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Chapter 5 Thermodynamic potentials - uni-frankfurt.de

itp.uni-frankfurt.de

The thermodynamic potentials vary as extensive state properties if the volume and num-ber of particles vary by a factor λ, i.e., V → λV Nj → λNj ⇒ U → λU . (5.15) Note that long-range interactions between particles, such as the unscreened Coulomb interaction, may invalidate (5.15). Surface effects will contribute in addition for ...

  Potential

Example Exercise 17.1 Calculating Oxidation Numbers for

www.austincc.edu

Let’s refer to the table of reduction potentials to predict whether or not the reaction is spontaneous. Table 17.3 lists Ni 2+(aq) as a weaker oxidizing agent than Sn 2+(aq). Moreover, Sn(s) is a weaker reducing agent than Ni(s).

  Exercise, Example, Potential, Number, Oxidation, Calculating, Example exercise 17, 1 calculating oxidation numbers for

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