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6 Principles of Stereochemistry - Sapling Learning

22666 This chapter and the one that follows deal with stereoisomers and their properties. Stereoiso-mersare compounds that have the same atomic connectivity but a different arrangement ofatoms in space. Recall that E and Zisomers of an alkene (Sec. ) are stereoisomers. In thischapter we ll learn about other types of study of stereoisomers and the chemical effects of stereoisomerism is called few ideas of Stereochemistry were introduced in Sec. This chapter delvesmore generally into Stereochemistry by concentrating on the basic definitions and l l s e e h ow s t e r e o c h e m i s t r y p l a y e d a key r o l e i n t h e d e t e r m i n a t i o n o f t h e g e o m e t r y o ftetravalent carbon. Chapter 7 continues the discussion of Stereochemistry by considering boththe stereochemical aspects of cyclic compounds and the application of stereochemical princi-ples to chemical use of molecular models during the study of this chapter is essential.

6.1 ENANTIOMERS, CHIRALITY, AND SYMMETRY 229 B. Asymmetric Carbon and Stereocenters Many chiral molecules contain one or more asymmetric carbon atoms.

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