Transcription of SAFETY DATA SHEET Unleaded Gasoline 95 …
1 SAFETY data SHEET Unleaded Gasoline 95 Octane ( premium )Prepared according to Annex II of EC regulation 1907/2006 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE Product identifierProduct nameUnleaded Gasoline 95 Octane ( premium )Synonyms, Trade NamesYeni nesil V/max 97 Relevant identified uses of the substance or mixture and uses advised againstIdentified usesFuel for spark ignition engines designed to run on Unleaded advised againstThis product must not be used in applications other than those recommended in Section 1, without first seeking the advice of the supplier. This product is not to be used as a solvent or cleaning agent; for lighting or brightening fires; as a skin cleanser. This product is designed only to suit automotive applications and no provision is made for the requirements of aviation Details of the supplier of the SAFETY data sheetOMV PETROL OF S A..SupplierAyaza a Eski B y kdere :33-37 B Blok 34398 Maslak-Istanbul/TURKEYTel: +90 212 329 1500 Fax: +90 212 329 Person0 800 211 02 290 555 675 55 Emergency telephone numberPOA : +90 212 329 17 79 (office hours)National Emergency Telephone NumberNational Poison Consultance Center: 114 SECTION 2: HAZARDS Classification of the substance or mixtureClassification (1999/45/EEC)Carc.
2 Cat. 2;R45, Muta. Cat. 2;R46. Xn;R65. Repr. Cat. 3;R63. Xi;R38. F+;R12. N;R51/53. Gasoline 95 Octane ( premium )Human healthVapours may cause drowsiness and dizziness. Slightly irritating to respiratory system. Irritating to skin. Moderately irritating to eyes. Harmful: May cause lung damage if swallowed. Possibility of organ or organ system damage from prolonged exposure; see Chapter 11 for details. Target organ(s): Bloodforming organs. Peripheral nervous system. May cause heritable genetic damage. Possible risk of harm to the unborn child. A component or components of this material may cause cancer. This product contains benzene which may cause leukaemia (AML acute myelogenous leukaemia). Signs and Symptoms : Skin irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blisters. Eye irritation signs and symptoms may include a burning sensation and a temporary redness of the eye. If material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever.
3 The onset of respiratory symptoms may be delayed for several hours after exposure. Breathing of high vapour concentrations may cause central nervous system (CNS) depression resulting in dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness and death. Damage to blood-forming organs may be evidenced by: a) fatigue and anaemia (RBC), b) decreased resistance to infection, and/or excessive bruising and bleeding (platelet effect). Peripheral nerve damage may be evidenced by impairment of motor function (incoordination, unsteady walk, or muscle weakness in the extremities, and/or loss of sensation in the arms and legs). Auditory system effects may include temporary hearing loss and/or ringing in the to aquatic organisms; may cause long-term adverse effects in the aquatic environment. Ether oxygenates are significantly more water soluble and less biodegradable than benzene, toluene, ethyl benzene and xylenes (BTEX).
4 Consequently ether oxygenates have the potential to migrate relatively longer distances than BTEX in and Chemical HazardsExtremely flammable. Electrostatic charges may be generated during handling. Electrostatic discharge may cause fire. Liquid evaporates quickly and can ignite leading to a flash fire, or an explosion in a confined Label elementsEC ; LOW BOILING POINT NAPHTHA - UNSPECIFIEDL abellingToxicExtremely flammableDangerous for the environmentRisk PhrasesR45 May cause cause heritable genetic : may cause lung damage if risk of harm to the unborn may cause drowsiness and to to aquatic organisms, may cause long-term adverse effects in the aquatic PhrasesS45In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).S53 Avoid exposure - obtain special instructions before release to the environment. Refer to special instructions/ SAFETY data out of the reach of not empty into swallowed, do not induce vomiting: seek medical advice immediately and show this container or Other hazardsSECTION 3: COMPOSITION/INFORMATION ON Mixtures112/ Unleaded Gasoline 95 Octane ( premium )ETHANOL1-5%CAS-No.
5 : 64-17-5EC No.: 200-578-6 Classification (67/548/EEC)F;R11 Classification (EC 1272/2008)Flam. Liq. 2 - H225 Gasoline ; LOW BOILING POINT NAPHTHA - UNSPECIFIED60-100%CAS-No.: 86290-81-5EC No.: 289-220-8 Classification (67/548/EEC)Carc. Cat. 2;R45 Muta. Cat. 2;R46 Xn;R65 Classification (EC 1272/2008)Muta. 1B - H340 Carc. 1B - H350 Asp. Tox. 1 - H304 TERT-BUTYL METHYL ETHER10-30%CAS-No.: 1634-04-4EC No.: 216-653-1 Classification (67/548/EEC)F;R11 Xi;R38 Classification (EC 1272/2008)Flam. Liq. 2 - H225 Skin Irrit. 2 - H315 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section notesMay contain several additives at < v/v each. May contain catalytically cracked oils in which polycyclic aromatic compounds, mainly 3-ring but some 4- to 6-ring species are CommentsComplex mixture of hydrocarbons consisting of paraffins, cycloparaffins, aromatic and olefinic hydrocarbons (including benzene at maximum), with carbon numbers predominantly in the C4 to C12 range.
6 Contains oxygenated hydrocarbons which may include methyl tertiary butyl ether (MTBE) and other ethers. May also contain several additives at < v/v 4: FIRST AID Description of first aid measuresInhalationRemove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101 F (37 C), shortness of breath, chest congestion or continued coughing or contactRemove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional contactFlush eyes with water while holding eyelids open.
7 Rest eyes for 30 minutes. If redness, burning, blurred vision, or swelling persist, transport to the nearest medical facility for additional Most important symptoms and effects, both acute and Indication of any immediate medical attention and special treatment needed113/ Unleaded Gasoline 95 Octane ( premium )No specific treatment. Treat 5: FIREFIGHTING Extinguishing mediaExtinguishing mediaFoam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires extinguishing mediaDo not use water in a Special hazards arising from the substance or mixtureHazardous combustion productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. The vapour is heavier than air, spreads along the ground and distant ignition is possible. Will float and can be reignited on surface Advice for firefightersSpecial Fire Fighting ProceduresKeep adjacent containers cool by spraying with water.
8 If possible remove containers from the danger zone. If the fire cannot be extinguished the only course of action is to evacuate immediately. Contain residual material at affected sites to prevent material from entering drains (sewers), ditches, and equipment for fire-fightersProper protective equipment including breathing apparatus must be worn when approaching a fire in a confined 6: ACCIDENTAL RELEASE Personal precautions, protective equipment and emergency proceduresAvoid contact with spilled or released the relevant local and international regulations. Evacuate the area of all nonessential personnel. Ventilate contaminated area thoroughly. Do not breathe fumes, vapour. Do not operate electrical equipment. Shut off leaks, if possible without personal risks. Remove all possible sources of ignition in the surrounding area. Take precautionary measures against static discharge. Ensure electrical continuity by bonding and grounding (earthing) all Environmental precautionsUse appropriate containment (of product and fire fighting water) to avoid environmental contamination.
9 Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Attempt to disperse the vapour or to direct its flow to a safe location for example by using fog sprays. Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. Local authorities should be advised if significant spillages cannot be contained. Maritime spillages should be dealt with using a Shipboard Oil Pollution Emergency Plan (SOPEP), as required by MARPOL Annex 1 Regulation Methods and material for containment and cleaning upFor small liquid spills (< 1 drum), transfer by mechanical means to a labelled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. For large liquid spills (> 1 drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal.
10 Do not flush away residues with water. Retain as contaminated waste. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. Shovel into a suitable clearly marked container for disposal or reclamation in accordance with local Reference to other sections For guidance on selection of personal protective equipment see Chapter 8 of this Material SAFETY data SHEET . See Chapter 13 for information on 7: HANDLING AND Precautions for safe handling114/ Unleaded Gasoline 95 Octane ( premium )Avoid breathing vapours or contact with material. Only use in well ventilated areas. Wash thoroughly after handling. For guidance on selection of personal protective equipment see Chapter 8 of this Material SAFETY data SHEET . Use the information in this data SHEET as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material.