Combustion Fundamentals
2CombustionFundamentalsTounderstandthefo nnationofpollutantsincombustionsystems,w emustfirstunder-standthenatureofthefuels beingburned,thethennodynamicsofthecombus tionpro-cess, ,detonations, spectrumoffuelscurrentlyinwidespreaduse, thesimplestincompositionisnaturalgas,whi chconsistsprimarilyofmethanebutincludesa ,buttheyare,atleast, , ,whichconsistsofmeasurementsoftheelement alcompositionofthefuel,generallypresente dasmassfractionsofcarbon,hydrogen,sulfur ,oxygen,nitrogen,andash, "CH4C2H6C3HshydrocarbonsCOH2H2SN2CO2(106 Jm-3) "p,101kPa;T,25 "Sweetened,"H2S (106Jkg-I)Kerosene( ) < < ,a measureoftheheatreleaseduringcompletecom bustion, ,physicalpropertiesthatinfluencethehandl inganduseofa ,thespecificgravityorAPIgravity,*viscosi ty(possiblyat severaltemperatures),flashpoint(ameasure ofthetemperatureatwhichthefuelissufficie ntlyvolatiletoignitereadily),anddistilla tionprofiles(fractionvaporizedasa functionoftemperature) ,coalsareclassifiedbyrank,a haveundergonerelativelylittlechange, , ,whichidentifiesthedegreeofcoalifactiono fa solidfuel( ).
Yeo, = --= 0.125 = 12.5% 64.25 9 YH,O =--5= 0.140 = 14.0% 64.2 = 47.25 = 0.735 = 73.5% YN, 64.25 Minor components and impurities in the fuel complicate our analysis ofcombus tion products somewhat. Fuel sulfur is usually oxidized to form sulfur dioxide (802 ), (Even though there are cases where sulfur compounds involving higher oxidation states
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