SAFETY DATA SHEET - tyfo.de

1 SECTION 1. Identification of the Substance / Mixture and of the Company Product identifier: TYFOCOR LS Arctic ready-to-use, frost protection -47 C Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Heat transfer fluid for solar thermal systems Details of the supplier of the SAFETY data SHEET Identification of TYFOROP Chemie GmbH, Anton-R e-Weg 7, D - 20537 Hamburg the company: Tel.: +49 (0)40 -20 94 97-0, Fax: -20 94 97-20, e-mail: Information about the product: E-mail (competent person): | Emergency information: Tel.: +49 (0)551-19240 GIZ-Nord Poison Center SECTION 2.

2 Hazards Identification Classification of the substance or mixture According to Regulation (EC) No. 1272/2008 [CLP] No need for classification according to GHS criteria for this product. According to Directive 67/548/EEC or 1999/45/EC Possible hazards: No particular hazards known. Label elements According to Regulation (EC) No. 1272/2008 [CLP] / Globally Harmonized System, EU (GHS) The product does not require a hazard warning label in accordance with GHS criteria. According to Directive 67/548/EEC or 1999/45/EC ('Preparation Directive') The product does not require a hazard warning label in accordance with EC Directives. Other hazards According to Regulation (EC) No. 1272/2008 [CLP] No other hazards known. SECTION 3.

3 Composition / Information on Ingredients Chemical nature: Aqueous solution of propane-1,2-diol (propylene glycol) with inhibitors. Hazardous ingredients according to Regulation 1272/2008/EC and Directive 1999/45/EC Substance Reg. 1272/2008/EC [CLP/GHS] Dir. 1999/45/EC . 1,1 -Iminodipropane-2-ol Content (w/w): > 1 % - < 3 % Eye 2 Hazard symbol: Xi CAS Number: 110-97-4 H319 R-phrases: 36 EC Number: 203-820-9 INDEX Number: 603-083-00-7 REACH Reg. No: 01-2119475444-34 For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R-phrases, and the hazard statements, the full text is listed in section 16.

4 SECTION 4. First-Aid Measures Description of first aid measures General advice: Remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. SAFETY DATA SHEET according to Regulation 1907/2006/EC [REACH] Revised Printing date: Page 01 of 05 TYFOROP SAFETY Data SHEET Revised: Printing Date: Product: TYFOCOR LS Arctic ready-to-use, frost protection -47 C Page 02 of 05 SECTION 4. First-Aid Measures - Continuation On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water.

5 Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling of the pro- duct (see section 2) and/or in section 11. Further important symptoms and effects are so far not known. Indication of any immediate medical attention and special treatment needed Treatment: Symptomatic treatment (decontamination, vital functions), no known specific antidote. SECTION 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing The product is non-flammable. Water spray, dry powder, and alcohol- media: resistant foam are suitable for extinguishing environmental fire. Special hazards arising from the substance or mixture Harmful vapours. Evolution of fumes/fog.

6 The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. SECTION 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For large amounts: Pump off product. For residues: Pick up with suitable absorbent material.

7 Dispose of absorbed material in accordance with regulations. Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13. SECTION 7. Handling and Storage Precautions for safe handling Advice on safe handling: No special precautions necessary. Advice on protection against fire/explosion: No special precautions necessary. Conditions for safe storage, including any incompatibilities Further information on Containers should be stored tightly sealed in a dry, cool place. Storage in storage conditions: galvanized containers is not recommended. Specific end uses For the relevant identified uses listed in section 1 the advice mentioned in this section 7 is to be observed.

8 SECTION 8. Exposure Control / Personal Protection Control parameters Components with occupational exposure limits: - TYFOROP SAFETY Data SHEET Revised: Printing Date: Product: TYFOCOR LS Arctic ready-to-use, frost protection -47 C Page 03 of 05 SECTION 8. Exposure Control / Personal Protection - Continuation Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 C, EN 14387 type A). Hand protection: Chemical resistant protective gloves (EN 374). Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresp.)

9 > 30 minutes of permeation time according to EN 374) butyl rubber (butyl) - mm coating thickness, nitrile rubber (NBR) - mm coating thickness. Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions ( temperature) it must be considered that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

10 Manufacturers directions for use should be observed because of great diversity of types. Eye protection: SAFETY glasses with side-shields (frame goggles) ( EN 166). General SAFETY and Handle in accordance with good industrial hygiene and SAFETY practice. hygiene measures: Wearing of closed work clothing is recommended. SECTION 9. Physical and Chemical Properties Information on basic physical and chemical properties Form: liquid. Colour: red fluorescent. Odour: product specific. pH value (20 C): - (ASTM D 1287) Freezing point: approx.