SECTION 2 - HAZARD IDENTIFICATION - …

1 Date IssuedDocument NbrRevisionDate Revised01 JUNE 201510010010US_en 001 JUNE 2015 Prepared to OSHA, CMA, ANSI, and Canadian WHMIS StandardsSECTION 1 - TRADE NAME: AMMONIATED JEWELRY CLEANER CONCENTRATESYNONYMS:NoneCAS# PRODUCT USE:Jewelry CleanerPRODUCT NUMBER:Model No: SUPPLIER/MANUFACTURER'S NAME:Connoisseurs Products CorporationADDRESS: 17 Presidential Way, Woburn, MA 01801-1040 USABUSINESS PHONE:(781) SITE EMERGENCY PHONE NUMBERS:1 (800) 424-9300 (CHEMTREC - 24 HRS.)1 (703) 527-3887 (CHEMTREC OUTSIDE ) SECTION 2 - HAZARD IDENTIFICATIONUS DOT SYMBOLSCANADA (WHMIS) SYMBOLSGHS HAZARD Symbols Signal Word: Warning!

2 GHS LABELING AND HAZARD CLASSIFICATION:This product does meet the definition of a hazardous substance or preparation as defined by the OSHA and described in 29 CFR (d).Component(s) Contributing to Classification(s):C12-15 Alcohol Ethoxylates, C11 Alcohol Ethoxylate, Ammonium LABEL ELEMENTSGHS HAZARD Classification(s):Eye Irritant Category 2 ASkin Corrosion/Irritant Category 2 STOT SE Category 3 Acute Aquatic Toxicity Category 1 AMMONIATED JEWELRY CLEANER CONCENTRATEPage 1 of 7 Printed: 23. Jun. 2015 SAFETY DATA SHEETAMMONIATED JEWELRY CLEANER CONCENTRATEM odel No: 13 EMERGENCY OVERVIEW:Product Description: This product is a water-white, thin, foamy liquid with a strong ammonia odor.

3 Health hazards : Exposure to this product can cause irritation to eyes, respiratory system, and skin. Product contains a corrosive material which may cause serious eye damage. Harmful if hazards : This product has a flash point greater than 200 F ( C).Reactivity hazards : This product is hazards : The environmental effects of this product have not been fully Considerations: Emergency responders must wear the proper personal protective equipment (and have appropriate fire-suppression equipment) suitable for the situation to which they are Statement(s):Precautionary Statement(s):May cause respiratory not handle until all safety precautions have been read and if hands thoroughly after skin not get in eyes, on skin, or on serious eye only in well ventilated to aquatic life with long lasting Statement(s):IF SWALLOWED.

4 Call a Poison Control SWALLOWED: Rinse mouth. Do NOT induce ON SKIN: Wash with plenty of skin irritation or rash occurs: Get medical off contaminated clothing and wash it before a Poison Center/Doctor if you feel INHALED: Remove person to fresh air and keep comfortable for necessary, use artificial respiration to support vital IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue Statement(s):Store in a well-ventilated place. Keep locked Statement(s):Dispose of contents/container in accordance with local/regional/national/international HEALTH hazards OR RISKS FROM EXPOSURE:SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of overexposure for this product are by contact with skin or eyes, and inhalation of mists or spray.

5 The symptoms of overexposure are described in the following :INHALATION: Inhalation of mist from this product may cause irritation to mucous membranes and respiratory CONTACT: Exposure to this product may cause skin CONTACT: Contact with eyes may cause : Ingestion may cause irritation of the digestive : The effects of long term, low level exposures to this product have not been ORGANS:ACUTE:Eyes, Respiratory System, SkinCHRONIC:None knownSECTION 3 - COMPOSITION and INFORMATION ON INGREDIENTSCOMPOSITIONWT. PERCENTAGECAS # HAZARD CLASSIFICATIONW ater65-75%7732-18-5 NoneC12 15 Alcohol Ethoxylate 5-15%68131-39-5 IrritantSodium Iminodisuccinate5-15%144538-83-0 NoneC11 Alcohol Ethoxylate 1-10%34398-01-1 Irritant Ammonium Hydroxide1-2%192003-74-0 IrritantBalance of other ingredients are less than 1% in concentration (or for carcinogens, reproductive toxins, or respiratory sensitizers)NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI 4 - FIRST-AID DESCRIPTION OF FIRST AID MEASURES:EYE CONTACT.

6 If product enters the eyes, open eyes while under gentle running water for at least 15 minutes. Seek medical attention if irritation CONTACT: Wash skin thoroughly after handling. Seek medical attention if irritation develops and persists. Remove contaminated clothing. Launder before : If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Seek medical attention if breathing difficulty : If product is swallowed, call physician or poison control center for most current information. If professional advice is not available, do not induce vomiting.

7 Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot AMMONIATED JEWELRY CLEANER CONCENTRATE Page 2 of 7 Printed: 23. Jun. 2015swallow. Seek medical advice. Take a copy of the label and SDS with the victim to the health CONDITIONS AGGRAVATED BY EXPOSURE: None SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:Contact with eyes may cause irritation. Skin exposure may cause skin RECOMMENDATIONS TO PHYSICIANS:Treat symptoms and eliminate 5 - FIRE-FIGHTING FIRE EXTINGUISHING MATERIALS:Use fire extinguishing methods below:Water Spray: YesCarbon Dioxide: YesFoam: YesDry Chemical: YesHalon: YesOther: Any C Class UNUSUAL FIRE AND EXPLOSION hazards :Combustion may produce noxious and irritating gases.

8 Explosion Sensitivity to Mechanical Impact: NoExplosion Sensitivity to Static Discharge: NoFLASH POINT: >200 F (>93 C)AUTOIGNITION TEMPERATURE: Not LIMITS (in air by volume, %): Lower: NA, Upper: SPECIAL FIRE-FIGHTING PROCEDURES:Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Isolate materials not yet involved in the fire and protect personnel. Move containers from fire area if this can be done without risk; otherwise, cool with carefully applied water spray. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive RATING SYSTEM HMIS RATING SYSTEMFLAMMABILITY HEALTHREACTIVITYOTHERH azard Scale: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe, *=Chronic HazardSECTION 6 - ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES:AMMONIATED JEWELRY CLEANER CONCENTRATE Page 3 of 7 Printed: 23.

9 Jun. 2015 HAZARDOUS MATERIAL IDENTIFICATION SYSTEMHEALTH HAZARD (BLUE)2 FLAMMABILITY HAZARD (RED)1 PHYSICAL HAZARD (YELLOW)1 PROTECTIVE EQUIPMENTEYESRESPIRATORYHANDSBODY See Sect 8 See Sect 8 For Routine Industrial Use and Handling ApplicationsSee SECTION for Exposure ENVIRONMENTAL PRECAUTIONS:Keep spilled material out of all sewers and open bodies of SPILL AND LEAK RESPONSE:Contain spill if safe to do so. Cover or absorb spilled liquid with sand, earth, or other inert material. Clean up spill immediately and place in appropriate containers. Keep spill out of sewers and open bodies of water. CAUTION: Floor may become of in accordance with applicable Federal, State, and local procedures (see SECTION 13 Disposal Considerations).

10 SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING:As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat, drink, smoke, or applycosmetics while handling this product. Avoid breathing vapors/mists generated by this product. Use in a well-ventilated location. Remove contaminated clothing immediately. STORAGE AND HANDLING PRACTICES:Containers of this product must be properly labeled. Store containers in a cool, dry location. Keep container tightly closed when not in SPECIFIC USES:Developed specifically for jewelry 8 EXPOSURE CONTROLS PERSONAL EXPOSURE PARAMETERS:CHEMICAL NAMECAS#ACGIH TLVOSHA TWAW ater7732-18-5 Not ListedNot ListedSodium Iminodisuccinate144538-83-0 Not ListedNot ListedC12 15 Alcohol Ethoxylate 68131-39-5 Not ListedNot ListedC11 Alcohol Ethoxylate 34398-01-1 Not ListedNot ListedAmmonium Hydroxide1336-21-625 ppm / 17 mg/m (as ammonia)35 ppm / 27 mg/m (as ammonia) EXPOSURE CONTROLS:VENTILATION AND ENGINEERING CONTROLS.