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6009 - Centers for Disease Control and Prevention

MERCURY6009Hg MW: CAS: 7439-97-6 RTECS: OV4550000 METHOD: 6009, Issue 2 EVALUATION: PARTIALI ssue 1: 15 May 1989 Issue 2: 15 August 1994 OSHA :C mg/m3 (skin) mg/m3 (skin) mg/m3 (skin)PROPERTIES: liquid; d g/mL @ 20 C; BP 356 C; HP -39 C; VP Pa ( mm Hg; mg/m3) @ 20 C; Vapor Density (air=1) :quicksilverSAMPLINGSAMPLER:SOLID SORBENT TUBE(Hopcalite in single section, 200 mg)FLOW to L/minVOL-MIN: 2 L @ mg/m3 -MAX:100 LSHIPMENT:routineSAMPLE STABILITY:30 days @ 25 C [1]FIELD BLANKS:2 to 10 field blanks per setMEDIA BLANKS:at least 3 per setMEASUREMENTTECHNIQUE:ATOMIC ABSORPTION, COLD VAPORANALYTE:elemental mercuryDESORPTION:conc. HNO3/HCl @ 25 C,dilute to 50 nmCALIBRATION:standard solutions of Hg2+ in 1% HNO3 to g per sampleESTIMATED g per samplePRECISION (S r) @ to 3 g per sample [4]ACCURACYRANGE to mg/m3 [2](10-L samples)BIAS:not significantOVERALL PRECISION (S rT):not determinedACCURACY:not determinedAPPLICABILITY: The working range us to mg/m3 for a 10-L air sample.

APPLICABILITY: The working range us 0.01 to 0.5 mg/m3 for a 10-L air sample. The sorbent material irreversibly collects elemental mercury. A prefilter can be used to exclude particulate mercury species from the sample. The prefilter can be analyzed by similar methodology. The method has been used in numerous field surveys [3].

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