SDS EU (Reach Annex II) - 1env Solutions Ltd

1 IMIDASECT ANTS Safety Data Sheet according to Regulation (EU) No. 2015/830 Date of issue: 30/09/2014 Revision date: 17/06/2015 Supersedes: 30/09/2014 Version: 17/06/2015 EN (English) 1/1 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Product form : Mixture Trade name : IMIDASECT ANTS Name : Imidacloprid Gel Product code : SHA 3200 B Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Biocide Uses advised against No additional information available Details of the supplier of the safety data sheet Sharda Cropchem Ltd. (formerly known as Sharda Worldwide Exports Pvt. Ltd.) Domnic Holm, 29th Road, Bandra (West) 400050 Mumbai - India T + 91 22 6678 2800 - F + 91 22 6678 2828 Emergency telephone number Emergency number : +91 22 6678 2800 (08-16h) Country Organisation/Company Address Emergency number UNITED KINGDOM Transportation Emergency, CARECHEM (24 HOUR) + 44 (0) 1865 407333 SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No.

2 1272/2008 [CLP]Mixture: SDS < 2015 : Show CLP information only Not classified Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display No labelling applicable Other hazards No additional information available SECTION 3: Composition/information on ingredients Substance Not applicable Mixture Name Product identifier % w/w Classification according to Regulation (EC) No. 1272/2008 [CLP] imidacloprid (ISO), 1-(6-chloropyridin-3-ylmethyl)-N-nitroim idazolidin-2-ylidenamine (CAS No) 138261-41-3 (EC no) 428-040-8 (EC index no) 612-252-00-4 < 0,1 Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of R- and H-statements: see section 16 SECTION 4: First aid measures Description of first aid measures First-aid measures general : If swallowed, seek medical advice immediately and show this container or label.

3 First-aid measures after inhalation : Move the affected person to the fresh air. If not breathing, give artificial respiration. Call a doctor. First-aid measures after skin contact : Remove contaminated clothes. After contact with skin, wash immediately with plenty of water. IMIDASECT ANTS Safety Data Sheet according to Regulation (EU) No. 2015/830 17/06/2015 EN (English) 2/1 First-aid measures after eye contact : Wash with plenty of water (during 20 minutes minimum) with eyes wide open after taking off soft contact lenses and immediately take medical advice. First-aid measures after ingestion : Rinse mouth. Immediately call a POISON CENTER or doctor/physician. Most important symptoms and effects, both acute and delayed No additional information available Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media : Water spray.

4 Dry powder. Foam. Carbon dioxide. Special hazards arising from the substance or mixture Fire hazard : Carbon monoxide. Advice for firefighters Firefighting instructions : Appropriate self-contained breathing apparatus may be required. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Wear suitable protective clothing, gloves and eye or face protection. Chemical resistant gloves (according to European standard NF EN 374 or equivalent). EC EN 166 "3". Wear eye protection. Personal protective equipment. EN ISO 20345. Emergency procedures : Evacuate personnel to a safe area. For emergency responders Protective equipment : Wear suitable hand, body and head protection. Environmental precautions Danger of pollution of drinking water when product enters the soil. Do not allow run-off from fire-fighting to enter drains or water courses.

5 Notify authorities if liquid enters sewers or public waters. Methods and material for containment and cleaning up For containment : Label the container and provide warning statements to prevent any contact. Methods for cleaning up : Soak up with inert absorbent material (for example sand, sawdust, a universal binder, silica gel). Clean spills promptly. Wash contaminated area with large amounts of water. Reference to other sections Reference to other sections (8, 13). SECTION 7: Handling and storage Precautions for safe handling Additional hazards when processed : Do not allow run-off from fire fighting to enter drains or water courses. Do not contaminate water with the product or its container (Do not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads). Precautions for safe handling : Avoid contact with skin and eyes. Do not eat, drink or smoke in areas where product is used.

6 Wash hands and other exposed areas with soap and water before leaving work. Remove contaminated clothing and shoes. Wash clothing and equipment after handling. Conditions for safe storage, including any incompatibilities Technical measures : Keep only in the original container in a cool well ventilated place. Store in a dry, cool area. Protect from light. Storage conditions : When not empty dispose of this container at hazardous or special waste collection point. Containers remain hazardous when empty. Continue to observe all precautions. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection Control parameters IMIDASECT ANTS United Kingdom Local name Glycerol, mist United Kingdom WEL TWA (mg/m ) 10 mg/m IMIDASECT ANTS Safety Data Sheet according to Regulation (EU) No. 2015/830 17/06/2015 EN (English) 3/1 Exposure controls Hand protection : Chemical resistant gloves (according to European standard NF EN 374 or equivalent) Eye protection : EC EN 166 "3".

7 Eye protection, including both chemical splash goggles and face shield, must be worn when possibility exists for eye contact due to spraying liquid or airborne particles Respiratory protection : Extra personal protection: P2 filter respirator for harmful particles. Extra personal protection: P3 filter respirator for toxic particles SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Physical state : Liquid Appearance : gel. Colour : Colourless. Odour : characteristic. Odour threshold : No data available pH : 7 - 8 Relative evaporation rate (butylacetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Auto-ignition temperature : 409 C Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : No data available Relative vapour density at 20 C : No data available Relative density : No data available Density : 1,3 - 1,4 g/ml Solubility : No data available Log Pow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : Product is not explosive.

8 Oxidising properties : Not classified. Explosive limits : No data available Other information No additional information available SECTION 10: Stability and reactivity Reactivity To our knowledge, the product does not present any particular risk, under normal conditions of use. Chemical stability The product is stable at normal handling and storage conditions. Possibility of hazardous reactions The product is stable at normal handling and storage conditions. Conditions to avoid Heat. Direct sunlight. Incompatible materials No additional information available Hazardous decomposition products No additional information available SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Not classified IMIDASECT ANTS Safety Data Sheet according to Regulation (EU) No. 2015/830 17/06/2015 EN (English) 4/1 IMIDASECT ANTS LD50 oral > 2000 mg/kg LD50 dermal > 2000 mg/kg Skin corrosion/irritation : Not classified pH: 7 - 8 Serious eye damage/irritation : Not classified pH: 7 - 8 Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified SECTION 12.

9 Ecological information Toxicity IMIDASECT ANTS LC50 fish 1 211 mg/l (Oncorhynchus mykiss) EC50 Daphnia 1 85 mg/l (Daphnia magna) ErC50 (algae) 39 mg/l Persistence and degradability No additional information available Bioaccumulative potential No additional information available Mobility in soil No additional information available Results of PBT and vPvB assessment No additional information available Other adverse effects No additional information available SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods : Collect all waste in suitable and labelled containers and dispose according to local legislation. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) : Not applicable Proper Shipping Name (IMDG) : Not applicable Proper Shipping Name (IATA) : Not applicable Proper Shipping Name (ADN) : Not applicable Proper Shipping Name (RID) : Not applicable Transport hazard class(es) ADR Transport hazard class(es) (ADR) : Not applicable IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : Not applicable IMIDASECT ANTS Safety Data Sheet according to Regulation (EU) No.

10 2015/830 17/06/2015 EN (English) 5/1 ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (RID) : Not applicable Packing group Packing group (ADR) : Not applicable Packing group (IMDG) : Not applicable Packing group (IATA) : Not applicable Packing group (ADN) : Not applicable Packing group (RID) : Not applicable Environmental hazards Dangerous for the environment : No Marine pollutant : No Other information : No supplementary information available Special precautions for user - Overland transport Portable tank and bulk container instructions (ADR) : T1, BK1, BK2 Portable tank and bulk container special provisions (ADR) : TP33 Special provisions for carriage - Packages (ADR) : V13 Special provisions for carriage - Bulk (ADR) : VV1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13 - Transport by sea No data available - Air transport No data available - Inland waterway transport Number of blue cones/lights (ADN) : 0 Not subject to ADN : No - Rail transport Carriage prohibited (RID) : No Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Other information, restriction and prohibition regulations : according to Regulation (EU) No.