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12.112.112.1 Nomenclature and Structure of Carbonyl Group

After studying this Unit, you will beable to write the common and IUPAC names of aldehydes, ketones andcarboxylic acids; write the structures of thecompounds containing functionalgroups namely Carbonyl andcarboxyl groups; describe the important methodsof preparation and reactions ofthese classes of compounds; correlate physical properties andchemical reactions of aldehydes,ketones and carboxylic acids,with their structures; explain the mechanism of a fewselected reactions of aldehydesand ketones; understand various factorsaffecting the acidity of carboxylicacids and their reactions; describe the uses of aldehydes,ketones and carboxylic compounds are of utmost importance to organicchemistry.

benzoic acids. However, it is possible to stop the oxidation at the aldehyde stage with suitable reagents that convert the methyl group to an intermediate that is difficult to oxidise further. The following methods are used for this purpose. (a) Use of chromyl chloride (CrO2Cl2): Chromyl chloride oxidises

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