SECTION 1: CHEMICAL PRODUCT AND COMPANY …

1 MATERIAL SAFETY DATA SHEET Smith s Dry Pigment Packs Page 1 of 4 Original Issue: March 2, 2012 SECTION 1: CHEMICAL PRODUCT AND COMPANY identification PRODUCT Iron Oxide pigments CHEMICAL Fe2O3 (red), Fe3O4 (black), FeOOH (yellow) and blends of two or more of these. Physical Solid powder Red, Black, Yellow, Tan, Brown, Orange, Maroon- varies with designated PRODUCT General Colorant for use in integrally colored overlay and concrete products COMPANY : Smith Paint Products 2200 Paxton Street Harrisburg, PA 17111 24 EMERGENCY: Chemtrec (800) 424-9300 HMIS RATINGS Health Flammability Reactivity Max Personal SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS wt.

2 % CAS No OSHA/PEL* ACGIH/TLV* Iron Oxide Red Pigment Red 1309-37-1 10 mg/m3 5 mg/m3 77491 Iron Oxide Black Pigment Black 100 1317-61-9 10 mg/m3 5 mg/m3 77499 Iron Oxide Yellow Pigment Yellow 100 51274-00-1 10 mg/m3 5 mg/m3 77492 *Unless otherwise noted, all PEL and TLV values are reported as 8 hour time weighted averages (TWA) SECTION 3: HAZARD identification LITTLE OR NO IMMEDIATE HAZARD- potential formation of explosive air/dust cloud with confinement, pressure and ignition source MATERIAL SAFETY DATA SHEET Smith s Dry Pigment Packs Page 2 of 4 SECTION 4: FIRST AID MEASURES from exposure, to fresh air.

3 Seek medical attention if symptoms worsen or persist. A NIOSH N-95 approved respirator is recommended whenever dusty, powder situations are encountered. Eye Flush eyes with water for 15 minutes, occasionally lifting upper and lower eyelids. Seek medical attention if necessary. Safety eyewear is recommended whenever dusty, powder situations are encountered. Skin Wash with soap and water if irritation develops. PRODUCT may have an abrasive action. If ingested, do not induce vomiting. If conscious, drink two glasses of water. Seek medical attention if necessary SECTION 5: FIRE FIGHTING MEASURES PRODUCT will not burn.

4 Use appropriate extinguishing media for packaging materials if applicable. Explosion Not Explosive Not Flammable or Combustible N/A Flash N/A N/A SECTION 6: ACCIDENTAL RELEASE MEASURES Proper respiratory and personal protective equipment may be required. Vacuum, sweep or scoop spilled materials into containers for reclaiming or disposal. It is the user s responsibility to obey local, state and federal regulations of proper disposal. Spilled materials may become slippery when wet. Care should be exercised when walking on spills on floors or concrete pads. SECTION 7: HANDLING AND STORAGE Engineering All facilities commonly handling powders need eyewash stations and proper protective equipment as needed.

5 Ventilation may be required according to conditions to avoid excessive dust formation. Storage Store PRODUCT at ambient temperatures. Keep material and packaging dry. Store in closed container(s) to avoid cross contamination of colors or other products SECTION 8: EXPOSURE CONTROLS- PERSONAL PROTECTION Control Use adequate ventilation to keep airborne concentrations low. Personal Protective Equipment N-95 respirator is recommended if excessive dust is generated Eye glasses/goggles recommended, as with any dusty or powder PRODUCT None required, rubber gloves may be used under prolong exposure.

6 Existing wounds or conditions may become irritated. MATERIAL SAFETY DATA SHEET Smith s Dry Pigment Packs Page 3 of 4 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical Solid powder pH (aqueous suspension) 5-7 range from red, black, yellow brown, orange, maroon Specific ; varies with color Melting N/A N/A Vapor N/A Boiling N/A Solubility in Insoluble SECTION 10: STABILITY AND REACTIVITY Stable with respect to storage conditions SECTION 7. None Hazardous Decomposition None Hazardous None SECTION 11: TOXICOLOGICAL INFORMATION LD-50 (oral).

7 >10 g/kg (rats) no human carcinogen no teratogenic no mutagenic Other no other studies available SECTION 12: ECOLOGICAL INFORMATION Environmental Fate: This material is not expected to biodegrade when released into the soil. This material is not expected to significantly bio-accumulate. LC-50 (fish) > 10,000 mg/kg SECTION 13: DISPOSAL CONSIDERATIONS Dispose of containers and contents in accordance with local, state and Federal requirements. ALWAYS minimize any use of ANY water system for the disposal of any industrial, commercial or residential waste. SECTION 14: TRANSPORTATION INFORMATION Proper Shipping N/A N/A N/A Hazard Class/ ID No.

8 / Packing N/A N/A N/A N/A N/A N/A Additional N/A N/A N/A SECTION 15: REGULATORY INFORMATION TSCA SECTION 8 (b): CAS listed in SECTION 2 MATERIAL SAFETY DATA SHEET Smith s Dry Pigment Packs Page 4 of 4 SARA Title III SECTION 302 Extremely Hazardous Substances: Since Iron Oxides are not EHS and no Threshold Planning Quantity is established, its presence in quantities at or above TPQ does not require any Emergency Planning Notification under 40 CFR part 355 SARA Title III SECTION 304 CERCLA Hazardous Substances: Releases in quantities equal to or above their Reportable Quantity are not subject to any Emergency Notification, as no reportable quantity is established under 40 CFR Part 302 SARA Title III Sections 311/312: No reporting (tier I or Tier II) shall be submitted by the facility under 40 CFR Part 370 Physical Hazards None Sudden Release of None None Health None None None SARA Title III SECTION 313 Toxic Chemicals.

9 No Reporting for routine annual toxic chemicals release shall be submitted under 40 CFR Part 372 STATE REGULATIONS Iron Oxides do not appear on the states Right to know lists: California Proposition 65 New Jersey RTK Hazardous Substance List Pennsylvania Hazardous Substance List Florida Toxic Substance List Massachusetts Hazardous Substance List Michigan Critical Materials Register Minnesota Hazardous Substance List WARNING: This PRODUCT MAY also contain extremely small amounts of one or more naturally-occurring materials known to cause cancer, birth defects or other reproductive harm.

10 SECTION 16: OTHER INFORMATION To the best of our knowledge, the information contained herein is accurate. However, Smith Paint Products nor any of its designated agents/distributors assumes any liability for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the sole responsibility of the User. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.