Urea Fertilizer 46-0-0 - Simplot

1 Urea Fertilizer 46-0-0 safety data sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/22/2019 Revision date: 11/22/2019 Version: 11/22/2019 EN (English) Page 1 SECTION 1: Identification Identification Product form : Mixture Product name : Urea Fertilizer 46-0-0 Product code : M11020 Recommended use and restrictions on use No additional information available Supplier JR Simplot Company Box 70013 Boise, ID 83707 T 1-208-336-2110 Emergency telephone number Emergency number : CHEMTREC 1-800-424-9300 SECTION 2.

2 Hazard(s) identification Classification of the substance or mixture GHS-US classification Serious eye damage/eye irritation, Category 2B H320 Causes eye irritation Full text of H statements : see section 16 GHS Label elements, including precautionary statements GHS US labelling Signal word (GHS US) : Warning Hazard statements (GHS US) : H320 - Causes eye irritation Precautionary statements (GHS US) : P264 - Wash hands, forearms and face thoroughly after handling. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

3 Continue rinsing. P337+P313 - If eye irritation persists: Get medical attention Other hazards which do not result in classification No additional information available Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/information on ingredients Substances Not applicable Mixtures Name Product identifier % GHS-US classification urea (57-13-6) (CAS-No.) 57-13-6 100 Eye Irrit. 2B, H320 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures Description of first aid measures First-aid measures general : Check the vital functions.

4 Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. Never give anything by mouth to an unconscious person.

5 If you feel unwell, seek medical advice (show the label where possible). Urea Fertilizer 46-0-0 safety data sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/22/2019 EN (English) 2/8 First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. Allow affected person to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Rinse with water. Soap may be used.

6 Do not apply (chemical) neutralizing agents. Take victim to a doctor if irritation persists. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash skin with plenty of water. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse with water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

7 Continue rinsing. If eye irritation persists: Get medical attention. First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Call Poison Information Centre ( ). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center or a doctor if you feel unwell. Most important symptoms and effects (acute and delayed) Potential adverse human health effects and symptoms : Based on available data , the classification criteria are not met.

8 Symptoms/effects after inhalation : AFTER INHALATION OF DUST: Dry/sore throat. Coughing. Symptoms/effects after eye contact : Redness of the eye tissue. Causes eye irritation. mild eye irritation. Symptoms/effects after ingestion : Nausea. Vomiting. Cramps/uncontrolled muscular contractions. Chronic symptoms : No effects known. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures Suitable (and unsuitable) extinguishing media Suitable extinguishing media : EXTINGUISHING MEDIA FOR SURROUNDING FIRES: All extinguishing media allowed.

9 Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : No unsuitable extinguishing media known. Do not use a heavy water stream. Specific hazards arising from the chemical Fire hazard : DIRECT FIRE HAZARD: Non combustible. INDIRECT FIRE HAZARD: Reactions involving a fire hazard: see "Reactivity Hazard". Explosion hazard : INDIRECT EXPLOSION HAZARD: Reactions with explosion hazards: see "Reactivity Hazard". Special protective equipment and precautions for fire-fighters Precautionary measures fire : Exposure to fire/heat: keep upwind.

10 Exposure to fire/heat: consider evacuation. Exposure to fire/heat: have neighbourhood close doors and windows. Firefighting instructions : Cool tanks/drums with water spray/remove them into safety . Dilute toxic gases with water spray. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus. Do not enter fire area without proper protective equipment, including respiratory protection.