Safety Data Sheet - Syngenta

1 Safety data Sheet7/18/20111/14/2015 Replaces:Date: bravo ZN 1. PRODUCT IDENTIFICATIONA7867 GUse:FungicideProduct identifier on label: bravo ZNManufacturer: Syngenta Crop Protection, LLCPost Office Box 18300 Greensboro NC 27419 Manufacturer Phone:1-800-334-9481 Emergency Phone:1-800-888-8372 Product No.: 2. HAZARDS IDENTIFICATIONW arningClassifications:Signal Word (OSHA):Causes skin irritationHazard Statements:May cause an allergic skin reactionCauses eye irritationFatal if inhaledMay cause respiratory irritationMay cause drowsiness or dizzinessSuspected of causing cancer May cause damage to organs through prolonged or repeated exposure Skin Corrosion/Irritation: Category 2 Skin Sensitizer: Category 1 BCarcinogenicity: Category 2 Specific Target Organ Toxicity: Repeated Category 2 Specific Target Organ Toxicity: Drowsiness Category 3 Specific Target Organ Toxicity: Respiratory Irritation Category 3 Eye Damage/Irritation: Category 2 BInhalation.

2 Category 2 Precautionary Statements:Obtain special instructions before not handle until all Safety precautions have been read and not breathe mist, vapors, hands and face thoroughly after Symbols:Page 1 of 9 Safety data Sheet7/18/20111/14/2015 Replaces:Date: bravo ZNIngredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. 3. COMPOSITION/INFORMATION ON INGREDIENTSC hemical NameConcentrationCommon NameCAS Number1,2-PropanediolPropylene Glycol57-55-6 Trade SecretSilica, amorphousSilica, amorphous112926-00-8 Trade SecretZinc OxideZinc Oxide1314-13-2< 6%Other ingredientsOther ingredientsTrade Secret> 4. FIRST AID MEASURESHave the product container, label or Safety data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice.

3 Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment :Eye Contact:Skin Contact:NoneOther Hazard Statements:Use only outdoors or in a well-ventilated work clothing must not be allowed out of the protective gloves, protective clothing, eye case of inadequate ventilation wear respiratory protection.

4 See Section 8 Exposure Control/Personal Protection. If on skin: Wash with plenty of soap and skin irritation or rash occurs: Get medical in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue eye irritation persists: Get medical inhaled: Remove person to fresh air and keep comfortable for exposed or concerned: Get medical call a poison center, doctor or a poison center, doctor or Syngenta if you feel treatment is urgent (see Section 4 First Aid Measures).Take off contaminated clothing and wash it before locked of contents and container in accordance with local 2 of 9 Safety data Sheet7/18/20111/14/2015 Replaces:Date: bravo ZNIf inhaled: Move person to fresh air.

5 If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment :Indication of immediate medical attention and special treatment needed:Most important symptoms/effects:There is no specific antidote if this product is suffering a temporary allergic reaction may respond to treatment with antihistamines or steroid creams and/or systemic irritationSkin irritationAllergic skin reactionDrowsiness or dizzinessRespiratory irritation 5. FIRE FIGHTING MEASURESS uitable (and unsuitable) extinguishing media:Specific Hazards:Special protective equipment and precautions for firefighters:Use dry chemical, foam or CO2 extinguishing media.

6 If water is used to fight fire, dike and collect a fire, irritating and possibly toxic gases may be generated by thermal decomposition or full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. 6. ACCIDENTAL RELEASE MEASURESP ersonal precautions, protective equipment, and emergency procedures:Methods and materials for containment and cleaning up:Follow exposure controls/personal protection outlined in Section the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water.

7 Clean up spills immediately, observing precautions outlined in Section 8. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent ( commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. HANDLING AND STORAGEP recautions for safe handling:Conditions for safe storage, including any incompatibilities:Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area.

8 Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after locked 3 of 9 Safety data Sheet7/18/20111/14/2015 Replaces:Date: bravo ZN 8. EXPOSURE CONTROLS/PERSONAL PROTECTIONI ngestion:Eye Contact:Skin Contact:Inhalation:THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT Exposure Limits:Appropriate engineering controls:Use effective engineering controls to comply with occupational exposure limits (if applicable).

9 Individual protection measures:Chemical NameOtherOSHA PELACGIH TLVS ourcePropylene GlycolNot EstablishedNot Established10 mg/m TWA AIHAS ilica, amorphous80 mg/m /% SiO2 TWANot Established6 mg/m TWANIOSHZinc Oxide15 mg/m TWA (total dust); 5 mg/m TWA (respirable)2 mg/m TWA (total dust); 10 mg/m STEL (respirable)5 mg/m TWA (dust); 15 mg/m CeilingNIOSHO ther ingredientsNot ApplicableNot ApplicableNot ApplicableNot ApplicableChlorothalonilNot EstablishedNot mg/m TWA SyngentaPrevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after eye contact is likely, use chemical splash contact is likely, wear chemical-resistant gloves (such as barrier laminate, butyl rubber, nitrile rubber, neoprene rubber, natural rubber, polyethylene, polyvinyl chloride [PVC] or Viton), coveralls, socks and chemical-resistant respirator is not normally required when handling this substance.

10 Use effective engineering controls to comply with occupational exposure case of emergency spills, use a NIOSH certified respirator with any N, R, P or HE viscous suspension 9. PHYSICAL AND CHEMICAL - Odor:Appearance:212 FNot ApplicableInitial boiling point and boiling range:Melting point/freezing point:Odor Threshold:Not AvailableNot ApplicableFlammability:Not ApplicableNot AvailableFlash Point (Test Method):Flammable Limits (% in Air):Page 4 of 9 Safety data Sheet7/18/20111/14/2015 Replaces:Date: bravo ZNVapor Pressure:Solubility (ies):Not ApplicableAutoignition Temperature:Vapor Density:Relative Density:Not AvailableDecomposition Temperature:Not AvailableViscosity:Not ApplicablePartition coefficient: n-octanol/water.