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2.3 Poly(methyl methacrylate) [9011-14-7
vtechworks.lib.vt.edu2.3.1 Polymerization of Methyl Methacrylate [80-62-6] PMMA can be produced using a variety of polymerization mechanisms. The most common technique is the free radical polymerization of MMA. The free radical polymerization of acrylates and methacrylates is a chain polymerization across the double bond of the monomer (Figure 2.5).