Solvent naphtha (petroleum), light aromatic - Petrobras

1 Solvent naphtha ( petroleum ), light aromatic Safety data sheet according to Regulation (EC) No. 453/ 2010 . Revision date: 05/12/2012 Version: SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Chemical type : petroleum substance Substance name : Solvent naphta( petroleum ), light aromatic Trade name : AB-9. EC index no. : 649-356-00-4. EC no : 265-199-0. CAS No. : 64742-95-6. REACH registration No. : 01-2119486773-24-007. Synonyms : AB-9 / Solvent naphtha / aromatic C9/ aromatic naphtha type I. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/preparation : Manufacture of substances Intermediate Formulation [mixing] of preparations and/or re-packaging Coatings Manufacture of rubber products Fuels Cleaning agent Uses advised against No additional information available Details of the supplier of the safety data sheet Only representative: Petrobras Europe Ltd.

2 4th Floor, 20 North Audley Street London W1K 6WL, United Kingdom Fax number: +44(0) 20 7355 8750. E-mail: Manufacturer: Petr leo Brasileiro S. A. Avenida Chile, 65. 20035-900 Rio de Janeiro - Brazil E-mail: Emergency telephone number Emergency number : For Chemical Emergency, Spill, Leak, Fire, Exposure or Accident Call CHEMTREC Day or Night Within USA and Canada: 1-800-424-9300. Outside USA and Canada (collect calls accepted): 1-703-527-3887. SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]. Flammable Liquids Category 3 H226. Skin corrosion/irritation Category 2 H315. Germ cell mutagenicity Category 1B H340.

3 Carcinogenicity Category 1B H350. Specific target organ toxicity Single exposure Category 3 H335. Aspiration hazard Category 1 H304. Chronic aquatic toxicity Category 2 H411. Classification according to Directive 67/548/EEC or 1999/45/EC. F ; R10. Xi ; R38. Muta. Cat. 2 ; R46. Carc. Cat. 2 ; R45/49. Xn ; R62/63. R67. Xn; R65. N ; R51/53. Adverse physicochemical, human health and environmental effects No additional information available. Full text of H-, R-phrases and others: see section 16. 05/12/2012 EN (English) 1/7. Solvent naphtha ( petroleum ), light aromatic Safety data sheet according to Regulation (EC) No. 453/ 2010 . Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP].

4 Hazard pictograms (CLP) : GHS02 GHS07 GHS08 GHS09. Signal word (CLP) : Danger Hazard statements (CLP) : H226 - Flammable liquid and vapour H315 - Causes skin irritation H340 - May cause genetic defects H350 - May cause cancer H336 - May cause drowsiness or dizziness H304 - May be fatal if swallowed and enters airways H411 - Toxic to aquatic life with long lasting effects Precautionary statements (CLP) : P201 - Obtain special instructions before use P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking. P242 - Use only non-sparking tools. P280 - Wear eye protection, protective clothing, protective gloves. P301+P310 - IF SWALLOWED, immediately call a doctor. P331 - Do NOT induce vomiting.

5 P403+P233 - Store in a well-ventilated place. Keep container tightly closed. Other hazards This substance/mixture does not meet the PBT/vPvB criteria of REACH, annex XIII. SECTION 3: Composition/information on ingredients Substances Classification according to Name Product identifier %. Directive 67/548/EEC. Solvent naphtha ( petroleum ), light aromatic . CAS no. 64742-95-6 100 F ; R10. EC number 265-199-0 Xi ; R38. EC index no. 649-356-00-4 Muta. Cat. 2 ; R46. Carc. Cat. 2 ; R45/49. Xn ; R62/63. R67. Xn; R65. N ; R51/53. Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]. Solvent naphtha ( petroleum ), light aromatic . CAS no. 64742-95-6 100 Flam. Liq. Cat.

6 3. EC number 265-199-0 Skin corrosion/irrit. Cat. 2. EC index no. 649-356-00-4 Germ cell mut. Cat. 1B. Carc. Cat. 1B. STOT - SE Aspiration haz. Cat. 1. Chronic aquatic tox. Cat. 2. Full text of R-, H- and EUH-phrases: see section 16. Mixtures Not applicable. This product is a petroleum substance. SECTION 4: First aid measures Description of first aid measures First-aid measures after inhalation : Remove the victim to fresh air. Monitor respiratory function. If there is breathing difficulty, provide oxygen. If necessary, give artificial respiration. Seek medical attention. Take this SDS. First-aid measures after skin contact : Remove contaminated clothing and shoes. Wash affected area with plenty of water for at least 15 minutes.

7 Wash contaminated clothing and shoes before reuse. Seek medical attention. Take this SDS. First-aid measures after eye contact : Wash immediately with running water for at least 15 minutes, keeping the eyelids open. Remove contact lenses if present and easily removable. Seek medical attention. Take this SDS. First-aid measures after ingestion : Rinse mouth of victim with water. Give plenty of water to drink. DO NOT INDUCE VOMITING. Seek medical attention. Most important symptoms and effects, both acute and delayed May cause skin dryness or cracking. May cause narcotic effects and respiratory irritation. May result in aspiration into the lungs, causing chemical pneumonia or delayed pulmonary edema.

8 05/12/2012 EN (English) 2/7. Solvent naphtha ( petroleum ), light aromatic Safety data sheet according to Regulation (EC) No. 453/ 2010 . Indication of any immediate medical attention and special treatment needed Keep victim warm and rested. Avoid any direct contact with the product. Never give anything by mouth to an unconscious person. Symptomatic treatment should include, above all, measured of support as correction of hydro electrolytic and metabolic disturbances and respiratory failure. SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media: : Water spray. dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Use water spray/stream to protect personnel and to cool endangered containers.

9 Unsuitable extinguishing media : Do not use water jet. Burning liquid may float on water. Special hazards arising from the substance or mixture Combustion products Toxic vapours may be formed. Incomplete combustion is likely to give rise to a complex mixture of airborne solid and liquid particulates and gases, including carbon monoxide and unidentified organic and inorganic compounds. Fire hazard : Vapours may spread to sources of ignition and provoke flames to retrocede. Closed containers may rupture violently when exposed to fire or excessive heat. Explosion hazard : Risk of explosion if heated in a confined system. Gas/vapour explosive with air within explosion limits. Reactivity : Stable in use and storage conditions as recommended in item 7.

10 Advice for firefighters Self-contained breathing apparatus (SCBA) operated in positive pressure mode and complete protective clothing. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Use personal protective equipment as described on section 8. Emergency procedures : Isolate the leak from sources of ignition. Prevent sparks or flames. For emergency responders Protective equipment : Use personal protective equipment as described on section 8. Environmental precautions Avoid spillage reaches watercourses and sewerage systems. It is recommended the installation of fire alarm system and leak detection in storage and handling sites.