The World of Herbicides - Herbicide Resistance Action ...

1 The World of HerbicidesAccording to HRAC classification on mode of Action 2010 Herbicides AFFECTING: Light ProcessesCell MetabolismGrowth/Cell DivisionC2C3C1 CInhibition ofphotosynthesis at PS IIBI nhibition of ALS (branched)chain amino acid synth.)K1 Inhibition ofmicrotubule assemblyK2 Inhibition ofmicrotubule organisationMUncoupler (membrane disruption)EInhibition ofprotoporphyrinogen oxidaseD PS-I-electron diversionFInhibition of pigmentsynthesis (bleaching)NLipid synthesis inhibition(not ACCase)ALipid synthesis inhibition(inhibition of ACCase)K3 Inhibition of cell division(inhibition of VLCFAs)LInhibition ofcellulose synthesisF1 Inhibition of PDS F4 Inhibition of DOXP synthaseF3 Unknown target F2 Inhibition of4-HPPD IDHP-inhibition ZUnknown modeof actionOSynthetic Auxins PAuxin transportinhibitionHGlutamine synthetase inhibition GInhibition ofEPSP synthase Phenyl-pyridazinesDiphenyl ethersThiadiazolesDiphenyletherPyrimidin edionesCyclohexanediones (DIMs)Chlorocarb.

2 AcidsOthersGlycinesOthersOthersUreasUrac ilsAmidesTriazolinoneTriazinesPhenylpyra zolesImidazolinonesTriazolopyrimidinesCh loroacetamidesPyridine-carboxylic acidsBenzoic acidsPhenoxy-carboxylic acidsTetrazolinonesAcetamidesSemicarbazo nePhthalamateBenzamideAlkylazinesNitrile sPyridinesPhosphoroamidatesDinitrophenol sBipyridyliumsPhosphorodithioateBenzofur anesQuinolinecarboxylic acidsPhosphinic acidsCarbamateSulfonylamino-carbonyl-tri azolinonesSulfonylureasPyrimidinyl (thio) benzoatesOxadiazolesTriazinonesTriazolin onesPyridazinoneNitrilesPhenylcarbamates N-Phenyl-phthalimidesOxazolidinedioneBen zothiadiazinoneBenzoic acidCarbamatesDinitroanilinesBenzamidesO xyacetamidesAryloxyphenoxy-propionates (FOPs) (DEN)Arylaminopropionic acidTriazolocarboxamideOONHClClClomeprop OOHOClClDichlorprop=2,4-DPOOHOClCl2,4-DO OHOClMCPAOClClOHO2.

3 4-DBOClOHOMCPBOClOHOM ecoprop = MCPP = CMPPFFNNNONH2 ClOFFFF lupoxamNClClClOOHOT riclopyrNClClOOHC lopyralidNFClClOOHONH2 FluroxypyrNClClClNH2 OOHP icloramNClClNH2 OOHA minopyralidNHNOOOOI soxabenClClNH2 OHOC hlorambenOHOOClClDicambaO HOClClClTBAClClCNDichlobenilClClSNH2 ChlorthiamidNHOOHON aptalamNOOHClQuinmeracNClOOHClQuinclorac OONNNHNHOFFNaDiflufenzopyr-sodiumNSOClOO Benazolin-ethyl+NNNN H2 FNHOT riaziflamIndaziflamNNNNH2 FCH3CH3 NHCH3 NNNNHNHSD esmetryneNNNClNHNHP ropazineNNNN HNHSA metryneNNNNHNHClAtrazineNNNNHSNHD imethametrynNNNNHNHClSimazineNNNNHNHClTe rbuthylazineNNNNHNHST erbutryneNNNNHNHSS imetryneNNNNHNHOP rometonNNNNHNHClC NCyanazineNNNNHNHSP rometryneNNNNHNHOT erbumetonNNNNNHClTrietazineNHNOF enuronSNNNHOM ethabenzthiazuronNHClNOChlorotoluronNHON OClChloroxuronNHNOFFFF luometuron (also F3)ClClNHNON eburonNHNClNOONOD imefuronNHNOI soproturonOClNHONM etoxuronNHNHOS iduronNHClClNODiuronNONHNOI souronClNHNOOM onolinuronNNSNONHT ebuthiuronBrClNHNOOC hlorobromuronSNNNSOONHOE thidimuronClClNHNOOL inuronNSNHOOOB entazoneNNHOBrOBromacilNNHOOL enacilNNHOClOTerbacilNHONHOOOP henmediphamNNClOOSP yridateNNOHClPyridafolNNOClNH2 Chloridazon/PyrazonNNNNOOH exazinoneNNNONH2 MetamitronNNNONH2 SMetribuzinNNNONH2 ONHA micarbazoneN+N+BrBrN+N+ClClDiquatParaqua tClClNHOP ropanilClNHOP entanochlorBrOHBrN ONO2O2 NBromofenoxim (also M)IOHICNI oxynil (also M)BrOHBrCNBromoxynil (also M)ONHOONHOD esmediphamBrNHONOM etobromuronONNHOFFFFP icolinafenNOFFFF luridoneNNOClNHFFFN orflurazonNOClClFFFF lurochloridoneOClNH2O2 NAclonifenNHNOFFFF luometuron(also C)

4 NOClOClomazoneONOClSOOI soxachlortoleNNOOClClOPyrazoxyfenNNOOHSF FFOOP yrasulfotoleOOOClSOOOOT efuryltrioneONHOFFFF lurtamoneONONHFFFFFD iflufenicanBeflubutamidFFFFOONHI soxaflutoleONOFFFSOOB enzofenapNNOOOClClPyrazolynateNNOSOOClCl OSulcotrioneClOOOOSOOM esotrioneOOON+OOSOOB enzobicyclonSOClSOOT embotrioneOOOClOFFFSOOT opramezoneONNOHONSOOOOHONFFFOOB icyclopyroneAmitrole (Inh. of lycopene cyclase)NHNNNH2 NHONHD ymron = DaimuronNHNOM ethyldymronNHNHOClCumyluronOHOP elargonic acidNNSSD azomet(CH2)7CO2H(CH2)7CH3 Oleic AcidONClClOOxaziclomefoneNH2 POOOO HFosamineClClNHOOOE tobenzanidOOCinmethylinNNOSOP yributicarbDSMAAsOOONa+Na+MSMAAsOOHONa+M etamSSNHNa+BromobutideNHOBrDifenzoquatMe tilsulfateNN+CH3SO-4 IndanofanOOOClChlorflurenolOHOHOClNNOONH NHOS OONS OOAmidosulfuronNNOONHNHOSOONNNNNNA zimsulfuronNNOONHNHOSOOOOB ensulfuron-methylNNONHNHOSOOOOClChlorimu ron-ethylNNNONHNHOSOOClChlorsulfuronNNNO ONHNHOSOOOOC inosulfuronNNOONHNOSOONOFFFNa+Trifloxysu lfuron-sodiumNNOONHNHOSOONHOC yclosulfamuronNNNONHNHNHOSOOOOE thametsulfuron-methylNNOONHNHOSOOOOE thoxysulfuronNNOONHNHOSOONFFFF lazasulfuronNNOONHNOSOONOOFFFNa+Flupyrsu lfuron-methyl-sodiumNNOONHNHOSOONNClOOHa losulfuron-methylNNNOONHNHOSOONClImazosu lfuronNNNONHNOSOOIOONa+Iodosulfuron-meth yl-sodiumNNNONHNHOSOOOOM etsulfuron-methylNNOONHNHOSOONHONOHF

5 OramsulfuronNNOONHNHOSOONONN icosulfuronNNNHNHOSOOOOOO xasulfuronNNOONHNHOSOOOFFFFOP rimisulfuron-methylNNNONHNHOSOOFFFP rosulfuronNNOONHNHOSOOOONHSOOM esosulfuron-methylNNOONHNHOSOONNOOP yrazosulfuron-ethylNNOONHNHOSOONSOOR imsulfuronNNNHNHOSOOOOS ulfometuron-methylNNOONHNHOS OONNSOOS ulfosulfuronNNNONHNHOS OOFFFFFFT ritosulfuronNNNONHNHOS OOSOOT hifensulfuron-methylNNNONHNHOS OOOClTriasulfuronNNNONNHOSOOOOT ribenuron-methylNNNONHNHOSOOONOFFFT riflusulfuron-methylNNOONHNHOSOOOONOFF lucetosulfuronNNOONHNHOSOONHNOO rthosulfamuronNHNONOOHI mazapicNHNONOOHI mazapyrNHNOOONHNOOO+Imazamethabenz-methy lNHNONOOHI mazaquinNHNONOOHOI mazamoxNHNONOOHI mazethapyrOHNO2NO2 DNOCOHNO2NO2 DinoterbOHNO2NO2 DinosebOONNNNOOOOOONa+Bispyribac-sodiumO ONNNNOOOOOONP yribenzoximSNNOOOOClNa+Pyrithiobac-sodiu mSNNOOOOP yriftalidONNOOOONOP yriminobac-methylNHNNOOOHOSOOFFP yrimisulfanSNOOONNNOOOONa+OSNOOONNNOOFFF Na+Flucarbazone-sodiumPropoxycarbazone-s odiumSSNHNONNOOOOO OThiencarbazone-methylNNNNSNHClOOOOFOC loransulam-methylNNNNSNHClClOOFOD iclosulamNNNNSNHFFOOOFF lorasulamNNNNSNHFFOOF lumetsulamNNNNSNHClClOOOOM etosulamNNNNNHSOOOOOFFFFFP enoxsulamNNNNNHSNOOOOOFFFP yroxsulamOHPNHOHOOOHG lyphosateOHPNHOHOOO(CH3)

6 3S+SulfosatePOHOONH2 ONH4+Glufosinate-ammoniumNH2 SNHOOOOA sulamPropyrisulfuronNNSNHNHONNNClOOOOB ialaphosCH3 POOHNH2 HNHOCH3 HNHOCH3 HOOHSNHSPOOSOOB ensulideSNOT iocarbazilSNOClThiobencarb = BenthiocarbSNOE sprocarbSNOC ycloateSNOEPTCNSOD imepiperateNSOM olinateSNOClOrbencarbSNOP ebulateSNOP rosulfocarbSNOV ernolateSNOClClClTri-allateOHOClClClTCAO HOClClDalaponOHOFFFFF lupropanateOOOONOA lloxydimOOONOB utroxydimClethodimOOSNOClCycloxydimOONOS S ethoxydimOONOSP rofoxydimSOONOOClTepraloxydimOOONOClPino xadenONNOOOT ralkoxydimOONOC yhalofop-butylOFNOOOCH3 HDiclofop-methylClClOOOOF luazifop-P-butylNFFFOOOOCH3 HFenoxaprop-P-ethylClONOOOOCH3 HMetamifopONClOOONFCH3 Haloxyfop-P-methylNFFFClOOOOCH3 PropaquizafopNNOClOCH3 OOONQ uizalofop-P-methylNNOClOOOCH3 Quizalofop-P-tefurylNNOClOOCH3 OOEthofumesateOOOSOOB enfuresateOOSOOB utylateSNOC lodinafop-propargylNClFOOOOCH3 NClOClNOOO xadiazonOClClNONOO xadiargylNNOOOOOOFFFB enzfendizoneClONFOOOP entoxazoneNNFHOOFClNHSClOOProfluazolNNOF OClOOFFFF lufenpyr-ethylSNNNONOFT hidiaziminNClFOClONNOFFC arfentrazone-ethylNNNOClClOAzafenidinNCl OOClOOCinidon-ethylNOClOOFOOF lumiclorac-pentylNOOFNOOF lumioxazinOClFFFOON+OONa+Acifluorfen-sod iumOClClOON+OOBifenoxOClFFFN+OOOOOOF luoroglycofen-ethylOClClON+OOChlomethoxy fenOFFFON+OONHSOOClFomesafenOFFFFClNHOSO ON+OOHalosafenOClFFFN+OOOOOOL actofenOClFFFON+OOOxyfluorfenOFFFClOOCH3 HOOClEthoxyfen-ethylNNOOFFFClOOOOB utafenacilNNNNClCNNP yraclonilNFClSOONNSOF luthiacet-methylClClNNNNHSOOOFFS ulfentrazoneNNFClOOFFFBrFluazolateNNFClO OClFFOOP yraflufen-ethylBencarbazoneNNNOFFFFNHNH2 SSOOS

7 AflufenacilNNOOFFFFClONHSNOONOClOAcetoch lorNOClOAlachlorNOClPropachlorNOClOButac hlorNOClODimethachlorNOClSOThenylchlorSN OClODimethenamidNOClNNMetazachlorNOClOMe tolachlorNOClOPretilachlorNOClOPropisoch lorNOClOPethoxamidClClClClOOOOC hlorthal-dimethyl = DCPANNO2NO2 SNH2 OONNO2NO2 FFFE thalfluralinNHNO2NO2 PendimethalinNHNO2NO2 ButralinOryzalinNNO2NO2 FFFT rifluralinNNO2NO2 FFFNH2 DinitramineNHOOClChlorprophamNHOOP rophamNNO2NO2 FFFB enefin = BenfluralinSPNHOONO2 SPNHOONO2 Amiprofos-methylButamifosNHOClClPropyzam ide = PronamideNOTebutamPSOSONOClAnilofosNPSOS OOP iperophosSOONNNNOC afenstroleONHON aproanilideNODiphenamidNSOSOFFFFFD ithiopyrNOOFFFFFSNT hiazopyrONNNSOFFFFF lufenacetONNSOM efenacetN NNNNOOClFentrazamideCarbetamideNHOONHOHN apropamideOONSNNONOOOFFFFFP yroxasulfoneIpfencarbazoneFFNOONNNCICIF lamprop-mNClFC H3 OHOO HA (1) Lipid synthesis inhibition (inh.)

8 Of ACCase)B (2) Inhibition of ALS (branched chain amino acid synthesis)C (5, 6, 7) Inhibition of photosynthesis PS IID (22) PS I electron diversionE (14) Inhibition of protoporphyrinogen oxidaseF Inhibition of pigment synthesis (bleaching)F1 (12) Inhibition of PDSF2 (27) Inhibition of 4-HPPDF3 (11, 13) Unknown targetF4 Inhibition of DOXP synthaseG (9) Inhibition of EPSP synthaseH (10) Inhibiton of glutamine synthetaseI (18) Inhibition of DHPK1 (3) Inhibition of microtubule assemblyK2 (23) Inhibition of microtubule organisationK3 (15) Inhibition of cell division (VLCFA)L (20, 21) Inhibition of cellulose synthesisM (24) Uncoupler of oxidative phosphorylationN (8, 26) Inhibition of lipid synthesis (not ACCase)O (4) Synthetic auxinP (19) Auxin transport inhibitionZ (17, 25,) Unknown mode of Action ( ) WSSA Group A free copy of this poster can be downloaded from Designed and produced by Syngenta 2010