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Benzene and Its Derivatives

282 Peppers of the capsicum family. Hot peppers contain significant amounts of the chemical capsaicin, which is used for medicinal purposes as well as for tantalizing taste buds (see Chemical Connections, Capsaicin, for Those Who Like It Hot ). Inset: A model of capsaicin. (Courtesy Douglas Brown)09 Benzene and Its Derivatives What Is the Structure of Benzene ? What Is Aromaticity? How Are Benzene Compounds Named, and What Are Their Physical Properties? What Is the Benzylic Position, and How Does It Contribute to Benzene Reactivity? What Is electrophilic aromatic substitution ? What Is the Mechanism of electrophilic aromatic substitution ? How Do Existing Substituents on Benzene Affect electrophilic aromatic substitution ? What Are Phenols?HOW How to Determine Whether a Lone Pair of Electrons Is or Is Not Part of an aromatic Pi How to Determine Whether a Substituent on Benzene Is Electron WithdrawingCHEMICAL CONNECTIONS9A Carcinogenic Polynuclear Aromatics and Cancer9B Capsaicin, for Those Who Like It HotKEY QUESTIONSBENZENE, A COLORLESS LIQUID, was first isolated by Michael Faraday in 1825 from the oily residu

9.5 What Is Electrophilic Aromatic Substitution? 9.6 What Is the Mechanism of Electrophilic Aromatic Substitution? 9.7 How Do Existing Substituents on Benzene Affect Electrophilic Aromatic Substitution? 9.8 What Are Phenols? HOW TO 9.1 How to Determine Whether a Lone Pair of Electrons Is or Is Not Part of an Aromatic Pi System

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  Aromatic, Substitution, Electrophilic aromatic substitution, Electrophilic

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