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2. CHEMISTRY OF DISINFECTANTS AND DISINFECTANT BY …

272. CHEMISTRY OF DISINFECTANTS ANDDISINFECTANT use of chlorine (Cl2) as a water DISINFECTANT has come underscrutiny because of its potential to react with natural organic matter(NOM) and form chlorinated DISINFECTANT by-products (DBPs). Withinthis context, NOM serves as the organic DBP precursor, whereas bro-mide ion (Br ) serves as the inorganic precursor. Treatment strategiesgenerally available to water systems exceeding drinking-water standardsinclude removing DBP precursors and using alternative disinfectantsfor primary and/or secondary (distribution system) DISINFECTANT options that show promise are chloramines(NH2Cl, monochloramine), chlorine dioxide (ClO2) and ozone (O3).While ozone can serve as a primary DISINFECTANT only and chloraminesas a secondary DISINFECTANT only, both chlorine and chlorine dioxide canserve as either primary or secondary presents the significant advantage of virtually elimi-nating the formation of chlorination by-products and, unlike chlorine,does not react with phenols to create taste- and odour-causing com-pounds.

In alkaline solution, it decomposes to give ... Chlorine dioxide is readily soluble in water, forming a. EHC 216: Disinfectants and Disinfectant By-products 32 greenish-yellow solution. It can be involved in a variety of redox reactions, such as oxidation of iodide ion, sulfide ion, iron(II) and

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