,protective equipment andemergency procedures2 / 8 Material name: STEOL CS-460 Material ID: 1211 product code: 1808 Version #: 04 Revision date: 08-09-2016 Print date: 08-09-2016 SDS USEliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Takeprecautionary measures against static discharge.

7 Use only non-sparking tools. Keep combustibles(wood, paper, oil, etc.) away from spilled Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic SHEET to prevent spreading. Use a non-combustible material likevermiculite, sand or earth to soak up the product and place into a container for later entry into waterways, sewer, basements or confined areas. Following product recovery,flush area with Spills: Wipe up with absorbent material ( cloth, fleece). Clean surface thoroughly toremove residual return spills to original containers for re-use. For waste disposal, see section 13 of the and materials forcontainment and cleaning upAvoid release to the environment. Contact local authorities in case of spillage to drain/aquaticenvironment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoiddischarge into drains, water courses or onto the ground.

8 Use appropriate containment to avoidenvironmental precautions7. Handling and storageVapors may form explosive mixtures with air. Do not handle, store or open near an open flame,sources of heat or sources of ignition. Protect material from direct sunlight. Do not fire risks from flammable and combustible materials (including combustible dust andstatic accumulating liquids) or dangerous reactions with incompatible materials. Handlingoperations that can promote accumulation of static charges include but are not limited to: mixing,filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and containerfilling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Takeprecautionary measures against static discharges. All equipment used when handling the productmust be grounded. Use non-sparking tools and explosion-proof equipment. Avoid contact withskin. Avoid contact with eyes.

9 Avoid prolonged exposure. Avoid contact with clothing. Provideadequate ventilation. Wear appropriate personal protective equipment. Observe good industrialhygiene practices. Avoid release to the environment. Do not empty into for safe handlingKeep away from heat, sparks and open flame. Prevent electrostatic charge build-up by usingcommon bonding and grounding techniques. Avoid spark promoters. Eliminate sources of container and equipment. These alone may be insufficient to remove staticelectricity. Store in original tightly closed container. Store in a cool, dry place out of direct in a well-ventilated place. Refrigeration recommended. Store away from incompatiblematerials (see Section 10 of the SDS). Keep in an area equipped with for safe storage,including any incompatibilities8. Exposure controls/personal protectionOccupational exposure limitsUS. OSHA Table Z-1 Limits for Air Contaminants (29 CFR )ValueComponentsTypePEL1900 mg/m3 Ethanol (CAS 64-17-5)1000 ppmUS.

10 ACGIH Threshold Limit ValuesValueComponentsTypeSTEL1000 ppmEthanol (CAS 64-17-5)US. NIOSH: Pocket Guide to Chemical HazardsValueComponentsTypeTWA1900 mg/m3 Ethanol (CAS 64-17-5)1000 ppmNo biological exposure limits noted for the ingredient(s).Biological limit valuesExplosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 airchanges per hour) should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not beenestablished, maintain airborne levels to an acceptable level. Eye wash facilities and emergencyshower must be available when handling this engineeringcontrolsIndividual protection measures, such as personal protective equipmentWear SAFETY glasses with side shields (or goggles).Eye/face protection3 / 8 Material name: STEOL CS-460 Material ID: 1211 product code: 1808 Version #: 04 Revision date: 08-09-2016 Print date: 08-09-2016 SDS USSkin protectionWear appropriate chemical resistant protectionWear appropriate chemical resistant case of insufficient ventilation, wear suitable respiratory protectionWear appropriate thermal protective clothing, when hazardsWhen using do not smoke.