SAFETY DATA SHEET - Verven - Peintures

1 2100 Hard-Hat Series FinishesSAFETY data SHEETP roduct name2100 Hard-Hat Series Product Details of the supplier of the SAFETY data type:e-mail address of person responsible for this SDS:Product description:Aerosol. Relevant identified uses of the substance or mixture and uses advised againstIndustrial usesConsumer usesProfessional usesIdentified usesSECTION 1: Identification of the substance/mixture and of the company/undertakingNone advised Emergency telephone numberSupplierTelephone number:Hours of operation:Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. Europe - Martin Mathys NV, Kolenbergstraat 23, B-3545 Zelem, BelgiumTelephone no.: +32 (0) 13 460 200 Fax no.: +32 (0) 13 460 20124 / 7+44 (0) 207 858 1228 See Section 11 for more detailed information on health effects and according to Regulation (EC) No. 1272/2008 [CLP/GHS]SECTION 2: Hazards Classification of the substance or mixtureProduct definition:MixtureSee Section 16 for the full text of the H statements declared Label elementsAerosol 1, H222, H229 Skin Irrit.

2 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335 STOT RE 2, H373 The product is classified as hazardous according to Regulation (EC) 1272/2008 as of issue/Date of revision:15/01/2018 Date of previous issue:29/11/2017 Hard-Hat Series FinishesConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 SECTION 2: Hazards identificationHazardous ingredients::Other hazards which do not result in classificationNone pictograms:Signal word:Hazard statements:Prevention:Precautionary statementsResponse:Storage:Disposal:Dang erExtremely flammable container: May burst if serious eye skin cause respiratory cause damage to organs through prolonged or repeated - Keep away from heat, sparks, open flames and hot surfaces. - No - Do not spray on an open flame or other ignition - Do not pierce or burn, even after use. Do not pierce or burn, even after - Do not breathe vapour or - Use only outdoors or in a well-ventilated - Wear protective gloves and eye protection: - nitrile rubber gloves and SAFETY glasses with side - IF ON SKIN:P352 - Wash with plenty of soap and + P412 - Protect from sunlight.

3 Do not expose to temperatures exceeding 50 - Dispose of contents and container in accordance with all local, regional,national and international label elementsContainers to be fitted with child-resistant fasteningsNot warning of dangerYes, applicable.:::Contains 2-butanone oxime. May produce an allergic packaging Other hazardsGeneral:P102 - Keep out of reach of - Read label before - If medical advice is needed, have product container or label at XVII - Restrictions on the manufacture,placing on the market and use of certain dangerous substances, mixtures and articles:Not (mixture of isomeres)Date of issue/Date of revision:15/01/2018 Date of previous issue:29/11/2017 Hard-Hat Series FinishesConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 SECTION 3: Composition/information on ingredientsIdentifiersProduct/ingredient namedimethyl etherEC: 204-065-8 CAS: 115-10-6 Index: 603-019-00-8 50 - 75 Flam.

4 Gas 1, H220[2]xylene (mixture of isomeres)REACH #:01-2119488216-32EC: 215-535-7 CAS: 1330-20-7 10 - 25 Flam. Liq. 3, H226 Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335 STOT RE 2, H373 Asp. Tox. 1, H304[1] [2]ethylbenzeneREACH #:01-2119489370-35EC: 202-849-4 CAS: 100-41-4 Index: 601-023-00-4 3 Flam. Liq. 2, H225 Acute Tox. 4, H332 STOT RE 2, H373 (hearing organs)Asp. Tox. 1, H304[1] [2]2-butanone oximeEC: 202-496-6 CAS: 96-29-7 Index: 616-014-00-0 0,3 Acute Tox. 4, H312 Eye Dam. 1, H318 Skin Sens. 1, H317 Carc. 2, H351[1]%TypeRegulation (EC) No. 1272/2008 [CLP]ClassificationSee Section 16 for the full text of the H statements declared exposure limits, if available, are listed in Section are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

5 [1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII[5] Substance of equivalent Mixtures:MixtureIf swallowed, seek medical advice immediately and show the container or person warm and at rest. Do NOT induce contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained 4: First aid measuresGeneralIn all cases of doubt, or when symptoms persist, seek medical attention.

6 Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice.:Skin Description of first aid measuresIngestionInhalationEye contact::::Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth of issue/Date of revision:15/01/2018 Date of previous issue:29/11/2017 Hard-Hat Series FinishesConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 SECTION 4: First aid measuresSee toxicological information (Section 11)There are no data available on the mixture itself. The mixture has been assessed following the conventional method of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly.

7 See Sections 2 and 3 for to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the splashed in the eyes, the liquid may cause irritation and reversible may cause nausea, diarrhea and takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye 2-butanone oxime.

8 May produce an allergic to physicianTreat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.:Specific Most important symptoms and effects, both acute and Indication of any immediate medical attention and special treatment neededNo specific treatment.:Over-exposure signs/symptomsEye contact:Adverse symptoms may include the following:pain or irritationwateringredness:Adverse symptoms may include the following:respiratory tract irritationcoughingInhalationSkin contact:Adverse symptoms may include the following:irritationrednessNo specific data .:IngestionSECTION 5: Firefighting measuresRecommended: alcohol-resistant foam, CO , powders, water not use water thermal decomposition productsHazards from the substance or Extinguishing media::Suitable extinguishing media:Unsuitable extinguishing Special hazards arising from the substance or mixtureExtremely flammable aerosol.

9 In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxidesDate of issue/Date of revision:15/01/2018 Date of previous issue:29/11/2017 Hard-Hat Series FinishesConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 SECTION 5: Firefighting measuresSpecial protective equipment for fire- Advice for firefightersSpecial protective actions for fire-fighters:Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

10 Move containers from fire area if this can be done without water spray to keep fire-exposed containers should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection for chemical information:Pressurised container: protect from sunlight and do not expose to temperature exceeding 50 C. Do not pierce or burn, even after use. Do not puncture, incinerate or store the container at temperatures above 49 C (120 F) or in direct explosion may occur under fire conditions or when heated. Bursting aerosol containers may be propelled from a fire at high action shall be taken involving any personal risk or without suitable surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurised contents and propellant.